Modeling the crystallization kinetics of polymers displaying high levels of secondary crystallization

The isothermal crystallization of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) was evaluated using a range of models, namely, Avrami, simplified Hillier, Tobin, Malkin, Urbanovici–Segal, Velisaris–Seferis, and Hay. Two methods of model evaluation were used: determination of the parameters through traditional double log plots and curve fitting via nonlinear, multivariable regression. Visual inspection of the cumulative crystallization curves, calculation of the R2 value and standard error of the regression, and evaluation of the returned parameters were used to assess which model best describes the experimental data. The Hay model was found to generate the best fit, closely followed by the Velisaris–Seferis parallel model, suggesting that primary and secondary crystallization occur concurrently. The Avrami, Malkin, and Tobin models were found to perform well when the data is restricted to the region where primary crystallization dominates; however, they could not be used to successfully model the entire crystallization process. This work highlights the importance of selecting the most appropriate model for analyzing kinetics, especially when high levels of lamellar thickening and infilling occur during crystallization.

Multi-stage parallel model in determining the quality of structural timber by the penetration method

Multi-stage parallel model in determining the quality of structural timber by the penetration method. Various devices are used in situ to diagnose the quality of structural timber. A semi-destructive method is used for the approximate determination of wood density. The Pilodyn 6J uses a depth of cut that correlates with wood density. The experiments were performed on spruce wood (Picea excelsa, Karst. L.). Boards 40 × 200 × 2500 mm3, were tested, n = 5 pcs. The density of wood was determined by the gravimetric method according to EN 408 (2013). The penetration depth (hp), number and width of annual rings (RoG) were determined on the boards. Based on the density of the wood, the quality of the structural timber was specified by strength classes according to EN 338 (2016). The dependences between the measured characteristics were expressed in a model with a multi-stage parallel scale (penetration depth ~ number of annual rings  rate of growth  strength class and density wood). It is possible to predict visual strength class of board and indicative density of wood (EN 338) by the proposed model in situ. Methods of model are easy to use, reliable and economically undemanding.

Morphosyntax–phonology mismatches in Muskogee

The mismatching of morphosyntactic and phonological domains inside words provides a testing ground for models of the morphosyntax–phonology interface. This paper describes a pattern of morphosyntax–phonology mismatches in Muskogee. Muskogee verbs are spelled out at two phases, vP and CP, resulting in two phonological domains, which this paper models as ω-recursion. The vP phase and ωmin are mismatched: either vP-phase material is parsed outside ωmin – an undermatch – or CP-phase material is parsed inside ωmin – an overmatch. The mismatch pattern requires a parallel model of morphosyntax–phonology mapping to distinguish mismatches using gradient Align constraints, rather than categorial Match constraints. Additionally, a phase-based model must allow earlier cycles to be altered in later cycles, ruling out strict phase inalterability in phonology, while a Stratal OT analysis must send a word's first phase through the stem-level phonology, regardless of its ultimate phasal structure.

Real-time Issues in the Ada Parallel Model with OpenMP

The current proposal for the next revision of the Ada language considers the possibility to map the language parallel features to an underlying OpenMP runtime. As previously presented, and discussed in previous workshops, the works on fine-grain parallelism in Ada map well to the OpenMP tasking model for parallelism. Nevertheless, and although the general model of integration, and the semantic constructs are already reflected in the proposed revision of the standard, the integration of these new features with the Real-Time Systems Annex of Ada is still not complete. This paper presents an overview of what is supported and the still open issues.