The normalized Laplacian plays an indispensable role in exploring the structural properties of irregular graphs. Let
L
n
8,4
represent a linear octagonal-quadrilateral network. Then, by identifying the opposite lateral edges of
L
n
8,4
, we get the corresponding Möbius graph
M
Q
n
8,4
. In this paper, starting from the decomposition theorem of polynomials, we infer that the normalized Laplacian spectrum of
M
Q
n
8,4
can be determined by the eigenvalues of two symmetric quasi-triangular matrices
ℒ
A
and
ℒ
S
of order
4
n
. Next, owing to the relationship between the two matrix roots and the coefficients mentioned above, we derive the explicit expressions of the degree-Kirchhoff indices and the complexity of
M
Q
n
8,4
.