scholarly journals Dispersant Effectiveness on Heavy Fuel Oil and Crude Oil in New Zealand

2003 ◽  
Vol 2003 (1) ◽  
pp. 509-513 ◽  
Author(s):  
Leigh Stevens ◽  
Julian Roberts

ABSTRACT The New Zealand (NZ) Maritime Safety Authority (MSA) recently identified seven crude oils and nine IFO-380 heavy fuel oils used or transported in NZ waters that had a high relative risk of being spilt. To determine the relative effectiveness of dispersants stocked by the MSA (Corexit 9527, Slickgone LTSW, Gamlen OSD LT, and Tergo R40) on the oils, effectiveness was tested using the Warren Spring Laboratory (WSL) LR 448 protocol. All testing was on fresh (unweathered) oil at 15°C, at a dispersant to oil ratio (DOR) of 1:25. Effective dispersion was considered to be equivalent to a WSL test result of ≥15%, as proposed in the work of Lunel & Davies (1996). Overall, the seven crude oils tested could be dispersed with MSA stocked dispersants; Corexit 9527 and Slickgone LTSW dispersing the greatest volume of oil, while Gamlen OSD LT and Tergo R40 were effective on the widest range of oils. For the nine IFO-380 heavy fuel oils, dispersant effectiveness was generally lower than for crude oils, and two oils could not be dispersed. Corexit 9527 was the most effective dispersant and worked on the widest range of fuel oils. Slickgone LTSW, Gamlen OSD LT, and Tergo R40 were less effective and worked on a smaller range of fuel oils. To assess whether other dispersants not currently stocked by the MSA offered a significantly improved capacity, two high performance products (Corexit 9500 and Slickgone EW) were tested on the same oils, and across a range of temperatures and DORs. Laboratory results showed that Corexit 9500 and Slickgone EW were significantly more effective on both the crude oils and the IFO-380 heavy fuel oils than existing MSA dispersant stocks. While the results of this study provide a good indication of the relative effectiveness of different dispersants, they do not indicate absolute levels of effectiveness, and field experiments are needed to define how laboratory effectiveness translates to effectiveness in the field.

1990 ◽  
Vol 112 (3) ◽  
pp. 324-330 ◽  
Author(s):  
R. S. G. Baert

This paper reports on an experimental study of the autoignition behavior of several heavy fuel oils in a large constant-volume combustion chamber with single-shot injection. In the experiments the pressure and the temperature of the air in the combustion chamber before fuel injection varied between 30 and 70 bar and between 730 and 920 K. Illumination delay and pressure delay values have been correlated with these pressures and temperatures. It is shown that for all but one of the fuels examined, ignition delay ranking changes little with the choice of ignition delay definition, but more with the pressure and temperature conditions in the combustion chamber. The usefulness of the Calculated Carbon Aromaticity Index is discussed.


2014 ◽  
Vol 2014 (1) ◽  
pp. 776-782
Author(s):  
Ganesh L. Ghurye ◽  
Tim J. Nedwed ◽  
Amy C. Tidwell ◽  
Gerard P. Canevari

ABSTRACT This study evaluated the effectiveness of three dispersants in simulated seawater on five different fuel oils (both intermediate fuel oils (IFOs) and heavy fuel oils (HFOs)) with viscosities ranging from 1,079 to 6,615 cSt and densities ranging from 0.995 to 0.998 g/cc. The three dispersants were COREXIT® 9500 dispersant, a dispersant under development by ExxonMobil – ED-6™ gel dispersant, and FINASOL™ OSR 52 dispersant. Testing was done at two dispersant-to-oil ratios (DOR) – 1:20 and 1:10. All three dispersants were effective (70%+ dispersant effectiveness (DE)) for fuel oils with a viscosity less than 2,000 cSt - IFOs 180 and 380. The dispersants were less effective (16 to 58% DE) for the higher viscosity oils (ranging in viscosity from 4,258 to 6,615 cSt). Increasing the amount of dispersant from a DOR of 1:20 to 1:10 significantly improved DE. For example, the DE of the two HFOs studied increased from less than 42% to greater than 56% using COREXIT 9500™ dispersant. The results of our bench-scale study indicate that dispersants can disperse heavy fuel oils and, therefore, could be a response option for spills of these products in a marine environment.


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