scholarly journals Synthesis and Purification of Carbon Nanotubes

2021 ◽  
Author(s):  
Syed Awais Rouf ◽  
Zahid Usman ◽  
Hafiz Tariq Masood ◽  
Abdul Mannan Majeed ◽  
Mudassira Sarwar ◽  
...  

In this chapter, we will evaluate the synthesis and purification of carbon nanotubes. Carbon nanotubes are cylindrical molecules that consists of graphene (rolled up of a single-layer carbon atom). A wide variety of synthesis techniques such as arc discharge synthesis, laser ablation of graphite/laser vaporization synthesis method, chemical vapor deposition (CVD), high pressure carbon monoxide synthesis and flame synthesis techniques, have been implemented to grow single and multi-walled carbon nanotubes for technological applications. All of the above methods exploit transition metals, like iron, cobalt, and nickel, as a catalyst. There are number of methods (filtering, chromatography and centrifugation) used to purify the carbon nanotubes, but the degree of purity remained questionable in these methods. In order to enhance the purification extent, alternate techniques such as Gas phase purification, Liquid phase purification and Purification by Intercalation are introduced. Here we will discuss the advantages and disadvantages of these purification routes. It will help researchers in selecting appropriate and effective method for synthesis and purification of carbon nanotubes.

Author(s):  
Masahiro Tomoda ◽  
Teppei Kawahara ◽  
Yohei Tasaki ◽  
Yasuyuki Takata ◽  
Makoto Hirasawa ◽  
...  

In this study, carbon nanotubes (CNTs) were synthesized from size-classified catalyst metal nanoparticles to observe the effect of the nanoparticles’ diameter on the diameter of the CNTs. The nanoparticles were generated by laser vaporization and classified by a differential mobility analyzer, which sorts them by diameter according to differences in electrical mobility. After classification, the nanoparticles were collected on a Si substrate. CNTs were synthesized from these catalyst metal nanoparticles by using chemical vapor deposition. This experiment synthesized mainly multi-walled carbon nanotubes (MWNTs), with a small amount of single-walled carbon nanotubes (SWNTs). The reason is thought to be that the particles’ diameters were appropriate for MWNT synthesis.


2003 ◽  
Vol 778 ◽  
Author(s):  
Lata Muthuswami ◽  
P. M. Ajayan ◽  
R. E. Geer

AbstractNanomechanical mapping of individual multi-walled carbon nanotubes (MWNTs) has been undertaken to investigate intra-tube variations of mechanical response. Ultrasonic force microscopy has been used to measure the relative axial and radial variations of contact stiffness of individual MWNTs synthesized using chemical vapor deposition (CVD) and arc-discharge (AD) techniques. For CVD-based MWNTs the contact stiffness of the tube was seen to vary strongly across volume defects (axial variation of the tube radius) and is assumed to result from the high crystalline defect density associated with such radial variations. These observations support recent experimental data of effective Young's modulus inferred from electrostatically-induced nanotube vibration amplitudes.


2021 ◽  
pp. 002199832199945
Author(s):  
Dinesh Kumar ◽  
Suneev Anil Bansal ◽  
Navin Kumar ◽  
Prashant Jindal

The present work has been aimed to synthesize Polyurethane (PU)/Multi-Walled Carbon Nanotubes (MWCNTs) composite using a two-step method to enhance mechanical properties. In the first step, films (0.2 mm thickness) have been synthesized using a solution mixing method to disperse MWCNTs in the PU matrix. In the second step, thin films of uniformly dispersed MWCNTs in the PU matrix have been compression molded to synthesize PU/MWCNTs composite required for real mechanical applications. The two-step method has the advantages of solution mixing as well as compression molding method. The results of quasi-static nanoindentation tests indicated that in comparison to pure PU, elastic modulus and hardness have been enhanced by 124% and 53% respectively for 10 wt% PU/MWCNTs composite. Fracture resistance of PU/MWCNTs composites, with 7 wt% of MWCNTs, has been enhanced by 52% as compared to pure PU. To understand bulk behavior, nanoindentation results have been cross-verified with compression testing. Results of compressive testing shown that the modulus of composite material has been significantly improved under the influence of the increasing composition of MWCNTs. A noticeable improvement of 52% has been observed in compressive modulus of 10 wt% composite in equivalence to pure PU. The overall improvement in mechanical behavior has been attributed to the uniform dispersion of MWCNTs in the PU matrix by the two-step synthesis method.


2008 ◽  
Vol 14 (S2) ◽  
pp. 304-305
Author(s):  
M Ellis ◽  
T Jutarosaga ◽  
S Smith ◽  
Y Wei ◽  
S Seraphin

Extended abstract of a paper presented at Microscopy and Microanalysis 2008 in Albuquerque, New Mexico, USA, August 3 – August 7, 2008


2013 ◽  
Vol 667 ◽  
pp. 534-537
Author(s):  
M.Z. Nuraini ◽  
S. Aishah ◽  
S.F. Nik ◽  
Mohamad Rusop

Fermented tapioca which is a new starting material was used as a carbon precursor. Carbon nanotubes (CNTs) were deposited on silicon wafer (Si) by Thermal Chemical Vapor Deposition (TCVD). The gas flow of Argon (Ar) was constant at 70 bubbles per minute and 20 minutes of deposition time. Before the deposition process, silicon was coated with Nickel using spin coater. Various parameters such as amount of inoculums have been studied. Chemical functional groups of carbon nanotubes were characterized using FT-IR Spectroscopy. The FT-IR result shows peaks attributed to multi–walled carbon nanotubes (MWCNT) vibration modes.


Carbon ◽  
2012 ◽  
Vol 50 (12) ◽  
pp. 4588-4595 ◽  
Author(s):  
Yoong Ahm Kim ◽  
Hiroyuki Muramatsu ◽  
Takuya Hayashi ◽  
Morinobu Endo

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