scholarly journals Study of Process Parameters for Making Biodegradable Linear Low Density Polyethylene in Natural Weathering Conditions

2017 ◽  
Vol 10 (05) ◽  
pp. 79-90
Author(s):  
Dr. Ruhul Amin ◽  
Dr. Dil Afroza Begum ◽  
Dr. Abdul Gafur
2013 ◽  
Vol 33 (7) ◽  
pp. 579-588 ◽  
Author(s):  
S.T. Sam ◽  
H. Ismail ◽  
H.P.S. Abdul Khalil

Abstract In the present study, linear low density polyethylene (LLDPE)/soya powder blends were compatibilized with epoxidized natural rubber (ENR 50) and exposed to natural weathering. The exposure period for the blends was 1 year. It was found that the degradability of the compatibilized blends was higher than that of uncompatibilized blends. Fourier transform infrared (FTIR) spectra, the tensile test, scanning electron microscopy (SEM), and differential scanning calorimetry (DSC) were applied to analyze the degradability of the blends. IR spectra showed that the carbonyl index (CI) of the blends increased as a function of exposure period and soya powder content. The compatibilized blends gave higher carbonyl indices. The retention tensile strength and elongation at break (Eb) of the compatibilized blends after weathering was generally lower than for the uncompatibilized blends. The increase of crystallinity also indicated a reduction of the amorphous portion after degradation. The higher crystallinity in compatibilized blends further confirms the higher degradability of ENR 50 compatibilized blends. The weight loss and molecular weight change indicated that the incorporation of ENR 50 into LLDPE/soya powder blends can enhance the degradability of the blends upon outdoor exposure.


Polymers ◽  
2021 ◽  
Vol 13 (10) ◽  
pp. 1537
Author(s):  
Luděk Hynčík ◽  
Petra Kochová ◽  
Jan Špička ◽  
Tomasz Bońkowski ◽  
Robert Cimrman ◽  
...  

Current industrial trends bring new challenges in energy absorbing systems. Polymer materials as the traditional packaging materials seem to be promising due to their low weight, structure, and production price. Based on the review, the linear low-density polyethylene (LLDPE) material was identified as the most promising material for absorbing impact energy. The current paper addresses the identification of the material parameters and the development of a constitutive material model to be used in future designs by virtual prototyping. The paper deals with the experimental measurement of the stress-strain relations of linear low-density polyethylene under static and dynamic loading. The quasi-static measurement was realized in two perpendicular principal directions and was supplemented by a test measurement in the 45° direction, i.e., exactly between the principal directions. The quasi-static stress-strain curves were analyzed as an initial step for dynamic strain rate-dependent material behavior. The dynamic response was tested in a drop tower using a spherical impactor hitting a flat material multi-layered specimen at two different energy levels. The strain rate-dependent material model was identified by optimizing the static material response obtained in the dynamic experiments. The material model was validated by the virtual reconstruction of the experiments and by comparing the numerical results to the experimental ones.


2015 ◽  
Vol 37 (11) ◽  
pp. 3167-3174 ◽  
Author(s):  
S. Sánchez-Valdes ◽  
E. Ramírez-Vargas ◽  
L.F. Ramos de Valle ◽  
J.G. Martinez-Colunga ◽  
J. Romero-Garcia ◽  
...  

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