nitrogen evolution
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2022 ◽  
Vol 157 ◽  
pp. 112020
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Zhiwei Yang ◽  
Gaofeng Dai ◽  
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Jun Sun ◽  
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2021 ◽  
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2017 ◽  
Vol 31 (7) ◽  
pp. 7191-7196 ◽  
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Fu Wei ◽  
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2015 ◽  
Vol 11 ◽  
pp. 2254-2260 ◽  
Author(s):  
Manuel R Fructos ◽  
Juan Urbano ◽  
M Mar Díaz-Requejo ◽  
Pedro J Pérez

Kinetic experiments based on the measurement of nitrogen evolution in the reaction of ethyl diazoacetate (N2CHCO2Et, EDA) and styrene or methanol catalyzed by the [IPrAu]+ core (IPr = 1,3-bis(diisopropylphenyl)imidazole-2-ylidene) have provided evidence that the transfer of the carbene group CHCO2Et to the substrate (styrene or methanol) takes place in the coordination sphere of Au(I) by means of an inner-sphere mechanism, in contrast to the generally accepted proposal of outer-sphere mechanisms for Au(I)-catalyzed reactions.


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