Tuning of visible light-driven CO2 reduction and hydrogen evolution activity by using POSS-modified porous organometallic polymers

Significant efforts have been devoted to photochemical CO2 reduction reaction (CO2RR) as a significant pathway for the development of renewable energy systems. However, competitive hydrogen evolution reaction (HER) greatly impedes...

Fullerene Polymers: A Brief Review

This paper reviews the ways in which C60 and other fullerene molecules can be incorporated into polymeric structures. Firstly, polymers in which the fullerenes are incorporated into the structure by covalent or noncovalent bonding are discussed. These include “pearl necklace” structures, “charm bracelet” structures, organometallic polymers, crosslinked polymers, end-capped polymers, star-shaped polymers and supramolecular polymers. Secondly, all-carbon polymers, which are produced by fusing fullerenes together, are covered. The synthesis and properties of each class of fullerene polymer are outlined and the prospects for commercial applications considered.

Ionic Liquid-Modified Porous Organometallic Polymers as Efficient and Selective Photocatalysts for Visible-Light-Driven CO2 Reduction

In the photoreduction of CO2 to CO, the competitive H2 evolution is always inevitable due to the approximate reduction potentials of H+/H2 and CO2/CO, which results in poor selectivity for CO production. Herein, imidazolium-type ionic liquid- (IL-) modified rhenium bipyridine-based porous organometallic polymers (Re-POMP-IL) were designed as efficient and selective photocatalysts for visible-light CO2 photoreduction to CO based on the affinity of IL with CO2. Photoreduction studies demonstrated that CO2 photoreduction promoted by Re-POMP-IL functioning as the catalyst exhibits excellent CO selectivity up to 95.5% and generate 40.1 mmol CO/g of Re-POMP-IL1.0 (obtained by providing equivalent [(5,5′-divinyl-2,2′-bipyridine)Re(CO)3Cl] and 3-ethyl-1-vinyl-1H-imidazol-3-ium bromide) at 12 h, outperforming that attained with the corresponding Re-POMP analogue without IL, which highlights the crucial role of IL. Notably, CO2 adsorption, light harvesting, and transfer of photogenerated charges as key steps for CO2RR were studied by employing POMPs modified with different amounts of IL as photocatalysts, among which the CO2 affinity as an important factor for POMPs catalyzed CO2 reduction is revealed. Overall, this work provides a practical pathway to improve the CO2 photoreduction efficiency and CO selectivity by employing IL as a regulator.

Organometallic polymers synthesized from prochiral molecules by a surface-assisted synthesis on Ag(111)

Organometallic polymers have been successfully synthesized on a Ag(111) surface via a surface-assisted synthesis by choosing prochiral molecules as the precursor.

Recent progress of magnetic nanomaterials from cobalt-containing organometallic polymer precursors

This review summarizes the recent progress in the syntheses and materials applications of Co-containing organometallic polymers, and mainly focuses on the preparation of magnetic nanostructures from Co-containing organometallic polymer precursors.

Molecular complexes and main-chain organometallic polymers based on Janus bis(carbenes) fused to metalloporphyrins

Janus bis(N-heterocyclic carbenes) composed of a porphyrin core with two N-heterocyclic carbene (NHC) heads fused to opposite pyrroles were used as bridging ligands for the preparation of metal complexes.