Multifunctional Viologen-Derived Supramolecular Network with Photo/Vapochromic and Proton Conduction Properties

A supramolecular network [H4bdcbpy(NO3)2·H2O] (H4bdcbpy = 1,1′-Bis(3,5-dicarboxybenzyl)-4,4′-bipyridinium) (1) was prepared by a zwitterionic viologen carboxylate ligand in hydrothermal synthesis conditions. The as-synthesized (1) has been well characterized by means of single-crystal/powder X-ray diffraction, elemental analysis, thermogravimetric analysis and infrared and UV-vis spectroscopy. This compound possesses a three-dimensional supramolecular structure, formed by the hydrogen bond and π–π interaction between the organic ligands. This compound shows photochromic properties under UV light, as well as vapochromic behavior upon exposure to volatile amines and ammonia, in which the electron transfer from electron-rich parts to the electron-deficient viologen unit gives rise to colored radicals. Moreover, the intensive intermolecular H-bonding networks in 1 endows it with a proton conductivity of 1.06 × 10−3 S cm−1 in water at 90 °C.

Coordination-based vapochromic behavior of a luminescent Pt(ii) complex with potassium ions

A luminescent Pt(ii) complex with potassium ions was successfully synthesized and its coordination-based vapochromic behavior was investigated.

Unique vapochromism of a paddlewheel-type dirhodium complex accompanied by dynamic structural and phase transitions

Paddlewheel-type dirhodium complex exhibits highly selective vapochromic behavior in response to pyridine vapor and undergoes dynamic structural and phase transitions.

Understanding the vapochromic response of mixed copper(i) iodide/silver(i) Iodide nanoparticles toward dimethyl sulfide

We report on the vapochromic behavior of a series of homo- and heterometallic copper(i) iodide/silver(i) iodide nanoparticles when exposed to dimethyl sulfide (DMS) vapor.