Properties and role of interfaces in multimaterial 3D printed composites

In polyjet printing photopolymer droplets are deposited on a build tray, leveled off by a roller and cured by UV light. This technique is attractive to fabricate heterogeneous architectures combining compliant and stiff constituents. Considering the layer-by-layer nature, interfaces between different photopolymers can be formed either before or after UV curing. We analyzed the properties of interfaces in 3D printed composites combining experiments with computer simulations. To investigate photopolymer blending, we characterized the mechanical properties of the so-called digital materials, obtained by mixing compliant and stiff voxels according to different volume fractions. We then used nanoindentation to measure the spatial variation in mechanical properties across bimaterial interfaces at the micrometer level. Finally, to characterize the impact of finite-size interfaces, we fabricated and tested composites having compliant and stiff layers alternating along different directions. We found that interfaces formed by deposition after curing were sharp whereas those formed before curing showed blending of the two materials over a length scale bigger than individual droplet size. We found structural and functional differences of the layered composites depending on the printing orientation and corresponding interface characteristics, which influenced deformation mechanisms. With the wide dissemination of 3D printing techniques, our results should be considered in the development of architectured materials with tailored interfaces between building blocks.

The onset of the frictional motion of dissimilar materials

Frictional motion between contacting bodies is governed by propagating rupture fronts that are essentially earthquakes. These fronts break the contacts composing the interface separating the bodies to enable their relative motion. The most general type of frictional motion takes place when the two bodies are not identical. Within these so-called bimaterial interfaces, the onset of frictional motion is often mediated by highly localized rupture fronts, called slip pulses. Here, we show how this unique rupture mode develops, evolves, and changes the character of the interface’s behavior. Bimaterial slip pulses initiate as “subshear” cracks (slower than shear waves) that transition to developed slip pulses where normal stresses almost vanish at their leading edge. The observed slip pulses propagate solely within a narrow range of “transonic” velocities, bounded between the shear wave velocity of the softer material and a limiting velocity. We derive analytic solutions for both subshear cracks and the leading edge of slip pulses. These solutions both provide an excellent description of our experimental measurements and quantitatively explain slip pulses’ limiting velocities. We furthermore find that frictional coupling between local normal stress variations and frictional resistance actually promotes the interface separation that is critical for slip-pulse localization. These results provide a full picture of slip-pulse formation and structure that is important for our fundamental understanding of both earthquake motion and the most general types of frictional processes.