ZIF-8/PI Nanofibrous Membranes With High-Temperature Resistance for Highly Efficient PM0.3 Air Filtration and Oil-Water Separation

Air and water pollution poses a serious threat to public health and the ecological environment worldwide. Particulate matter (PM) is the major air pollutant, and its primary sources are processes that require high temperatures, such as fossil fuel combustion and vehicle exhaust. PM0.3 can penetrate and seriously harm the bronchi of the lungs, but it is difficult to remove PM0.3 due to its small size. Therefore, PM0.3 air filters that are highly efficient and resistant to high temperatures must be developed. Polyimide (PI) is an excellent polymer with a high temperature resistance and a good mechanical property. Air filters made from PI nanofibers have a high PM removal efficiency and a low air flow resistance. Herein, zeolitic imidazolate framework-8 (ZIF-8) was used to modify PI nanofibers to fabricate air filters with a high specific surface area and filtration efficiency. Compared with traditional PI membranes, the ZIF-8/PI multifunction nanofiber membranes achieved super-high filtration efficiency for ultrafine particles (PM0.3, 100%), and the pressure drop was only 63 Pa. The filtration mechanism of performance improvement caused by the introduction of ZIF-8/PI nanofiber membrane is explored. Moreover, the ZIF-8/PI nanofiber membranes exhibited excellent thermal stability (300 C) and efficient water–oil separation ability (99.85%).

PVP-Assisted Shellac Nanofiber Membrane as Highly Efficient, Eco-Friendly, Translucent Air Filter

Particulate matter (PM), composed of tiny solids and liquid droplets in polluted air, poses a serious threat to human health. Traditional air filters usually cause secondary pollution due to their poor degradability. Here, shellac, as an environmentally friendly natural organic material, was successfully applied to fabricate biodegradable air filters. Since pure shellac fiber shows poor mechanical properties and bad light transmittance, we then introduced a small amount of polyvinylpyrrolidone (PVP) in the shellac solution to prepare highly efficient air filter membranes by the electrospinning method. The prepared PVP-assisted shellac nanofiber membrane (P-Shellac FME) demonstrated improved filtration efficiencies as high as 95% and 98% for PM2.5 and PM10, respectively. The P-Shellac FME also showed good stability, with filtration efficiencies still above 90% and 95% for PM2.5 and PM10 even after six hours of air filtering under high PM concentrations. The pressure drop going through the filter was only 101 Pa, which is also comparable to the value of 76 Pa obtained using commercial polypropylene nanofibers (PP nanofibers, peeled off from the surgical mask), indicating good air permeability of P-Shellac FME. Additionally, P-Shellac FME also showed the advantages of translucence, biodegradability, improved mechanical properties, and low cost. We believe that the P-Shellac FME will make a significant contribution in the application of air filtration.