scholarly journals "APPLICATION OF CENTRAL COMPOSITE DESIGN OPTIMIZATION TECHNIQUE FOR DETERMINATION OF COPPER IN FRUIT AND VEGETABLE SAMPLES WITH ADSORPTIVE STRIPPING VOLTAMMETRY IN THE PRESENCE OF CALCEIN "

2018 ◽  
Vol 17 (2) ◽  
pp. 245-255 ◽  
Author(s):  
S. A. R. Shahamirifard ◽  
M. Ghaedi ◽  
M. Montazerozohori ◽  
A. Masoudiasl

In this work, the use of carbon dots (CDs) as a complexing agent and sensitizer in a polymeric matrix for determination of copper(ii) by UV-vis spectroscopy is reported for the first time.


2018 ◽  
Vol 42 (4) ◽  
pp. 2590-2604 ◽  
Author(s):  
Seyed Alireza Shahamirifard ◽  
Mehrorang Ghaedi

A selective, accurate and highly sensitive optical chemical sensor (optode) for the simultaneous determination of copper(ii) and cobalt(ii) without any prior separation or purification ion sensing was developed.


2015 ◽  
Vol 4 (2) ◽  
pp. 55
Author(s):  
Deswati ◽  
Hamzar Suyani ◽  
Bustanul Arifin ◽  
Imelda ◽  
Yunita Salamah

 ABSTRACT The research about determination of Cu(II) by adsorptive stripping voltammetry (AdSV) was conducted. AdSV method was applied to the determination of copper in ultra trace concentration. The parameters of ligand, accumulation potential, accumulation time, pH and ligand concentration was studied. Calcon was found as complexing agent that give the highest peak current. The optimum condition are accumulation potential -0,7 V, accumulation time 60 s, pH 10, and calcon concentration 0.12 mM. The relative standar deviation (n=8) at 10 µg/L standard concentration were obtained 4,27 %. This method was applied to determination of Cu(II) in sample from Batang Air Dingin, Lubuk Minturun and Muara Padang. The sample concentration were 4,778 µg/L and 5,189 µg/L for Batang Air Dingin and Muara Padang, respectively. The recovery of this method was studied for sample from Muara Padang and 98,31 % was obtained. Key words :   Adsorptive, Stripping, Voltammetry, Calcon and Copper    


2007 ◽  
Vol 19 (15) ◽  
pp. 1609-1615 ◽  
Author(s):  
Mohammad Bagher Gholivand ◽  
Ali Sohrabi ◽  
Shahriar Abbasi

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