Long-range proton–carbon coupling constants for the determination of the stereochemical structure of organic compounds.
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A new methods for elucidating stereochemistry of organic compounds was developed on the basis of long-range proton–carbon coupling constants (2,3JC,H) and interpreting spin-coupling constants (3JH,H). Reaction of compound containing pyrin ring with nucleophile reagent was done to open the ring. HSQC-TOCSY experiments one of the new NMR spectroscopy method used to measure this values of spin-coupling constants and elucidating the stereochemistry of the product.
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1994 ◽
Vol 49
(10)
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pp. 1407-1409
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1985 ◽
Vol 34
(11)
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pp. 2278-2281
2003 ◽
Vol 41
(6)
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pp. 431-434
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1976 ◽
Vol 61
(3)
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pp. 479-480
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1979 ◽
Vol 101
(15)
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pp. 4058-4059
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1976 ◽
Vol 54
(20)
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pp. 3216-3223
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