ABSTRACT
In April 1986, a large quantity of unrefined crude oil was released into the nearshore marine environment on Trinidad's east coast. The oil was observed to have affected approximately 20 kilometers of coastline. Physical examination of the oil collected revealed that it had the appearance of a light grade crude, was golden brown in color, and had a characteristic gassy odor. Also observed was a mass mortality of the bivalve Donax sp (chip-chip), which inhabits sandy areas of the intertidal zone.
Oil was extracted from samples of water, beach sand, and chip-chip collected from selected stations along the affected area. Also collected were samples of oil from possible sources located both offshore and at land-based facilities. Chemical characterization of the oil extracts, using capillary gas chromatography, atomic absorption and fluorescence spectroscopy, and carbon-13 nuclear magnetic resonance spectrometry, yielded data sets that distinguished the oils in the environment from the suspect source oils investigated.
Application of statistical pattern recognition techniques, utilizing a hierarchical clustering procedure, to data from both environmental and suspect source samples yielded a high probability match between the spill samples and samples from one of the two oil companies operating in the area.