Synthesis of thermo-sensitive polymer with super narrow molecular weight distribution: PET-RAFT polymerization of N-isopropyl acrylamide meditated by cross-linked zinc porphyrins with high active site loadings

To overcome aggregation of porphyrins and realize heterogeneous catalysis with high active site loadings, the twisted ZnTHP-Me2Si and layered ZnTHP-Ph2Si are synthesized through cross-linking zinc tetraphenylporphyrin (ZnTHP) respectively with dichlorodimethylsilane...

Excited state electron transfer in A2 and A2B2 functionalized zinc porphyrins carrying rigid and flexible β-pyrrole π-extended substituents

Optical absorption and emission, electrochemical, and photochemical properties of peripherally functionalized with flexible and rigid [Formula: see text]-extended substituents on A2 and A2B2 type zinc porphyrins is investigated. The significance of rigid [Formula: see text]-substituents over flexible ones in governing the spectral properties is unraveled. Flexible [Formula: see text]-substituents on the porphyrin ring caused appreciable spectral broadening compared to porphyrin carrying rigid [Formula: see text]-substituents. Further, supramolecular dyads are formed by coordinating phenyl imidazole functionalized fullerene, C[Formula: see text]Im. The calculated binding constants for the 1:1 complexes is in the order of 2–7 × 105 M[Formula: see text] suggesting stable complex formation. Free-energy calculations performed according to the Rehm–Weller approach suggested possibility of excited state electron transfer in these dyads. Femtosecond transient absorption studies of the dyads performed in [Formula: see text]-dichlorobenzene showed evidence of occurrence of electron transfer from the singlet-excited state that was in competition with the intersystem crossing process to populate the triplet-excited state of porphyrins.

The synthesis of star-shaped poly(N-isopropylacrylamide) with two zinc porphyrins as the core and end groups via ATRP and “CLICK” chemistry and a photocatalytic performance study

The synthesis of star-shaped poly(N-isopropylacrylamide) with two zinc porphyrins as the core and end groups via ATRP & “CLICK” chemistry and a photocatalytic performance study.

Benchmarking computational methods and influence of guest conformation on chirogenesis in zinc porphyrin complexes

Different computational methods and influence of the guest conformation and solvent effect to analyze chirogenesis in zinc porphyrins by several chiral compounds have been investigated.