Chemical heterogeneities reveal early rapid cooling of Apollo Troctolite 76535

The evolution of the lunar interior is constrained by samples of the magnesian suite of rocks returned by the Apollo missions. Reconciling the paradoxical geochemical features of this suite constitutes a feasibility test of lunar differentiation models. Here we present the results of a microanalytical examination of the archetypal specimen, troctolite 76535, previously thought to have cooled slowly from a large magma body. We report a degree of intra-crystalline compositional heterogeneity (phosphorus in olivine and sodium in plagioclase) fundamentally inconsistent with prolonged residence at high temperature. Diffusion chronometry shows these heterogeneities could not have survived magmatic temperatures for >~20 My, i.e., far less than the previous estimated cooling duration of >100 My. Quantitative modeling provides a constraint on the thermal history of the lower lunar crust, and the textural evidence of dissolution and reprecipitation in olivine grains supports reactive melt infiltration as the mechanism by which the magnesian suite formed.

Conditions and extent of volatile loss from the Moon during formation of the Procellarum basin

Rocks from the lunar interior are depleted in moderately volatile elements (MVEs) compared to terrestrial rocks. Most MVEs are also enriched in their heavier isotopes compared to those in terrestrial rocks. Such elemental depletion and heavy isotope enrichments have been attributed to liquid–vapor exchange and vapor loss from the protolunar disk, incomplete accretion of MVEs during condensation of the Moon, and degassing of MVEs during lunar magma ocean crystallization. New Monte Carlo simulation results suggest that the lunar MVE depletion is consistent with evaporative loss at 1,670 ± 129 K and an oxygen fugacity +2.3 ± 2.1 log units above the fayalite-magnetite-quartz buffer. Here, we propose that these chemical and isotopic features could have resulted from the formation of the putative Procellarum basin early in the Moon’s history, during which nearside magma ocean melts would have been exposed at the surface, allowing equilibration with any primitive atmosphere together with MVE loss and isotopic fractionation.

Modelling the ascent of picritic lunar magmas

<p>Quantifying the volatile content of the lunar interior is valuable for understanding the formation, thermal evolution, and magmatic evolution of the Earth and Moon. Petrological modelling and geochemical measurements have been used to study the volatile composition of the lunar interior. Improvements to analytical instruments have facilitated more precise measurements of the volatile content of lunar samples and meteorites, however, several problems remain with these measurements, hence, the volatile content of lunar magmas has yet to be constrained with certainty. We propose a volcanological approach for inferring the volatile contents of different lunar magmas.</p><p>            A terrestrial magma ascent model has been modified for lunar applications. Numerous parameters were adjusted for lunar conditions, including: magma major element composition, from low-Ti (green and yellow glasses) to high-Ti (orange, red, and black glasses); H<sub>2</sub>O content; CO content; gravity; and pressure. The model calculated values for gas exsolution, viscosity, mass flow rate, and several other ascent processes, from a depth of 10 km to the surface. Using these results, we will assess the effect of varying magmatic volatile content on lunar magma ascent processes. We will also compare and contrast our results with existing models for lunar magma ascent, as well as models for magma ascent on other planetary bodies. Future work will involve modelling eruptions, using results from the magma ascent model, and verifying the results of the models using images and digital elevation models of the lunar surface.</p>

LRO/LAMP observations of the lunar helium exosphere: constraints on thermal accommodation and outgassing rate

We report a comprehensive study by the UV spectrograph LAMP onboard the Lunar Reconnaissance Orbiter to map the spatial distribution and temporal evolution of helium atoms in the lunar exosphere, via spectroscopy of the HeI emission line at 58.4 nm. Comparisons with several Monte Carlo models show that lunar exospheric helium is fully thermalized with the surface (accommodation coefficient of 1.0). LAMP-derived helium source rates are compared to the flux of solar wind alpha particles measured in situ by the ARTEMIS twin spacecraft. Our observations confirm that these alpha particles (He++) are the main source of lunar exospheric helium, representing 79% of the total source rate, with the remaining 21% presumed to be outgassing from the lunar interior. The endogenic source rate we derive, (1.49 ± 0.08) · 106 cm-2s-1, is consistent with previous measurements but is now better constrained. LAMP-constrained exospheric surface densities present a dawn/dusk ratio of ∼1.8, within the value measured by the Apollo 17 surface mass spectrometer LACE. Finally, observations of lunar helium during three Earth’s magnetotail crossings, when the Moon is shielded from the solar wind, confirm previous observations of an exponential decay of helium with a time constant of 4.5 days.

Multiple sulfur isotopic reservoirs in the Moon and implications for the evolution of planetary interiors

Very few in situ lunar sulfur studies exist, with the major focus being on bulk-rocks in which a relatively restricted sulfur isotope fractionation is observed, leading to suggestions that the source of sulfur in the lunar interior is homogeneous. Using a novel approach, we present for the first time two complementary datasets combining in situ secondary ion mass spectrometry and X-ray absorption near-edge structure spectroscopy of lunar apatite, to investigate the late-stage behaviour of sulfur in lunar basaltic melts. Our measurements reveal varied sulfur contents of ~20–2,800 ppm and δ34S values of -33.3 ± 3.8‰ to +36.4 ± 3.2‰ (2σ). The apatites have S6+/ΣStot ratios of >0, with average values as high as 0.55, providing evidence for the existence of relatively oxidized late-stage silicate melts on the Moon. We propose the existence of multiple, previously unrecognised, distinct sulfur isotopic reservoirs in the lunar interior and atypical oxidizing conditions in late-stage silicate melts. These findings are important for our understanding of lunar formation processes and the evolution of redox conditions during the formation of terrestrial bodies.

Geological Characteristics of the Moon

The geological characteristics of the Moon provide the fundamental data that permit the study of the geological processes that have formed and modified the crust, that record the state and evolution of the lunar interior, and that identify the external processes that have been important in lunar evolution. Careful documentation of the stratigraphic relationships among these features can then be used to reconstruct the sequence of events and the geological history of the Moon. These results can then be placed in the context of the geological evolution of the terrestrial planets, including Earth. The Moon’s global topography and internal structures include landforms and features that comprise the geological characteristics of its surface. The Moon is dominated by the ancient cratered highlands and the relatively younger flat and smooth volcanic maria. Unlike the current geological characteristics of Earth, the major geological features of the Moon (impact craters and basins, lava flows and related features, and tectonic scarps and ridges) all formed predominantly in the first half of the solar system’s history. In contrast to the plate-tectonic dominated Earth, the Moon is composed of a single global lithospheric plate (a one-plate planet) that has preserved the record of planetary geological features from the earliest phases of planetary evolution. Exciting fundamental outstanding questions form the basis for the future international robotic and human exploration of the Moon.