Influence of titanium and zirconium on structure and heat-resistance of low-carbon iron-aluminium alloys

The paper considers the effect of introducing ferroalloys containing titanium and zirconium on the structure and heat-resistance of low-carbon ferroalloys. Theoretically and experimentally, it has been proven that addition of 1.0 mass. % of titanium and 0.1 mass. % of zirconium to a low-carbon iron-aluminum melt containing 12 – 14 mass. % of aluminum, grinds its structure increasing temporary resistance and heat-melting. Titanium and zirconium are strong carbide-forming elements. When introduced into a low-carbon iron-aluminium alloy, they form a large number of crystallization centers, thus affecting its microstructure, allowing to get shredded and more equal grain compared to an alloy without additive. This in turn increases the strength limit of processed alloy. In addition, the use of titanium as a modifying additive in a low-carbon ferroalloy allows increasing its heatresistance, which exceeds several times the heat-resistance of famous chrome-nickel steel of 20Kh23N18 grade. As a result, a new technology for obtaining titanium and zirconium was developed based on research of the effect of their modifying additives on the structure and heat-resistance of low-carbon iron-aluminum alloys.

Complex Technology of Ash and Slag Waste from Power Plants

The development of a comprehensive technology for the processing of ash waste (ASW), which is based on the extraction of carbon from the CSO by flotation method and iron-containing minerals by means of magnetic separation, is presented. The proposed approach is based on the extraction of carbon from ash and slag by flotation and iron-containing minerals by magnetic separation. In this work, the optimal size of the ash fraction supplied for flotation was established. It is shown that when the technological process is carried out according to the stadium scheme when flotation reagents are fed in fractions, it allows their consumption to be reduced and the recovery of carbon concentrate from underburning to be significantly increased. The developed technology was tested on a pilot plant. High-quality carbon, iron-containing and aluminosilicate products were obtained. Auxiliary enrichment processes such as classification, thickening and filtration were tested.

Modeling cometabolism of hexavalent chromium by iron reducing bacteria in tertiary substrate system

In this study, a bacterial strain Serratia sp. was employed for the reduction of synthetically prepared different concentration of Cr(VI) solution (10, 25, 40, 50 and 100 mg/L). Cometabolism study have been carried out in the binary substrate system as well as in the tertiary substrate system. The results revealed that when glucose was added as a co-substrate, at low Cr(VI) concentration, complete reduction was achieved followed by increased biomass growth, but when Cr(VI) concentration was increased to 100 mg/L, the reduction decline to 93%. But in presence of high carbon iron filings (HCIF) as co-substrate even at higher Cr(VI) concentration i.e. 100 mg/L, 100% reduction was achieved and the cell growth continued till 124 h. The study was illustrated via Monod growth kinetic model for tertiary substrate system and the kinetic parameters revealed that the HCIF and glucose combination showed least inhibition to hexavalent chromium reduction by Serratia sp.