scholarly journals Electrochemical Property of Particle-size Controlled H2Ti12O25 as a Negative Electrode Material for Lithium-ion Battery

2015 ◽  
Vol 83 (10) ◽  
pp. 834-836 ◽  
Author(s):  
Hideaki NAGAI ◽  
Kunimitsu KATAOKA ◽  
Junji AKIMOTO ◽  
Tomoyuki SOTOKAWA ◽  
Yoshimasa KUMASHIRO
2014 ◽  
Vol 492 ◽  
pp. 370-374
Author(s):  
Xiao Zhen Liu ◽  
Guang Jian Lu ◽  
Xiao Zhou Liu ◽  
Jie Chen ◽  
Han Zhang Xiao

Pr doped SnO2 particles as negative electrode material of lithium-ion battery are synthesized by the coprecipitation method with SnCl4·5H2O and Pr2O3 as raw materials. The structure of the SnO2 particles and Pr doped SnO2 particles are investigated respectively by XRD analysis. Doping is achieved well by coprecipitation method and is recognized as replacement doping or caulking doping. Electrochemical properties of the SnO2 particles and Pr doped SnO2 particles are tested by charge-discharge and cycle voltammogram experimentation, respectively. The initial specific discharge capacity of Pr doped SnO2 the negative electrode materials is 676.3mAh/g. After 20 cycles, the capacity retention ratio is 90.5%. The reversible capacity of Pr doped SnO2 negative electrode material higher than the reversible capacity of SnO2 negative electrode material. Pr doped SnO2 particles has good lithiumion intercalation/deintercalation performance.


RSC Advances ◽  
2016 ◽  
Vol 6 (54) ◽  
pp. 48620-48629 ◽  
Author(s):  
Tsan-Yao Chen ◽  
Yu-Ting Liu ◽  
Ping-Ching Wu ◽  
Chih-Wei Hu ◽  
Po-Wei Yang ◽  
...  

Sn dopants undergo restructuring into Ti sites of TiO2 upon lithiation reaction. These Sn dopants attract Li to form local SnLix alloys, which sufficiently increase the capacity of Sn-substituted TiO2 as a negative electrode material.


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