Random walks and diffusion provide our most basic example of how new laws emerge in statistical mechanics. Random walks have fractal properties, with fluctuations on all scales. The microscopic nature of the random steps is unimportant to the emergent fractal behavior. The diffusion equation is the law which emerges when many random walks are combined; it describes the evolution of any locally conserved density at macroscopic distances and times. The chapter introduces powerful Fourier and Green’s function methods for solving for the resulting behavior. Exercises explore this emergence, with applications to perfume, polymers, stock markets, the Sun, bacteria, and flocking of animals.