Element Partitioning (Mineral-Melt, Metal-/Sulfide-Silicate) in Planetary Sciences

Element partitioning—at its most basic—is the distribution of an element of interest between two constituent phases as a function of some process. Major constituent elements generally affect the thermodynamic environment (chemical equilibrium) and therefore trace element partitioning is often considered, as trace elements are present in minute quantities and their equilibrium exchange reactions do not impart significant changes to the larger system. Trace elements are responsive to thermodynamic conditions, and thus they act as passive tracers of chemical reactions without appreciably influencing the bulk reactions themselves. In planetary sciences, the phase pairs typically considered are mineral-melt, metal-silicate, and sulfide-silicate, owing largely to the ubiquity of their coexistence in planetary materials across scales and context, from the micrometer-sized components of meteorites up to the size of planets (thousands of kilometers). It is common to speak of trace elements in terms of their tendency toward forming metallic, sulfidic, or oxide phases, and the terms “siderophile,” “chalcophile,” and “lithophile” (respectively) are used to define these tendencies under what is known as the Goldschmidt Classification scheme. The metric of an element’s tendency to concentrate into one phase relative to another is expressed as the ratio of its concentration (as a weight or molar fraction) in one phase over another, where convention dictates the reference frame as solid over liquid, and metal or sulfide over silicate; this mathematical term is the element’s partition coefficient, or distribution coefficient, between the two respective phases,DMPhaseBPhaseA (where M is the element of interest, most often reported as molar fraction), or simply DM. In general, trace elements obey Henry’s Law, where the element’s activity and concentration are linearly proportional. Practically speaking, this means that the element is sufficiently dilute in the system such that its atoms interact negligibly with one another compared to their interactions with major element phases, and thus the trace element’s partition coefficient in most settings is not appreciably affected by its concentration. The radius and charge of an element’s ionized species (its ionic radius and valence state)—in relation to either the major element ion for which it is substituting or the lattice site vacancy or interstitial space it is filling—generally determine the likelihood of trace element substitution or vacancy/interstitial fill (along with the net charge of the lattice space). The key energy consideration that underlies an element’s partitioning is the Gibbs free energy of reaction between the phases involved. Gibbs free energy is the change in internal energy associated with a chemical reaction (at a given temperature and pressure) that can be used to do work, and is denoted as ΔGrxn. Reactions with negative ΔGrxn values are spontaneous, and the magnitude of this negative value for a given phase, for example, a metal oxide, denotes the relative affinity of the metal toward forming oxides. That is to say, an element with a highly negative ΔGrxn for its oxide species at relevant pressure-temperature conditions will tend to be found in oxide and silicate minerals, that is, it will be lithophile (and vice versa for siderophile elements). Trace element partitioning systematics in mineral-melt and metal-/sulfide-silicate systems have boundless applications in planetary science. A growing collective understanding of the partition coefficients of elements has been built on decades of physical chemistry, deterministic theory, petrology, experimental petrology, and natural observations. Leveraging this immense intellectual, technical, and methodological foundation, modern trace element partitioning research is particularly aimed at constraining the evolution of plate tectonics on Earth (conditions and timing of onset), understanding the formation history of planetary materials such as chondrite meteorites and their constituents (e.g., chondrules), and de-convolving the multiply operating processes at play during the accretion and differentiation of Earth and other terrestrial planets.

Condensation Calculations in Planetary Science and Cosmochemistry

The Sun’s chemical and isotopic composition records the composition of the solar nebula from which the planets formed. If a piece of the Sun is cooled to 1,000 K at 1 mbar total pressure, a mineral assemblage is produced that is consistent with the minerals found in the least equilibrated (most chemically heterogeneous), oldest, and compositionally Sunlike (chondritic), hence most “primitive,” meteorites. This is an equilibrium or fractional condensation experiment. The result can be simulated by calculations using equations of state for hundreds of gaseous molecules, condensed mineral solids, and silicate liquids, the products of a century of experimental measurements and recent theoretical studies. Such calculations have revolutionized our understanding of the chemistry of the cosmos. The mid-20th century realization that meteorites are fossil records of the early solar system made chemistry central to understanding the origin of the Earth, Moon, and other bodies. Thus “condensation,” more generally the distribution of elements and isotopes between vapor and condensed solids and/or liquids at or approaching chemical equilibrium, came to deeply inform discussion of how meteoritic and cometary compositions bear on the origins of atmospheres and oceans and the differences in composition among the planets. This expansion of thinking has had profound effects upon our thinking about the origin and evolution of Earth and the other worlds of our solar system. Condensation calculations have also been more broadly applied to protoplanetary disks around young stars, to the mineral “rain” of mineral grains expected to form in cool dwarf star atmospheres, to the expanding circumstellar envelopes of giant stars, to the vapor plumes expected to form in giant planetary impacts, and to the chemically and isotopically distinct “shells” computed and observed to exist in supernovae. The beauty of equilibrium condensation calculations is that the distribution of elements between gaseous molecules, solids, and liquids is fixed by temperature, total pressure, and the overall elemental composition of the system. As with all sophisticated calculations, there are inherent caveats, subtleties, and computational difficulties. In particular, local equilibrium chemistry has yet to be consistently integrated into gridded, dynamical astrophysical simulations so that effects like the blocking of light and heat by grains (opacity), absorption and re-emission of light by grains (radiative transfer), and buffering of heat by grain evaporation/condensation are fed back into the physics at each node or instance of a gridded calculation over time. A deeper integration of thermochemical computations of chemistry with physical models makes the prospect of a general protoplanetary disk model as hopeful in the 2020s as a general circulation model for global climate may have been in the early 1970s.

The Atmosphere of Titan

Titan, Saturn’s largest satellite, is one of the most intriguing moons in our Solar System, in particular because of its dense and extended nitrogen-based and organic-laden atmosphere. Other unique features include a methanological cycle similar to the Earth’s hydrological one, surface features similar to terrestrial ones, and a probable under-surface liquid water ocean. Besides the dinitrogen main component, the gaseous content includes methane and hydrogen, which, through photochemistry and photolysis, produce a host of trace gases such as hydrocarbons and nitriles. This very advanced organic chemistry creates layers of orange-brown haze surrounding the satellite. The chemical compounds diffuse downward in the form of aerosols and condensates and are finally deposited on the surface. There is very little oxygen in the atmosphere, mainly in the form of H2O, CO, and CO2. The atmospheric chemical and thermal structure varies significantly with seasons, much like on Earth, albeit on much longer time scales. Extensive analysis of Titan data from ground, Earth-orbiting observatories, and space missions, like those returned by the 13-year operating Cassini-Huygens spacecraft, reveals a complex system with strong interactions among the atmosphere, the surface, and the interior. The processes operating in the atmosphere are informative of what occurs on Earth and give hints as to the origin and evolution of our outer Solar System.

Astrobiology (Overview)

Astrobiology seeks to understand the origin, evolution, distribution, and future of life in the universe and thus to integrate biology with planetary science, astronomy, cosmology, and the other physical sciences. The discipline emerged in the late 20th century, partly in response to the development of space exploration programs in the United States, Russia, and elsewhere. Many astrobiologists are now involved in the search for life on Mars, Europa, Enceladus, and beyond. However, research in astrobiology does not presume the existence of extraterrestrial life, for which there is no compelling evidence; indeed, it includes the study of life on Earth in its astronomical and cosmic context. Moreover, the absence of observed life from all other planetary bodies requires a scientific explanation, and suggests several hypotheses amenable to further observational, theoretical, and experimental investigation under the aegis of astrobiology. Despite the apparent uniqueness of Earth’s biosphere— the “n = 1 problem”—astrobiology is increasingly driven by large quantities of data. Such data have been provided by the robotic exploration of the Solar System, the first observations of extrasolar planets, laboratory experiments into prebiotic chemistry, spectroscopic measurements of organic molecules in extraterrestrial environments, analytical advances in the biogeochemistry and paleobiology of very ancient rocks, surveys of Earth’s microbial diversity and ecology, and experiments to delimit the capacity of organisms to survive and thrive in extreme conditions.

Migration of Low-Mass Planets

Planet migration is the variation over time of a planet’s semimajor axis, leading to either a contraction or an expansion of the orbit. It results from the exchange of energy and angular momentum between the planet and the disk in which it is embedded during its formation and can cause the semimajor axis to change by as much as two orders of magnitude over the disk’s lifetime. The migration of forming protoplanets is an unavoidable process, and it is thought to be a key ingredient for understanding the variety of extrasolar planetary systems. Although migration occurs for protoplanets of all masses, its properties for low-mass planets (those having up to a few Earth masses) differ significantly from those for high-mass planets. The torque that is exerted by the disk on the planet is composed of different contributions. While migration was first thought to be invariably inward, physical processes that are able to halt or even reverse migration were later uncovered, leading to the realization that the migration path of a forming planet has a very sensitive dependence on the underlying disk parameters. There are other processes that go beyond the case of a single planet experiencing smooth migration under the disk’s tide. This is the case of planetary migration in low-viscosity disks, a fashionable research avenue because protoplanetary disks are thought to have very low viscosity, if any, over most of their planet-forming regions. Such a process is generally significantly chaotic and has to be tackled through high-resolution numerical simulations. The migration of several low-mass planets is also is a very fashionable topic, owing to the discovery by the Kepler mission of many multiple extrasolar planetary systems. The orbital properties of these systems suggest that at least some of them have experienced substantial migration. Although there have been many studies to account for the orbital properties of these systems, there is as yet no clear picture of the different processes that shaped them. Finally, some recently unveiled processes could be important for the migration of low-mass planets. One process is aero-resonant migration, in which a swarm of planetesimals subjected to aerodynamic drag push a planet inward when they reach a mean-motion resonance with the planet, while another process is based on so-called thermal torques, which arise when thermal diffusion in the disk is taken into account, or when the planet, heated by accretion, releases heat into the ambient gas.

Telecommunication Law

Telecommunication law is a broad complex of legal rules, the aim of which is to regulate telecommunication services—the conveyance of signals by means of telecommunication networks; it also covers satellite and space research services. The utmost purpose of these norms is to enable an interference-free transmission of signals, both on a domestic and an international scale. Telecommunication law is composed of three levels of regulations: international, regional, and domestic. The international regulation is performed traditionally by states organized in the International Telecommunication Union on the basis of the ITU Constitution, Convention, and Radio Regulations; trade aspects of telecommunications are regulated by the World Trade Organization. There are several regional cooperation structures dealing with telecommunications; the telecommunication framework of the European Union can serve as an example of a highly harmonized regional regulation based on the Electronic Communication Code. Domestic telecommunication laws are adopted by sovereign states; however, the international rules and regional regulations influence their content and structure. These legal mechanisms are very useful regulatory frameworks that guarantee that telecommunication signals are conveyed to their consumers without administrative and factual obstacles. They have functioned for decades on a pragmatic basis driven mostly by technical and economic needs.

Trans-Neptunian Dwarf Planets

This is an advance summary of a forthcoming article in the Oxford Research Encyclopedia of Planetary Science. Please check back later for the full article. The International Astronomical Union (IAU) officially recognizes five objects as dwarf planets: Ceres in the main asteroid belt between Mars and Jupiter; and Pluto, Eris, Haumea, and Makemake in the trans-Neptunian region beyond the orbit of Neptune. However, the definition used by the IAU applies to many other trans-Neptunian objects (TNOs) and can be summarized as any nonsatellite large enough to be rounded by its own gravity. Practically speaking, this means any nonsatellite with a diameter >400 km. In the trans-Neptunian region, there are more than 100 objects that satisfy this definition, based on published results and diameter estimates. The dynamical structure of the trans-Neptunian region records the migration history of the giant planets in the early days of the solar system. The semi-major axes, eccentricities, and orbital inclinations of TNOs across various dynamical classes provide constraints on different aspects of planetary migration. For many TNOs, the orbital parameters are all that is known about them, due to their large distances, small sizes, and low albedos. The TNO dwarf planets are a different story. These objects are large enough to be studied in more detail from ground- and space-based observatories. Imaging observations can be used to detect satellites and measure surface colors, while spectroscopy can be used to constrain surface composition. In this way, TNO dwarf planets not only help provide context for the dynamical evolution of the outer solar system, but also reveal the composition of the primordial solar nebula as well as the physical and chemical processes at work at very cold temperatures. The largest TNO dwarf planets, those officially recognized by the IAU, plus others such as Sedna, Quaoar, and Gonggong, are large enough to support volatile ices on their surfaces in the present day. These ices are able to exist as solids and gases on some TNOs, due to their sizes and surface temperatures (similar to water ice on Earth) and include N2 (nitrogen), CH4 (methane), and CO (carbon monoxide). A global atmosphere composed of these three species has been detected around Pluto, the largest TNO dwarf planet, with the possibility of local atmospheres or global atmospheres at perihelion for Eris and Makemake. The presence of nonvolatile species, such as H2O (water), NH3 (ammonia), and organics provide valuable information on objects that may be too small to retain volatile ices over the age of the solar system. In particular, large quantities of H2O mixed with NH3 points to ancient cryovolcanism caused by internal differentiation of ice from rock. Organic material, formed through radiation processing of surface ices such as CH4, records the radiation histories of these objects as well as providing clues to their primordial surface compositions. The dynamical, physical, and chemical diversity of the >100 TNO dwarf planets are key to understanding the formation of the solar system and subsequent evolution to its current state. Most of our knowledge comes from a small handful of objects, but we are continually expanding our horizons as additional objects are studied in more detail.

Water Ice at Mid-Latitudes on Mars

This is an advance summary of a forthcoming article in the Oxford Research Encyclopedia of Planetary Science. Please check back later for the full article. Mars’ mid-latitudes (roughly 30–60° N and S) host voluminous deposits of water ice in the subsurface. At present, perennial water ice cannot exist at the surface in these regions. This is because, for a significant portion of the Martian year, surface temperatures exceed the sublimation point of water ice under Mars’ low atmospheric pressure. Therefore, any seasonal water-ice frost that accumulates in winter sublimates back into the atmosphere in spring. However, a centimeters-to-meters-thick covering of lithic material can inhibit sublimation sufficiently to allow perennial stability of ice in the subsurface. Perennial ice in Mars’ mid-latitudes exists as pore-ice and excess-ice lenses within the regolith, and as massive accumulations of buried, high-purity ice akin to debris-covered glaciers on Earth. The ice is thought to range in age from hundreds of thousands to many hundreds of millions of years old. Its emplacement and modification has been widely attributed to cyclical climate changes induced by variations in Mars’ orbital parameters (primarily its axial tilt). Water ice in Mars’ mid-latitudes is therefore of significant interest for reconstructing such climate changes. It could also provide an essential in situ supply of water for future human missions to Mars. It is possible to infer the presence of water ice in Mars’ subsurface without direct imaging of the ice itself. For example, the distribution of near-surface ice was mapped using Mars Odyssey Neutron Spectrometer detections to calculate the percentage of water-equivalent hydrogen in the upper 1 m of the regolith. Orbital images have revealed a great diversity of ice-related landforms which suggest flow, thermal cycling, sublimation, and disruption (e.g. by impact cratering) of subsurface ice. In some locations, orbital ground-penetrating radar observations have been used to confirm subsurface ice content in areas where its presence has been inferred from the geomorphology of the surface. Water ice in Mars’ mid-latitudes has also been imaged directly by landed and orbital missions. The Phoenix lander exposed water-ice lenses just centimeters beneath the surface, in trenches that it excavated at 68 °N latitude. Orbital images from the High Resolution Imaging Science Experiment (HiRISE) camera on board Mars Reconnaissance Orbiter revealed transient bright ice deposits exhumed by small, fresh impacts into mid-latitude terrains, and ~100 m-high scarps of water ice in exposures through debris-covered ice deposits. In all these cases, the exposed ice has been observed to lose mass by sublimation over time. This demonstrates the essential role of lithic cover in preserving subsurface water ice in Mars’ mid-latitudes.

Composition of Earth

Early models of the composition of the Earth relied heavily on meteorites. In all these models Earth had different layers, each layer corresponded to a different type of meteorite or meteorite component. Later, more realistic models based on analyses of samples from Earth began with Ringwood’s pyrolite composition in the 1960s. Further improvement came with the analyses of rare MgO rich peridotites from a variety of occurrences all over the Earth, as xenoliths enclosed in melts from the upper mantle or as ultramafic massifs, tectonically emplaced on the Earth’s surface. Chemical systematics of these rocks allow the determination of the major element composition of the primitive upper mantle (PUM), the upper mantle after core formation and before extraction of basalts ultimately leading to the formation of the crust. Trace element analyses of upper mantle rocks confirmed their primitive nature. Geochemical and geophysical evidence argue for a bulk Earth mantle of uniform composition, identical to the PUM, also designated as “bulk silicate Earth” (BSE). The formation of a metal core was accompanied by the removal of siderophile and chalcophile elements into the core. Detailed modeling suggests that core formation was an ongoing process parallel to the accretion of Earth. The composition of the core is model dependent and thus uncertain and makes reliable estimates for siderophile and chalcophile element concentrations of bulk Earth difficult. Improved stable isotope analyses show isotopic similarities with noncarbonaceous chondrites (NCC), while the chemical composition of the mantle of the Earth indicates similarities with carbonaceous chondrites (CC). In detail, however, it can be shown that no single known meteorite group, nor any mixture of meteorite groups can match the chemical and isotopic composition of Earth. This conclusion is extremely important for any formation model of the Earth.

Science and Exploration of the Moon: Overview

Earth’s moon, hereafter referred to as “the Moon,” has been an object of intense study since before the time of the Apollo and Luna missions to the lunar surface and associated sample returns. As a differentiated rocky body and as Earth’s companion in the solar system, much study has been given to aspects such as the Moon’s surface characteristics, composition, interior, geologic history, origin, and what it records about the early history of the Earth-Moon system and the evolution of differentiated rocky bodies in the solar system. Much of the Apollo and post-Apollo knowledge came from surface geologic exploration, remote sensing, and extensive studies of the lunar samples. After a hiatus of nearly two decades following the end of Apollo and Luna missions, a new era of lunar exploration began with a series of orbital missions, including missions designed to prepare the way for longer duration human use and further exploration of the Moon. Participation in these missions has become international. The more recent missions have provided global context and have investigated composition, mineralogy, topography, gravity, tectonics, thermal evolution of the interior, thermal and radiation environments at the surface, exosphere composition and phenomena, and characteristics of the poles with their permanently shaded cold-trap environments. New samples were recognized as a class of achondrite meteorites, shown through geochemical and mineralogical similarities to have originated on the Moon. New sample-based studies with ever-improving analytical techniques and approaches have also led to significant discoveries such as the determination of volatile contents, including intrinsic H contents of lunar minerals and glasses. The Moon preserves a record of the impact history of the solar system, and new developments in timing of events, sample based and model based, are leading to a new reckoning of planetary chronology and the events that occurred in the early solar system. The new data provide the grist to test models of formation of the Moon and its early differentiation, and its thermal and volcanic evolution. Thought to have been born of a giant impact into early Earth, new data are providing key constraints on timing and process. The new data are also being used to test hypotheses and work out details such as for the magma ocean concept, the possible existence of an early magnetic field generated by a core dynamo, the effects of intense asteroidal and cometary bombardment during the first 500 million–600 million years, sequestration of volatile compounds at the poles, volcanism through time, including new information about the youngest volcanism on the Moon, and the formation and degradation processes of impact craters, so well preserved on the Moon. The Moon is a natural laboratory and cornerstone for understanding many processes operating in the space environment of the Earth and Moon, now and in the past, and of the geologic processes that have affected the planets through time. The Moon is a destination for further human exploration and activity, including use of valuable resources in space. It behooves humanity to learn as much about Earth’s nearest neighbor in space as possible.