Chiral Liquid Crystalline Electronic Systems

Liquid crystals bearing extended π-conjugated units function as organic semiconductors and liquid crystalline semiconductors have been studied for their applications in light-emitting diodes, field-effect transistors, and solar cells. However, studies on electronic functionalities in chiral liquid crystal phases have been limited so far. Electronic charge carrier transport has been confirmed in chiral nematic and chiral smectic C phases. In the chiral nematic phase, consisting of molecules bearing extended π-conjugated units, circularly polarized photoluminescence has been observed within the wavelength range of reflection band. Recently, circularly polarized electroluminescence has been confirmed from devices based on active layers of chiral conjugated polymers with twisted structures induced by the molecular chirality. The chiral smectic C phase of oligothiophene derivatives is ferroelectric and indicates a bulk photovoltaic effect, which is driven by spontaneous polarization. This bulk photovoltaic effect has also been observed in achiral polar liquid crystal phases in which extended π-conjugated units are properly assembled. In this manuscript, optical and electronic functions of these chiral π-conjugated liquid crystalline semiconductors are reviewed.

Orientation Control of Helical Nanofilament Phase and Its Chiroptical Applications

Chiral liquid crystal phases show fascinating structural and optical properties due to their inherent helical characteristics. Among the various chiral liquid crystal phases, the helical nanofilament phase, made of achiral bent-shaped molecules, has been of keen research interest due to its unusual polar and chiral properties. This review is intended to introduce the recent progress in orientation control and its application to the helical nanofilament phase, which includes topographic confinement, photoalignment, and chiroptical applications such as photonic crystal and chirality sensor.

Semiconducting and electropolymerizable liquid crystalline carbazole-containing porphyrin-core dendrimers

We have successfully synthesized porphyrin-core dendrimers with peripheral carbazole moieties, which can be electrochemically crosslinked. Moreover, these dendrimers exhibit discotic nematic liquid crystal phases with high hole mobilities.