The Effect of Immersion Time on the Electrochemical Characterization of Additively Manufactured 316L Stainless Steel Exposed to Artificial Seawater

2018 ◽  
Author(s):  
B. Shaw ◽  
T. Palmer ◽  
M. Kadhi ◽  
E. Sikora ◽  
D. Wang
Keyword(s):  
Stainless Steel ◽  
Immersion Time ◽  
316L Stainless Steel ◽  
Electrochemical Characterization ◽  
Artificial Seawater

scholarly journals Advanced Characterization of Additively Manufactured 316L Stainless Steel for Nuclear Applications

2021 ◽  
Vol 27 (S1) ◽  
pp. 2160-2161
Author(s):  
Lingfeng He ◽  
Laura Hawkins ◽  
Jingfan Yang ◽  
Xiang Liu ◽  
Miao Song ◽  
...  
Keyword(s):  
Stainless Steel ◽  
316L Stainless Steel ◽  
Advanced Characterization ◽  
Nuclear Applications

Passivation behavior of 316L stainless steel in artificial seawater: effects of pH and dissolved oxygen

2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Zhaopeng Wang ◽  
Yi Wang ◽  
Bowei Zhang ◽  
Zhan Zhang ◽  
Kui Xiao ◽  
...  
Keyword(s):  
Stainless Steel ◽  
Dissolved Oxygen ◽  
Passive Film ◽  
Polarization Resistance ◽  
316L Stainless Steel ◽  
Ph Value ◽  
Artificial Seawater ◽  
Compositional Variation ◽  
Content Type ◽  
Semiconductor Properties

Purpose The purpose of this paper is to investigate the influence of the potential of hydrogen (pH) and dissolved oxygen in artificial seawater on the passivation behavior of 316L stainless steel. Design/methodology/approach The corrosion behavior was studied by using electrochemical measurements such as electrochemical impedance spectroscopy and polarization curve. The passive films were characterized with X-ray photoelectron spectroscopy. Findings The polarization resistance of the passive film decreases as the pH value drops ascribed to the formation of much more point defects. The donor carrier concentration (ND) in the passive film formed in the deaerated condition is lower than that in aerated conditions. Nevertheless, this phenomenon is the opposite when the pH value is 1 due to the significant decrease of Fe oxides/hydroxides coupled with the stable content of Cr oxides/hydroxides species. In addition, the compositional variation of the passive film also leads to the changes of its semiconductor properties from N-type to bipolar type. Originality/value This paper shows the variation of polarization resistance, corrosion potential, passive film composition and semiconductor properties with the pH value and dissolved oxygen. The results can serve as references to the further study on crevice corrosion of 316L in seawater.

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