Hydrophilic surface-assisted thermoresponsive smart window based on lower critical solution temperature type phase separation

A polyelectrolyte-containing copolymer with a CO2/N2-switchable cloud point, resulting from the gas-induced alternation of hydrophilicity, was prepared.

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Unexpected LCST-type phase behaviour of a poly(vinyl thiazolium) polymer in acetone

RSC Advances ◽

10.1039/c6ra09023k ◽

2016 ◽

Vol 6 (62) ◽

pp. 57117-57121 ◽

Cited By ~ 5

Author(s):

Konrad Grygiel ◽

Weiyi Zhang ◽

Christophe Detrembleur ◽

Jiayin Yuan

Keyword(s):

Phase Transition ◽

Lower Critical Solution Temperature ◽

Acetone Solution ◽

Phase Behaviour ◽

Solution Temperature ◽

Critical Solution Temperature ◽

Type Phase

A poly(vinyl thiazolium) polymer in acetone solution exhibited an unexpected lower critical solution temperature (LCST)-type phase transition.

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Calculation of shear influences on the phase separation behavior of polymer solutions in the region of their lower critical solution temperature. Creation of closed miscibility gaps

Macromolecules ◽

10.1021/ma00009a018 ◽

1991 ◽

Vol 24 (9) ◽

pp. 2236-2239 ◽

Cited By ~ 15

Author(s):

R. Horst ◽

B. A. Wolf

Keyword(s):

Phase Separation ◽

Lower Critical Solution Temperature ◽

Polymer Solutions ◽

Solution Temperature ◽

Critical Solution Temperature ◽

Phase Separation Behavior ◽

Miscibility Gaps ◽

Separation Behavior

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Unified model of association-induced lower critical solution temperature phase separation and its application to solutions of telechelic poly(ethylene oxide) and of telechelic poly(N-isopropylacrylamide) in water

The Journal of Chemical Physics ◽

10.1063/1.2400230 ◽

2006 ◽

Vol 125 (24) ◽

pp. 244902 ◽

Cited By ~ 11

Author(s):

Yukinori Okada ◽

Fumihiko Tanaka ◽

Piotr Kujawa ◽

Françoise M. Winnik

Keyword(s):

Phase Separation ◽

Ethylene Oxide ◽

Lower Critical Solution Temperature ◽

Unified Model ◽

Solution Temperature ◽

Temperature Phase ◽

Critical Solution Temperature ◽

Poly Ethylene Oxide ◽

Poly Ethylene

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Cationic Poly(ionic liquid) with Tunable Lower Critical Solution Temperature-Type Phase Transition

ACS Macro Letters ◽

10.1021/mz400155r ◽

2013 ◽

Vol 2 (5) ◽

pp. 456-459 ◽

Cited By ~ 93

Author(s):

Yongjun Men ◽

Helmut Schlaad ◽

Jiayin Yuan

Keyword(s):

Phase Transition ◽

Ionic Liquid ◽

Lower Critical Solution Temperature ◽

Solution Temperature ◽

Critical Solution Temperature ◽

Type Phase ◽

Poly Ionic Liquid

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Key Factors to Prepare Polyelectrolytes Showing Temperature-Sensitive Lower Critical Solution Temperature-type Phase Transitions in Water

Australian Journal of Chemistry ◽

10.1071/ch11378 ◽

2012 ◽

Vol 65 (1) ◽

pp. 91 ◽

Cited By ~ 63

Author(s):

Yuki Kohno ◽

Hiroyuki Ohno

Keyword(s):

Phase Transition ◽

Lower Critical Solution Temperature ◽

Alkyl Chain ◽

Alkyl Chain Length ◽

Phase Behaviour ◽

Solution Temperature ◽

Temperature Sensitive ◽

Key Factors ◽

Critical Solution Temperature ◽

Type Phase

Tetrabutylphosphonium styrenesulfonate and its homopolymer showed a lower critical solution temperature-type phase transition in water. As the hydrophobicity of these monomeric and polymeric salts affects phase behaviour, the phase transition temperature of the polyelectrolyte was changed by the introduction of monomers having different alkyl chain length on the phosphonium cations.

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