scholarly journals Measurement of geologic nitrogen using mass spectrometry, colourimetry, and a newly adapted fluorometry technique

2016 ◽  
Author(s):  
Benjamin W. Johnson ◽  
Natashia Drage ◽  
Jody Spence ◽  
Nova Hanson ◽  
Rana El-Sabaawi ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Continental Crust ◽  
Large Scale ◽  
Organic N ◽  
Stable Form ◽  
Earth System ◽  
N Budget ◽  
Rock Types ◽  
The Earth ◽  
Assess Quality

Abstract. Long viewed as a mostly noble, atmospheric species, recent work demonstrates that nitrogen in fact cycles throughout the Earth system, including the atmosphere, biosphere, oceans, and solid Earth. Despite this new-found behaviour, more thorough investigation of N in geologic materials is limited due to its low concentration (1 to 10 s ppm) and difficulty in analysis. In addition, N can exist in multiple species (NO3−, NH4+, N2, organic-N), and determining which species is actually quantified can be difficult. In rocks and minerals, NH4+ is the most stable form of N over geologic time scales. As such, techniques designed to measure NH4+ can be particularly useful. We measured a number of geochemical rock standards using three different techniques: mass spectrometry, colourimetry, and fluorometry. The fluorometry approach is a novel adaptation of a technique commonly used in biologic science, applied herein to geologic NH4+. Briefly, NH4+ can be quantified by HF-dissolution, neutralization, addition of a fluorescing reagent, and analysis on a standard fluorometer. We reproduce published values for several rock standards (BCR-2, BHVO-2, and G-2), especially if an additional distillation step is performed. While it is difficult to assess quality of each method, due to lack of international geologic N standards, fluorometry appears better suited to analyzing mineral-bound NH4+ than mass spectrometry, and is a simpler, quicker alternative to colourimetry. To demonstrate a potential application of fluorometry, we calculated a continental crust N budget based on new measurements. We used glacial tills as a proxy for upper crust and analyzed several poorly constrained rock types (volcanics, mid-crustal xenoliths) to determine that the continental crust contains ∼ 2 × 1018 kg N. This estimate is consistent with recent budget estimates, and shows that fluorometry is appropriate for large-scale questions where high sample throughput is helpful. Lastly, we report the first δ15N values of six rock standards: BCR-2 (1.05 ± 0.4 ‰), BHVO-2 (−0.3 ± 0.2 ‰), G-2 (1.23 ± 1.32 ‰), LKSD-4 (3.59 ± 0.1 ‰), Till-4 (6.33 ± 0.1 ‰), and SY-4 (2.13 ± 0.5 ‰). The need for international geologic N standards is crucial for further investigation of the Earth system N cycle, and we suggest that existing rock standards may be suited to this need.

scholarly journals Measurement of geologic nitrogen using mass spectrometry, colorimetry, and a newly adapted fluorometry technique

Solid Earth ◽  
2017 ◽  
Vol 8 (2) ◽  
pp. 307-318 ◽  
Author(s):  
Benjamin W. Johnson ◽  
Natashia Drage ◽  
Jody Spence ◽  
Nova Hanson ◽  
Rana El-Sabaawi ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Continental Crust ◽  
Large Scale ◽  
Organic N ◽  
Stable Form ◽  
Earth System ◽  
N Budget ◽  
Atmospheric Species ◽  
Rock Types ◽  
The Earth

Abstract. Long viewed as a mostly noble, atmospheric species, recent work demonstrates that nitrogen in fact cycles throughout the Earth system, including the atmosphere, biosphere, oceans, and solid Earth. Despite this new-found behaviour, more thorough investigation of N in geologic materials is limited due to its low concentration (one to tens of parts per million) and difficulty in analysis. In addition, N can exist in multiple species (NO3−, NH4+, N2, organic N), and determining which species is actually quantified can be difficult. In rocks and minerals, NH4+ is the most stable form of N over geologic timescales. As such, techniques designed to measure NH4+ can be particularly useful.We measured a number of geochemical rock standards using three different techniques: elemental analyzer (EA) mass spectrometry, colorimetry, and fluorometry. The fluorometry approach is a novel adaptation of a technique commonly used in biologic science, applied herein to geologic NH4+. Briefly, NH4+ can be quantified by HF dissolution, neutralization, addition of a fluorescing reagent, and analysis on a standard fluorometer. We reproduce published values for several rock standards (BCR-2, BHVO-2, and G-2), especially if an additional distillation step is performed. While it is difficult to assess the quality of each method, due to lack of international geologic N standards, fluorometry appears better suited to analyzing mineral-bound NH4+ than EA mass spectrometry and is a simpler, quicker alternative to colorimetry.To demonstrate a potential application of fluorometry, we calculated a continental crust N budget based on new measurements. We used glacial tills as a proxy for upper crust and analyzed several poorly constrained rock types (volcanics, mid-crustal xenoliths) to determine that the continental crust contains  ∼  2  ×  1018 kg N. This estimate is consistent with recent budget estimates and shows that fluorometry is appropriate for large-scale questions where high sample throughput is helpful.Lastly, we report the first δ15N values of six rock standards: BCR-2 (1. 05  ±  0. 4 ‰), BHVO-2 (−0. 3  ±  0. 2 ‰), G-2 (1. 23  ±  1. 32 ‰), LKSD-4 (3. 59  ±  0. 1 ‰), Till-4 (6. 33  ±  0. 1 ‰), and SY-4 (2. 13  ±  0. 5 ‰). The need for international geologic N standards is crucial for further investigation of the Earth system N cycle, and we suggest that existing rock standards may be suited to this need.

Dryland Degradation and Expansion: Implications for Mexican Policies from the Earth System Perspective

2020 ◽  
pp. 1-4
Author(s):  
Gabriel Lopez Porras
Keyword(s):  
Climate Change ◽  
Ecosystem Services ◽  
Science Policy ◽  
Land Degradation ◽  
Water Scarcity ◽  
Large Scale ◽  
Earth System ◽  
Sustainable Land Management ◽  
System Perspective ◽  
The Earth

Despite international efforts to stop dryland degradation and expansion, current dryland pathways are predicted to result in large-scale migration, growing poverty and famine, and increasing climate change, land degradation, conflicts and water scarcity. Earth system science has played a key role in analysing dryland problems, and has been even incorporated in global assessments such as the ones made by the Intergovernmental Science-Policy Platform on Biodiversity and Ecosystem Services. However, policies addressing dryland degradation, like the ‘Mexican programme for the promotion of sustainable land management’, do not embrace an Earth system perspective, so they do not consider the complexity and non-linearity that underlie dryland problems. By exploring how this Mexican programme could integrate the Earth system perspective, this paper discusses how ’Earth system’ policies could better address dryland degradation and expansion in the Anthropocene.

Preliminary monthly gravity field models from kinematic orbits of SWARM Satellites

2021 ◽  
Author(s):  
Xingfu Zhang ◽  
Qiujie Chen ◽  
Yunzhong Shen
Keyword(s):  
Gravity Field ◽  
Large Scale ◽  
Earth System ◽  
The Earth ◽  
Swarm Satellites ◽  
Variable Gravity ◽  
Data Gap ◽  
One Year ◽  
Gravity Recovery ◽  
Gravity Field Models

<p>      Although the Gravity Recovery and Climate Experiment (GRACE) and GRACE Follow-On (GRACE FO) satellite missions play an important role in monitoring global mass changes within the Earth system, there is a data gap of about one year spanning July 2017 to May 2018, which leads to discontinuous gravity observations for monitoring global mass changes. As an alternative mission, the SWARM satellites can provide gravity observations to close this data gap. In this paper, we are dedicated to developing alternative monthly time-variable gravity field solutions from SWARM data. Using kinematic orbits of SWARM from ITSG for the period January 2015 to September 2020, we have generated a preliminary time series of monthly gravity field models named Tongji-Swarm2019 up to degree and order 60. The comparisons between Tongji-Swarm2019 and GRACE/GRACE-FO monthly solutions show that Tongji-Swarm2019 solutions agree with GRACE/GRACE-FO models in terms of large-scale mass change signals over amazon, Greenland and other regions. We can conclude that Tongji-Swarm2019 monthly gravity field models are able to close the gap between GRACE and GRACE FO.</p>

scholarly journals Earth System Model Evaluation Tool (ESMValTool) v2.0 – an extended set of large-scale diagnostics for quasi-operational and comprehensive evaluation of Earth system models in CMIP

2020 ◽  
Vol 13 (7) ◽  
pp. 3383-3438 ◽  
Author(s):  
Veronika Eyring ◽  
Lisa Bock ◽  
Axel Lauer ◽  
Mattia Righi ◽  
Manuel Schlund ◽  
...  
Keyword(s):  
Model Evaluation ◽  
Large Scale ◽  
Performance Metrics ◽  
Earth System Model ◽  
System Model ◽  
Earth System ◽  
Evaluation Tool ◽  
The Earth ◽  
And Performance ◽  
Earth System Models

Abstract. The Earth System Model Evaluation Tool (ESMValTool) is a community diagnostics and performance metrics tool designed to improve comprehensive and routine evaluation of Earth system models (ESMs) participating in the Coupled Model Intercomparison Project (CMIP). It has undergone rapid development since the first release in 2016 and is now a well-tested tool that provides end-to-end provenance tracking to ensure reproducibility. It consists of (1) an easy-to-install, well-documented Python package providing the core functionalities (ESMValCore) that performs common preprocessing operations and (2) a diagnostic part that includes tailored diagnostics and performance metrics for specific scientific applications. Here we describe large-scale diagnostics of the second major release of the tool that supports the evaluation of ESMs participating in CMIP Phase 6 (CMIP6). ESMValTool v2.0 includes a large collection of diagnostics and performance metrics for atmospheric, oceanic, and terrestrial variables for the mean state, trends, and variability. ESMValTool v2.0 also successfully reproduces figures from the evaluation and projections chapters of the Intergovernmental Panel on Climate Change (IPCC) Fifth Assessment Report (AR5) and incorporates updates from targeted analysis packages, such as the NCAR Climate Variability Diagnostics Package for the evaluation of modes of variability, the Thermodynamic Diagnostic Tool (TheDiaTo) to evaluate the energetics of the climate system, as well as parts of AutoAssess that contains a mix of top–down performance metrics. The tool has been fully integrated into the Earth System Grid Federation (ESGF) infrastructure at the Deutsches Klimarechenzentrum (DKRZ) to provide evaluation results from CMIP6 model simulations shortly after the output is published to the CMIP archive. A result browser has been implemented that enables advanced monitoring of the evaluation results by a broad user community at much faster timescales than what was possible in CMIP5.

scholarly journals On inclusion of water resource management in Earth System models – Part 1: Problem definition and representation of water demand

2014 ◽  
Vol 11 (7) ◽  
pp. 8239-8298 ◽  
Author(s):  
A. Nazemi ◽  
H. S. Wheater
Keyword(s):  
Resource Management ◽  
Water Resource ◽  
Water Demand ◽  
Water Resource Management ◽  
Large Scale ◽  
Earth System ◽  
Water Demands ◽  
The Earth ◽  
Scale Models ◽  
Earth System Models

Abstract. Human activities have caused various changes in the Earth System, and hence, the interconnections between humans and the Earth System should be recognized and reflected in models that simulate the Earth System processes. One key anthropogenic activity is water resource management that determines the dynamics of human–water interactions in time and space. There are various reasons to include water resource management in Earth System models. First, the extent of human water requirements is increasing rapidly at the global scale and it is crucial to analyze the possible imbalance between water demands and supply under various scenarios of climate change and across various temporal and spatial scales. Second, recent observations show that human–water interactions, manifested through water resource management, can substantially alter the terrestrial water cycle, affect land-atmospheric feedbacks and may further interact with climate and contribute to sea-level change. Here, we divide the water resource management into two interdependent elements, related to water demand as well as water supply and allocation. In this paper, we survey the current literature on how various water demands have been included in large-scale models, including Land Surface Schemes and Global Hydrological Models. The available algorithms are classified based on the type of demand, mode of simulation and underlying modeling assumptions. We discuss the pros and cons of available algorithms, address various sources of uncertainty and highlight limitations in current applications. We conclude that current capability of large-scale models in terms of representing human water demands is rather limited, particularly with respect to future projections and online simulations. We argue that current limitations in simulating various human demands and their impact on the Earth System are mainly due to the uncertainties in data support, demand algorithms and large-scale models. To fill these gaps, the available models, algorithms and data for representing various water demands should be systematically tested, intercompared and improved and human water demands should be considered in conjunction with water supply and allocation, particularly in the face of water scarcity and unknown future climate.

scholarly journals Applying the concept of "energy return on investment" to desert greening of the Sahara/Sahel using a global climate model

2014 ◽  
Vol 5 (1) ◽  
pp. 43-53 ◽  
Author(s):  
S. P. K. Bowring ◽  
L. M. Miller ◽  
L. Ganzeveld ◽  
A. Kleidon
Keyword(s):  
Return On Investment ◽  
Energy Input ◽  
Large Scale ◽  
Climate Model ◽  
Global Climate ◽  
Global Climate Model ◽  
Earth System ◽  
Energy Return On Investment ◽  
The Earth ◽  
Sahel Region

Abstract. Altering the large-scale dynamics of the Earth system through continual and deliberate human intervention now seems possible. In doing so, one should question the energetic sustainability of such interventions. Here, from the basis that a region might be unnaturally vegetated by employing technological means, we apply the metric of "energy return on investment" (EROI) to benchmark the energetic sustainability of such a scenario. We do this by applying EROI to a series of global climate model simulations where the entire Sahara/Sahel region is irrigated with increased rates of desalinated water to produce biomass. The energy content of this biomass is greater than the energy input rate for a minimum irrigation rate of about 200 mm yr−1 in the winter and 500 mm yr−1 in the summer, thereby yielding an EROI ratio >1 : 1, expressing energetic sustainability. Quantified annually, the EROI was >1 : 1 for irrigation rates more than 500 mm yr−1, progressively increasing to a maximum of 1.8 : 1 with 900 mm yr−1, and then decreasing with further increases in the irrigation rate. Including the precipitation feedback arising from changes in moisture recycling within the study region approximately doubles these EROI ratios. This overall result varies spatially and temporally, so while the entire Sahara/Sahel region is irrigated equally, the western coastal region from June to August had the highest EROI. Other factors would complicate such a large-scale modification of the Earth system, but this sensitivity study concludes that with a required energy input, desert greening may be energetically sustainable. More specifically, we have shown how this type of EROI analysis could be applied as a metric to assess a diverse range of human alterations to, and interventions within, the Earth system.

scholarly journals Steno and the rock cycle

Substantia ◽  
2021 ◽  
pp. 89-97
Author(s):  
Alan H. Cutler
Keyword(s):  
Physical Properties ◽  
19Th Century ◽  
Modern Concept ◽  
Earth System ◽  
Rock Types ◽  
The Earth ◽  
Geological Evolution ◽  
Geological Work ◽  
The 19Th Century ◽  
Geologic Processes

Geologists categorize the basic types of rock according to their origin – igneous, sedimentary, or metamorphic -- rather than by their physical properties. This is expressed dynamically by the fundamental concept of the rock cycle, which describes how the basic rock types are derived from one another within the Earth system as a result of ongoing cyclic geologic processes.  In Nicolaus Steno’s published geological work, particularly De Solido, he takes a similar approach, outlining how a substance can be examined “to disclose the place and manner of its production”. Steno also recognizes the roles of erosion, transport, and deposition in the production of sedimentary strata from pre-existing earth materials. His description and diagrams of the geological evolution of Tuscany also show a clear cyclicity of process. While the modern concept of the rock cycle did not emerge until the 19th century, Steno’s work contains key elements of this important concept.

scholarly journals Applications and Challenges of GRACE and GRACE Follow-On Satellite Gravimetry

2022 ◽  
Author(s):  
Jianli Chen ◽  
Anny Cazenave ◽  
Christoph Dahle ◽  
William Llovel ◽  
Isabelle Panet ◽  
...  
Keyword(s):  
Solid Earth ◽  
Large Scale ◽  
Time Variable ◽  
Global Ocean ◽  
Earth System ◽  
Satellite Gravimetry ◽  
Time Variable Gravity ◽  
The Earth ◽  
Gravity Measurements ◽  
Variable Gravity

AbstractTime-variable gravity measurements from the Gravity Recovery and Climate Experiment (GRACE) and GRACE Follow-On (GRACE-FO) missions have opened up a new avenue of opportunities for studying large-scale mass redistribution and transport in the Earth system. Over the past 19 years, GRACE/GRACE-FO time-variable gravity measurements have been widely used to study mass variations in different components of the Earth system, including the hydrosphere, ocean, cryosphere, and solid Earth, and significantly improved our understanding of long-term variability of the climate system. We carry out a comprehensive review of GRACE/GRACE-FO satellite gravimetry, time-variable gravity fields, data processing methods, and major applications in several different fields, including terrestrial water storage change, global ocean mass variation, ice sheets and glaciers mass balance, and deformation of the solid Earth. We discuss in detail several major challenges we need to face when using GRACE/GRACE-FO time-variable gravity measurements to study mass changes, and how we should address them. We also discuss the potential of satellite gravimetry in detecting gravitational changes that are believed to originate from the deep Earth. The extended record of GRACE/GRACE-FO gravity series, with expected continuous improvements in the coming years, will lead to a broader range of applications and improve our understanding of both climate change and the Earth system.

Time to wake up to climate change and the accelerating phosphorus cycle

2020 ◽  
Author(s):  
Phil Haygarth
Keyword(s):  
Climate Change ◽  
Large Scale ◽  
Rock Phosphate ◽  
Agricultural Landscapes ◽  
Earth System ◽  
Phosphorus Cycle ◽  
The Earth ◽  
Related Quality ◽  
Quality Water ◽  
Phosphorus Loads

<p>We urgently need to wake up to the role that climate change will be playing in the phosphorus cycle.  The paper will attempt to address the complexities, controversies and uncertainties of estimating the effects that climate change is having on the phosphorus cycle.  Citing an example from three UK catchments, the effect of climate change on average winter phosphorus loads is predicted to increase by up to 30% by the 2050s, and these effects will only be off-set by large-scale agricultural changes (e.g. a 20–80% reduction in phosphorus inputs).  Achieving phosphorus-related quality water in diverse and productive agricultural landscapes under a changing climate is going to be a massive challenge.  It is less than a century since we started mining rock phosphate, but in the context of a 4.5-billion-year-old earth and the acceleration due to climate, we are living through a switching point for phosphorus in the earth system.</p>

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