In the big data environment, the visualization technique has been increasingly adopted to mine the data on library and information (L&I), with the diversification of data sources and the growth of data volume. The previous research into the information association of L&I visualization network rarely tries to construct such a network or explore the information association of the network. To overcome these defects, this paper explores the visualization of L&I from the perspective of big data analysis and fusion. Firstly, the authors analyzed the topology of the L&I visualization network and calculated the metrics for the construction of L&I visualization topology map. Next, the importance of meta-paths of the L&I visualization network was calculated. Finally, a complex big data L&I visualization network was established, and the associations between information nodes were analyzed in detail. Experimental results verify the effectiveness of the proposed algorithm.