Low temperature isomerizational transformation of gas gasoline on modified zeolite catalysts

New multicomponent catalytic systems synthesized by modifying zeolites (НМOR17 and HZSM-5) and γ-Al2O3 with metals (Co, Ni), zirconium dioxide and subsequent sulfation and tungestation of the obtained samples. It was shown that the introduction of zirconia into the M/MOR (where M = Co, Ni) system allows one to lower the isomerization temperature by 140-160°С, turning the medium-temperature skeletal-isomerisation catalyst M/MOR into a low-temperature M/MOR/ZrO2. It was found that sulfated Co/MOR/ZrO2/SO42- and Co/HZSM-5/ZrO2/SO42- have a higher isomerization activity, which makes it possible to increase the content of isomeric C5-C6 components with high octane numbers in gas gasoline from 43 to 66%. It was found that upon contacting the gas gasoline with the Co/MOR/ZrO2/SO42- or Co/HZSM-5/ZrO2/SO42- catalytic systems, efficient processing of higher molecular weight C7+ alkanes occurs not only into iso-C5 and C6, but also into n-pentane whose content in contact products rises from 19 to 40%. For the first time it was found that at temperatures of 160-200 °C, impurity gaseous C4- alkanes in the gas gasoline are consumed of when contacted with synthesized catalysts, turning into liquid alkanes. It was established that sulfated catalysts have more isomerizing activity in the low-temperature isomerization conversion of gas gasoline than volframated ones. The effect of the concentration of SO42- ions on the activity of the catalysts was studied and it was found that 2 wt.% is satisfactory for the studied catalysts. The temperature dependence of the activity of the most active of the synthesized catalysts in this process – Co/HZSM-5/ZrO2/SO42-, was studied. The results showed that the optimum temperature for the isomerization functioning of the selected catalyst is 180 oC. The change in the activity of the optimal catalyst (Co/HZSM-5/ZrO2/SO42-) depending on the reaction period was also studied. It was established that with the course of the process, the activity of the catalyst increases and reaches a maximum of 30 minutes work. After this, the activity of the catalyst gradually decreases. In this case, the total concentration of iso-C5 and iso-C6 increases by 22.9% and reaches 66.1%, and the conversion of C7+ components of gas gasoline is 69.2%.

Interconversion between a planar 1,3-dichlorobicyclo[1.1.0]tetrasilane and a (chloro)(chlorosilyl)cyclotrisilene

A 1,3-dichlorotetrasilabicyclo[1.1.0]butane with a π-type bridgehead Si–Si bond undergoes a skeletal isomerisation to a 1-chloro-2-(chlorosilyl)cyclotrisilene.