On the Electron Impact Integral Cross-Sections for Butanol and Pentanol Isomers

The need for a reliable and comprehensive database of cross-sections for many atomic and molecular species is immense due to its key role in R&D domains such as plasma modelling, bio-chemical processes, medicine and many other natural and technological environments. Elastic, momentum transfer and total cross-sections of butanol and pentanol isomers by the impact of 6–5000 eV electrons are presented in this work. The calculations were performed by employing the spherical complex optical potential formalism along with single-centre expansion and group additivity rule. The investigations into the presence of isomeric variations reveal that they are more pronounced at low and intermediate energies. Elastic, total cross-sections (with the exception of n-pentanol) and momentum transfer cross-sections for all pentanol isomers are reported here for the first time, to the best of our knowledge. Our momentum transfer cross-sections for butanol isomers are in very good agreement with the experimental and theoretical values available, and in reasonable consensus for other cross-sections.

Study of The Tool Path Generation Method of an Ultra-Precision Spherical Complex Surface Based on a Five-Axis Machine Tool

The improvement of ultra-precision machining technology has significantly boosted the demand for the surface quality and surface accuracy of the workpieces to be machined. However, the geometric shapes of workpiece surfaces cannot be adequately manufactured with simple plane, cylindrical, or spherical surfaces because of their different applications in various fields. In this research, a method was proposed to generate tool paths for the machining of complex spherical surfaces based on an ultra-precise five-axis turning and milling machine with a C-Y-Z-X-B structure. Through the proposed tool path generation method, ultra-precise complex spherical surface machining was achieved. First, the complex spherical surface model was modeled and calculated, and then it was combined with the designed model to generate the tool path. Then the tool paths were generated with a numerically controlled (NC) program. Based on an ultra-precision three-coordinate measuring instrument and a white light interferometer, the machining accuracy of a workpiece surface was characterized, and t[1]he effectiveness of the provided tool path generation method was verified. The surface roughness of the machined workpiece was less than 90 nm. Furthermore, the surface roughness within the spherical region appeared to be less than 30 nm. The presented tool path generation method in this research produced ultra-precision spherical complex surfaces. The method could be applied to complex spherical surfaces with other characteristics.

Differential and integral cross sections for electron elastic scattering by ammonia for incident energies ranging from 10 eV to 20 keV

Differential and integral cross sections for elastic scattering of electron by NH3 molecule are investigated for the energy ranging from 10 eV to 20 keV. The calculations are carried out in the framework of partial wave formalism describing the target molecule by means of one center molecular Hartree-Fock functions. A spherical complex optical potential used includes a static part – obtained here numerically from quantum calculation – and fine effects like correlation, polarization and exchange potentials. The results obtained in this model point out clearly the role played by the exchange and the correlation-polarization contributions in particular at lower scattering angles and lower incident energies. Both differential and integral cross sections obtained are compared with a large set of experimental data available in the literature and well agreement is found throughout the scattering angles and whole energy range investigated here.