redox mediators
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2022 ◽  
Author(s):  
Peng Li ◽  
Wenfeng Yuan ◽  
Yitie Huang ◽  
Caiyu Zhang ◽  
Chide Ni ◽  
...  

Abstract To identify suitable biocatalysts applied in microbial fuel cells (MFCs), Pseudomonas stutzeri S116 isolated from marine sludge was investigated, which possessed excellcent bioelectricity generation ability (BGA). Herein, P. stutzeri as a bioanode and biocathode achieved maximum output voltage (254.2 mV and 226.0 mV), and power density of (765 mW/m2 and 656.6 mW/m2). Complete genome sequencing of P. stutzeri was performed to reveal its potential microbial functions. The results exhibited that the strain was the ecologically dominant Pseudomonas, and its primary annotations were associated with energy production and conversion (6.84%), amino acid transport and metabolism (6.82%) and inorganic ion transport and metabolism (6.77%). The thirty-six genes involved in oxidative phosphorylation indicate that strain possesses an integrated electron transport chain. Moreover, many genes encoding redox mediators (mainly riboflavin and phenazine) were detected in the databases. Simultaneously, thiosulfate oxidization and dissimilatory nitrate reduction were annotated in the sulfur metabolism and nitrogen metabolism pathway. Gene function and cyclic voltammetry (CV) analysis indicated BGA of P. stutzeri probably was attributed to its cytochrome c and redox mediators, which enhance extracellular electron transfer (EET) rate.


2022 ◽  
pp. 2103527
Author(s):  
Hyun‐Soo Kim ◽  
Boran Kim ◽  
Hyunyoung Park ◽  
Jongsoon Kim ◽  
Won‐Hee Ryu

Nanoscale ◽  
2022 ◽  
Author(s):  
Telmo Oliveira Paiva ◽  
Angela Nicole Schneider ◽  
Laure Bataille ◽  
Arnaud Chovin ◽  
Agnes Anne ◽  
...  

The enzymatic activity of tobacco mosaic virus (TMV) nanorod particles decorated with an integrated electro-catalytic system, comprising the quinoprotein glucose-dehydrogenase (PQQ-GDH) enzyme and ferrocenylated PEG chains as redox mediators, is...


2022 ◽  
Author(s):  
R. Francke ◽  
A. Prudlik ◽  
R. D. Little

This chapter is intended to serve as a mini-tutorial rather than a comprehensive review. Discussions focus upon fundamental aspects of electrochemically mediated electron transfer. Examples are provided to illustrate the major concepts and a sample procedure is provided.


2022 ◽  
Author(s):  
Giribabu Lingamallu ◽  
Siva Gangadhar Palivela ◽  
Anooja Jagadeesh ◽  
Rajesh Naga Manne ◽  
Andrew Simon George ◽  
...  

In dye-sensitized solar cells (DSSC), π-spacers play a critical role in regulating photovoltaic accomplishment. This is more pronounced when we use alternate redox mediators like cobalt and copper which are...


Author(s):  
Lihua Li ◽  
Liang Zhao ◽  
Xiao Jiang ◽  
Ze Yu ◽  
Jihong Liu ◽  
...  

In recent years, copper(II/I) complexes have attracted growing interest as redox mediators in dye-sensitized solar cells. Here, we report a new class of copper complexes bearing a bis(2-pyridylmethyl)-1,2-ethanedithiol ligand, coded...


2022 ◽  
Vol 301 ◽  
pp. 113924
Author(s):  
Tao Li ◽  
Xiao-Li Yang ◽  
Hai-Liang Song ◽  
Han Xu ◽  
Qiao-Ling Chen

2022 ◽  
Author(s):  
Catherine E. Housecroft ◽  
Edwin C Constable

Abstract: The use of renewable energy is essential for the future of the Earth, and solar photons are the ultimate source of energy to satisfy the ever-increasing global energy demands....


Author(s):  
Hanyun Zhong ◽  
Jing Wang ◽  
Yonggang Wang ◽  
Ping He ◽  
Haoshen Zhou

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