Gaivoron—Zavallia section of the Middle Pobuzhzhіa is the most representative part of the granulite complex of the Ukrainian Shield (structural-tectonophysical results and magnetometric studies)

In the article according to the geological and geophysical data of the well-exposed areas of development of Archean rocks of the Ukrainian Shield, two alternative approaches to establishing the structure and stratigraphy of the oldest granulite complexes are discuss. The outcrops of the enderbite-gneiss complex up to 3.6—3.8 billion years old are located along the Southern Bug River between the Gaivoron town and the Zavallia village. The first, «stratigenic-metamorphogenic» approach assumes that the main features of the composition and structure of the Lower Archean complexes are inherited from the original stratotypic strata. These strata are transformed in the conditions of quasi-isochemical metamorphism with preservation of the sequence of formation in section and the primary constitution in the form of stratification, rhythmicity, direction of change of their composition vertically and laterally. On the structural-formation map and geological section of the Gaivoron—Zavallia section, the Archean granulite complex is shown in the form of a synclinorium composed of four adjacent formations, which are equated to the world of metamorphosed volcanic-sedimentary rocks. The second, «deformation-metamorphogenic» approach, which is supported by the authors of this article, is based on the idea that the granulite complex of Pobuzhzhіa is a subvertically layered medium formed by tangential tectonic forces. The latter lead to shear deformations and displacement of matter at the atomic-molecular (with mineral transformation of rocks) and rock masses at the regional level. This creates structural and textural elements that are superimposed on the primary structure of rocks and often erase it. Field structural-tectonophysical, tectonofacial and magnetometric studies, its results are presented in the article. It was performed specifically to compare these two concepts. Magnetometric studies have shown that the enderbite-gneiss complex of the district by its magnetic characteristics belongs to the middle and lower crust of the Ukrainian Shield.

Iron- and Nickel Enriched Olivine from Phlogopite Harzburgite of the Bug Granulite Complex (Ukrainian Shield)

An abundance of the trace elements has been determined in olivine of the Archean spinel-bearing phlogopite harzburgite enclave (sample UR17/2) from the Bug granulite complex of the Ukrainian Shield by SIMS analysis. Major elements were analyzed in the olivine by SEM-EDS and EPMA analysis. The olivine shows a homogeneous chemical composition: MgO — 45.20—45.64 wt.%, FeO — 13.66—14.23 wt.%, with Fo85—86 and Fe/Mn ratio of 68.3—68.6 which corresponds to the ratio of 60—70 in olivine of peridotites. Ni content in the UR17/2 olivine ranges from 4730 to 5612 ppm, which is higher than in olivine from mantle peridotites, high magnesium OIB and Hawaiian picrites. The olivine has average content of Ti — 20.6 ppm, Nb — 0.03 ppm, Zr — 0.32—0.60 ppm, the low total REE (0.1—0.5 ppm). The olivine crystallization temperature, calculated using an Al-in-olivine thermometer, corresponds to ~ 900°C. Enrichment in Fe and Ni is the main feature that distinguishes the UR17/2 olivine from other mantle-derived olivine. Сomposition of the UR17/2 olivine and host harzburgite indicates an influence of T, P, the oxygen fugacity and composition of parent magma on the partition coefficients of Fe and Ni. Сomposition and structure (degree of polymerization) of magma are the main factors responsible for the olivine enrichment by iron and nickel.

Trace Elements in Apatite as Genetic Indicators of the Evate Apatite-Magnetite Deposit, NE Mozambique

The Evate deposit is a Neoproterozoic (~590 Ma) magnetite-apatite-carbonate body emplaced parallel to foliation of the Monapo granulite complex in NE Mozambique. A complicated history of the deposit is recorded in apatite textures visualized in cathodoluminescence (CL) images. In spite of different solid and fluid inclusions, mineral assemblages, and the CL textures, electron probe microanalyses indicate relatively consistent apatite compositions corresponding to fluorapatite (XF = 0.51–0.73, XOH = 0.21–0.47, XCl = 0.02–0.06) with limited belovite- and cesanite-type substitutions. Laser ablation inductively coupled plasma mass spectrometric analyses show that apatites from unaltered magnetite-forsterite-spinel ores are depleted in Y, REE, Ba, and Sr compared to apatites from carbonate-anhydrite ores. Hydrothermally overprinted apatites with complex patchy domain CL textures are enriched in Y-REE in greenish-grey zones, Fe-U-Th in blue zones, and Mn-Sr-Ba in brown domains. Observed CL-emissions in the Evate apatites result from very subtle variations in REE, Mn, and U contents controlled by the variability of redox conditions. The decreased Th:U ratio in the hydrothermally overprinted apatites reflects the oxidation and partial removal of U4+ from the apatite structure during the interaction with oxidizing aqueous fluids capable of transporting U6+. Flat, LREE (La-Sm)-enriched chondrite-normalized patterns with Eu/Eu* = 0.7–1.4 and Ce/Ce* = 0.9–1.5, together with concentrations of diagnostic trace elements (Sr, Mn, Y, REE) are consistent with apatites from magmatic carbonatites and phoscorites. This study corroborates that the Evate deposit is a post-collisional orogenic carbonatite genetically linked with mafic plutonic rocks intruding the Monapo granulite complex after granulite-facies metamorphism, and later overprinted by intensive hydrothermalism. The Evate apatite is peculiar in retaining its pristine magmatic signature despite the extensive hydrothermal-metasomatic alteration accompanied by dissolution-reprecipitation.