Scope and limitation of propylene carbonate as a sustainable solvent in the Suzuki–Miyaura reaction

The Suzuki–Miyaura reaction was carried out in propylene carbonate yielding an interesting side-product besides the biphenyl derivative.

Crystal structure of 4,4′-dinitro-[1,1′-biphenyl]-2-amine

In the title biphenyl derivative, C12H9N3O4, the dihedral angle between the benzene rings is 52.84 (10)°. The nitro group attached to the benzene ring is inclined to the ring by 4.03 (2)°, while the nitro group attached to the amino-substituted benzene ring is inclined to the ring by 8.84 (2)°. In the crystal, molecules are linked by two pairs of N—H...O hydrogen bonds, forming chains propagating along [101]. Within the chains, these N—H...O hydrogen bonds result in the formation ofR22(20) andR22(14) ring motifs. The latter ring motif is reinforced by a pair of C—H...O hydrogen bonds, enclosingR21(6) ring motifs. The chains are linked by a second C—H...O hydrogen bond, forming a three-dimensional supramolecular structure.

Diradicalized biphenyl derivative carbon-based material molecules: exploring the tuning effects on magnetic couplings

DFT calculations reveal three different interference effects on the magnetic properties of carbon-based molecule coupled nitroxide diradicals: twisting, sideways group, and position effects.