Soil Chemistry and Clay Mineralogy of an Alluvial Chronosequence from the North Carolina Sandhills of the Upper Coastal Plain, USA

Temporal changes in soil development were assessed on fluvial terraces of the Little River in the upper Coastal Plain of North Carolina. We examined five profiles from each of six surfaces spanning about 100,000 years. Soil-age relationships were evaluated with inter-surface clay mineral comparisons and regression of chemical properties versus previously reported optically-stimulated luminescence ages using the most developed subsoil horizon per profile. Bases to alumina (Bases/Al2O3) ratios have negative correlations with age, whereas dithionite-Fe (FeD) concentrations are positively correlated with time and differentiate floodplain (<200 yr BP) from terrace (≥10 ± 2 ka) soils and T4 pedons (75 ± 10 ka) from younger (T1-T3b, 10 ± 2–55 ± 15 ka) and older (T5b, 94 ± 16 ka) profiles. Entisols develop into Ultisols with exponentially decreasing Bases/Al2O3 ratios, reflecting rapid weatherable mineral depletion and alumina enrichment during argillic horizon development in the first 13–21 kyr of pedogenesis. Increasing FeD represents transformation and illuviation of free Fe inherited from parent sediments. Within ~80–110 kyr, a mixed clay mineral assemblage becomes dominated by kaolinite and gibbsite. Argillic horizons form by illuviation, secondary mineral transformations, and potentially, a bioturbation-translocation mechanism, in which clays distributed within generally sandy deposits are transported to surface horizons by ants and termites and later illuviated to subsoils. T5b profiles have FeD concentrations similar to, and gibbsite abundances greater than, those of pedons on 0.6–1.6 Ma terraces along Coastal Plain rivers that also drain the Appalachian Piedmont. This is likely because the greater permeability and lower weatherable mineral contents of sandy, Coastal Plain-sourced Little River alluvium favor more rapid weathering, gibbsite formation, and Fe translocation than the finer-grained, mineralogically mixed sediments of Piedmont-draining rivers. Therefore, recognizing provenance-related textural and mineralogical distinctions is crucial for evaluating regional chronosequences.

An Upper Cretaceous paleodrainage system on the Coastal Plain unconformity of Alabama-Georgia

ABSTRACT Rocks of the Upper Cretaceous Tuscaloosa Formation (Cenomanian) and Eutaw Formation (Santonian) in southwestern Georgia and southeastern Alabama record an interval of fluvial and nearshore marine deposition. In the vicinity of Columbus, Georgia, basal units of the Tuscaloosa Formation consist of a residual paleosol built on crystalline rocks of the Appalachian Piedmont covered by conglomeratic sandstones deposited in braided stream systems flowing across the mid-Cenomanian Coastal Plain unconformity. The unconformity, which separates Cretaceous detrital rocks from underlying metamorphic rocks and residual paleosols built on those metamorphic rocks, lies primarily within the Tuscaloosa Formation in this region and is marked at the modern surface by the geomorphic Fall Line. Mapping of the unconformity across the region reveals areas of significant paleorelief associated with a number of distinct paleovalleys incised into the mid-Cenomanian surface. The most distinct of these lie immediately east of the Alabama-Georgia state line, within 15 km of the modern Lower Chattahoochee River Valley. Spatially, these distinct paleovalleys lie immediately north of a Santonian estuarine environment recorded in the Eutaw Formation, disconformably above the Tuscaloosa Formation. Collectively, paleo-valleys in the mid-Cenomanian surface, the fluvial nature of the Tuscaloosa Formation in southwestern Georgia and southeastern Alabama, and the estuarine environment in the younger Eutaw Formation suggest a persistent (~10 m.y.) paleodrainage system that may be a forerunner to the modern Chattahoochee River.

New insights into the geologic evolution of the Grenvillian Trenton Prong inlier, Central Appalachian Piedmont, USA

New geochemical and 40Ar/39Ar hornblende and biotite data from the Grenvillian Trenton Prong inlier provide the first constraints for the identification of lithotectonic units, their tectonic setting, and their metamorphic to post-metamorphic history. Gneissic tonalite, diorite, and gabbro compose the Colonial Lake Suite magmatic arc that developed along eastern Laurentia prior to 1.2 Ga. Spatially associated low- and high-TiO2 amphibolites were formed from island-arc basalt proximal to the arc front and mid-ocean ridge basalt-like basalt in a back-arc setting, respectively. Supracrustal paragneisses include meta-arkose derived from a continental sediment source of Laurentian affinity and metagraywacke and metapelite from an arc-like sediment source deposited in a back-arc basin, inboard of the Colonial Lake arc. The Assunpink Creek Granite was emplaced post-tectonically as small bodies of peraluminous syenogranite produced through partial melting of a subduction-modified felsic crustal source. Prograde mineral assemblages reached granulite- to amphibolite-facies metamorphic conditions during the Ottawan phase of the Grenvillian Orogeny. Hornblende 40Ar/39Ar ages of 935–923 Ma and a biotite age of 868 Ma record slow cooling in the northern part of the inlier following the metamorphic peak. Elsewhere in the inlier, biotite 40Ar/39Ar ages of 440 Ma and 377–341 Ma record partial to complete thermal resetting or new growth during the Taconian and Acadian orogens. The results of this study are consistent with the Trenton Prong being the down-dropped continuation of the Grenvillian New Jersey Highlands on the hanging wall of a major detachment fault. The Trenton Prong therefore correlates to other central and northern Appalachian Grenvillian inliers and to parts of the Grenville Province proper.

Further detrital zircon evidence for peri-Gondwanan blocks in the central Appalachian Piedmont Province, USA

Evidence for exotic terranes in the central Appalachian Piedmont Province is fragmented between central Virginia, northern Maryland, and southeastern Pennsylvania. Here we present laser ablation-inductively coupled plasma mass spectrometry data from detrital zircon that support the presence of an exotic terrane in this region. U–Pb dating of detrital zircon from new samples of the Storck quartzite (central Virginia) and the Hoods Mill rocks (northern Maryland) confirms the presence of a major peak at ca. 630–610 Ma in these units. These ages are consistent with derivation from Gondwana, but not Ediacaran Laurentia. Further, modern εHf values of five of the ca. 670–580 Ma grains in these samples are inconsistent with derivation from the few plutons of this age in Ediacaran Laurentia. The Loch Raven Schist and a metasedimentary xenolith in the Wilmington Complex contain a smaller proportion of ca. 670–580 Ma grains than the Storck quartzite and the Hoods Mill rocks, but more such grains than in sediment derived from Ediacaran Laurentia, so we tentatively conclude that these two units also received sediment from Gondwana. Detrital zircon ages from the Piney Run Formation, Pleasant Grove Schist, Prettyboy Schist, and Wissahickon Formation allow sediment provenance solely in Ediacaran Laurentia. We also present new zircon spot U–Pb and Lu–Hf isotopic data from western Newfoundland plutons for comparison with these types of data from the detrital zircon. Intrusion ages of the Steel Mountain Anorthosite, Disappointment Hill Tonalite, and Round Pond Granite are 608 ± 12, 600 ± 8, and 590 ± 9 Ma, respectively. None of these units was derived entirely from the depleted mantle.