Fast and stable vapochromic response induced through nanocrystal formation of a luminescent platinum(II) complex on periodic mesoporous organosilica

A hybrid vapoluminescent system exhibiting fast and repeatable response was constructed using periodic mesoporous organosilica with bipyridine moieties (BPy-PMO) and a Pt(II) complex bearing a potentially luminescent 2-phenylpyridinato (ppy) ligand. An intense red luminescence appeared when the Pt(II)-complex immobilised BPy-PMO was exposed to methanol vapour and disappeared on exposure to pyridine vapour. The ON-OFF vapochromic behaviour occurred repeatedly in a methanol/pyridine/heating cycle. Interestingly, a rapid response was achieved in the second cycle and cycles thereafter. Scanning and transmission electron microscopies (SEM/TEM), absorption and emission, and nuclear magnetic resonance spectroscopies, mass spectrometry, and powder X-ray diffraction indicated that methanol vapour induced Si-C cleavage and thus liberated [Pt(ppy)(bpy)]Cl (bpy = 2,2′-bipyridine) from the BPy-PMO framework. Furthermore, the self-assembling properties of the Pt(II) complex resulted in the formation of highly luminescent micro/nanocrystals that were homogeneously dispersed on the porous support. The unique vapoluminescence triggered by the unprecedented protodesilylation on exposure to protic solvent vapour at room temperature is attributable to BPy-PMO being a giant ligand and an effective vapour condenser. Consequently, this hybrid system presents a new strategy for developing sensors using bulk powdery materials.

Enhanced vapour sensing using silicon nanowire devices coated with Pt nanoparticle functionalized porous organic frameworks

Silicon nanowires functionalized with metalized porous organic frameworks exhibit superior sensing properties for methanol vapour detection.

Turbulent film condensation in a vertical tube in presence of non condensable gas

This paper presents the simulation of the condensation of methanol vapour in the presence of non-condensable gas in turbulent flows in a vertical tube. The liquid and gas stream are approached by two coupled turbulent boundary layer. For solving the coupled governing equations for liquid film and gas flow together with the interfacial matching conditions an implicit finite difference method is employed. The effect of the influencing parameters are studied so the effect of inlet Reynolds number, the effect of temperature gradient, mass fraction are illustrated. The numerical results demonstrate that an important concentration of no-condensable gas reduces the heat transfer coefficient and film thickness considerably. The local heat flux and film thickness increase as tube surface temperature decreases at any bulk concentration of non-condensable gas. Moreover, inlet velocity increases as film thickness decreases and heat flux increases.