lithium complexes
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Author(s):  
Cesar Gabriel Vera de la Garza ◽  
Luis Daniel Solis Rodriguez ◽  
Serguei Fomine ◽  
Wilmer E. Vallejo Narváez

2021 ◽  
Author(s):  
Andrew J. Valentine ◽  
Ana M. Geer ◽  
Laurence J. Taylor ◽  
Andrew M. Teale ◽  
Katherine E. Wood ◽  
...  

Spectroscopic and computational investigation of the effects of para-substituted m-terphenyl lithium complexes reveals significant electronic differences at the metal centre.


2020 ◽  
Vol 98 (8) ◽  
pp. 453-459
Author(s):  
Tingshan Zhong ◽  
Jixing Zhao ◽  
Hao Lei

A series of lithium complexes with trianionic bis(trityl)/aryloxide ligands were prepared by triple deprotonation of phenols with two ortho-diarylmethyl substituents. Transmetalation with one of the lithium complexes via salt metathesis resulted in the synthesis of corresponding Mg and Zn complexes, which showed distinct coordination stoichiometry and structures. The metal complexes were characterized by multi-nuclear NMR, UV–vis, and infrared spectroscopy. Additionally, the redox property of a trilithium compound was investigated by electrochemical methods. X-ray crystallography revealed that the new bis(trityl)/aryloxide ligands could simultaneously bind to two nearby metal centers both in chelating κ2-O,C fashion, making themselves rare examples of tridentate binucleating alkyl/aryloxo scaffolds.


ACS Omega ◽  
2019 ◽  
Vol 4 (25) ◽  
pp. 21559-21566 ◽  
Author(s):  
Syed Raza Shah ◽  
Zarbad Shah ◽  
Ajmal Khan ◽  
Ayaz Ahmed ◽  
Sohani ◽  
...  

2019 ◽  
Vol 2019 (46) ◽  
pp. 4894-4901 ◽  
Author(s):  
Kieren J. Evans ◽  
Cameron L. Campbell ◽  
Mairi F. Haddow ◽  
Christian Luz ◽  
Paul A. Morton ◽  
...  

2019 ◽  
Vol 6 (1) ◽  
pp. 40-49 ◽  
Author(s):  
Denis N. Bazhin ◽  
Yulia S. Kudyakova ◽  
Artem S. Bogomyakov ◽  
Pavel A. Slepukhin ◽  
Grigory A. Kim ◽  
...  

A convenient and straightforward synthesis of a novel type of Ln–Li β-diketonates with a discrete molecular structure is presented.


2018 ◽  
Vol 37 (8) ◽  
pp. 1291-1303 ◽  
Author(s):  
Kim S. Flaig ◽  
Benjamin Raible ◽  
Verena Mormul ◽  
Natalie Denninger ◽  
Cäcilia Maichle-Mössmer ◽  
...  

2018 ◽  
Vol 2018 (9) ◽  
pp. 1093-1098 ◽  
Author(s):  
Kuldeep Chand ◽  
Cheng-Long Tsai ◽  
Hsuan-Ying Chen ◽  
Wei-Min Ching ◽  
Sung-Po Hsu ◽  
...  

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