Synthesis of Zirconia Micro-Nanoflakes with Highly Exposed (001) Facets and Their Crystal Growth

This study reports a novel preparation method of zirconia micro-nanoflakes with high (001) facets that is generated through a hydrolysis reaction of the fluozirconic acid (H2ZrF6). Zirconia micro-nanoflakes synthesized at varied conditions were analyzed by the SEM, EDS, μ-XRD, and Raman spectroscopy to characterize the morphology and probe into the crystal growth mechanism. The synthesized zirconia crystals in the form of elliptical micro-nanoflakes or irregular nanoflakes generally display the highly exposed (001) facets with a thickness of 1–100 nm and a length of 0.1–2.0 μm. As the temperature and initial solution concentration increased, the particle sizes of the synthesized zirconia micro-nanoflakes became more uniform and the thicknesses of the (001) facets became larger, suggesting that the synthesized zirconia crystals grow along the (001) facets and mostly along the c-axis direction. This is confirmed by the data from the μ-XRD patterns. The results also demonstrate that an oriented attachment-based growth occurring in a fluorine-rich solution environment was involved in the aggregation and coarsening of zirconia micro-nanoflakes. Meanwhile, synthesized zirconia micro-nanoflakes also evolved from a mixture of monoclinic and tetragonal systems to a pure monoclinic system (i.e., baddeleyite) with the temperature increasing, suggesting a key role of temperature regarding zirconia’s growth.

A Near-Infrared Light Triggered Composite Nanoplatform for Synergetic Therapy and Multimodal Tumor Imaging

Transition-metal chalcogenide compounds with facile preparation and multifunctional elements act as ideal photothermal agents for cancer theranostics. This work synthesizes Cu7.2S4/5MoS2 composite nanoflowers and investigates the crystal growth mechanism to optimize the synthesis strategy and obtain excellent photothermal therapy agents. Cu7.2S4/5MoS2 exhibits a high photothermal conversion efficiency of 58.7% and acts as a theranostic nanoplatform and demonstrated an effective photothermal–chemodynamic–photodynamic synergetic therapeutic effect in both in vitro and in vivo tests. Moreover, Cu7.2S4/5MoS2 shows strong photoacoustic signal amplitudes and computed tomographic contrast enhancement in vivo. These results suggest a potential application of Cu7.2S4/5MoS2 composite nanoflowers as photo/H2O2-responsive therapeutic agents against tumors.

Optical Temperature Sensing of YbNbO4:Er3+ Phosphors Synthesized by Hydrothermal Method

The novel YbNbO4:Er3+ phosphors were firstly synthesized through the hydrothermal method by adding LiOH·H2O as flux in the H2O/EG system. YbNbO4:Er3+ phosphors showed the agglomerated irregular polygons coexisting with some tiny grains. XRD and Raman spectra were measured to understand the phase structure and the crystal growth mechanism of YbNbO4:Er3+ phosphors. The upconversion (UC) emission spectra, the pump power dependency and UC mechanism were studied under 980 nm excitation. Based on the fluorescence intensity ratio technique, YbNbO4:Er3+ exhibited the maximum sensor sensitivity of 0.00712 K−1 at 220 K, providing a promising application in optical low-temperature sensors.

Reversed Crystal Growth of Metal Organic Framework MIL-68(In)

An investigation of the crystal growth of metal organic framework MIL-68(In) under solvothermal conditions revealed a non-classical reversed crystal growth mechanism via a route of nanorods – orientated aggregation into...

The Effect of Microwave on the Crystallization Behavior of CMAS System Glass-Ceramics

The microwave sintering of glass-ceramics, non-thermal microwave effect, and crystal growth mechanism remain important challenges in materials science. In this study, we focus on developing approaches to affect crystal growth in the glass network of glass-ceramics by microwave heating, rather than performing a single study on the crystal structure and type. Raman spectroscopy is used to detect the structure of the glass network. We demonstrated that the non-thermal microwave effect promoted the diffusion of metal ions, which promoted the aggregation and precipitation of metal ions in the glass network to form crystals. The samples produced by microwave heating contain more non-bridging oxygen bonds than conventional sintered samples; therefore, the non-thermal microwave effect has a depolymerization effect on the glass network of the sample. Under the influence of microwave field, many metal ions precipitate, which precipitates many crystal nuclei. In addition, many active metal ions are captured during the crystal nucleus growth, which shortens the sintering process of glass-ceramics.

Synthesis, Characterization and Mechanism Study of Green Aragonite Crystals from Waste Biomaterials as Calcium Supplement

In present work, environmentally benign green aragonite crystals were synthesized from waste chicken eggshells and bivalve seashells through a simple and low-cost wet carbonation method. This method involves a constant stirring of calcium oxide slurry and magnesium chloride suspension in aqueous solution with constraint carbon dioxide injection at 80 °C. The physicochemical properties of the synthesized aragonite were further compared with the aragonite synthesized from commercial calcium oxide. The morphological analysis, such as acicular shape and optimum aspect ratio (~21), were confirmed by scanning electron microscopy. The average crystal size (10–30 µm) and specific surface area (2–18 m2 g−1) were determined by particle size and Brunauer–Emmett–Teller analysis, respectively. Moreover, a schematic crystal growth mechanism was proposed to demonstrate the genesis and progression of aragonite crystal. Green aragonite can bridge the void for numerous applications and holds the potential for the commercial-scale synthesis with eggshells and bivalve seashells as low-cost precursors.

Quasi-2D perovskite emitters: a boon for efficient blue light-emitting diodes

A deeper understanding of the quasi-2D perovskites crystal growth mechanism, orientation, phase purity, blocking halide ion migration and phase segregation can possibly open up a new paradigm for the development of high-performance blue PeLEDs.