Igneous Rock Associations 28. Construction of a Venusian Greenstone Belt: A Petrological Perspective

The crustal evolution of Venus appears to be principally driven by intraplate processes that may be related to mantle upwelling as there is no physiographic (i.e. mid-ocean ridge, volcanic arc) evidence of Earth-like plate tectonics. Rocks with basaltic composition were identified at the Venera 9, 10, 13, and 14, and Vega 1 and 2 landing sites whereas the rock encountered at the Venera 8 landing site may be silicic. The Venera 14 rock is chemically indistinguishable from terrestrial olivine tholeiite but bears a strong resemblance to basalt from terrestrial Archean greenstone belts. Forward petrological modeling (i.e. fractional crystallization and partial melting) and primary melt composition calculations using the rock compositions of Venus can yield results indistinguishable from many volcanic (ultramafic, intermediate, silicic) and plutonic (tonalite, trondhjemite, granodiorite, anorthosite) rocks that typify Archean greenstone belts. Evidence of chemically precipitated (carbonate, evaporite, chert, banded-iron formation) and clastic (sandstone, shale) sedimentary rocks is scarce to absent, but their existence is dependent upon an ancient Venusian hydrosphere. Nevertheless, it appears that the volcanic–volcaniclastic–plutonic portion of terrestrial greenstone belts can be constructed from the known surface compositions of Venusian rocks and suggests that it is possible that Venus and Early Earth had parallel evolutionary tracks in the growth of proto-continental crust.

Seismic reflections from a lithospheric suture zone below the Archaean Yilgarn Craton

Seismic reflectors in the uppermost mantle, which can indicate past plate tectonic subduction, are exceedingly rare below Archaean cratons, and restricted to the Neoarchaean. Here we present reprocessed seismic reflection profiles from the northwest Archaean Yilgarn Craton and the Palaeoproterozoic Capricorn Orogen of western Australia that reveal the existence of a ~4 km thick south-dipping band of seismic reflectors that extends from the base of the Archaean crust to at least 60 km depth. We interpret these reflectors, which lie south of a ~50 km deep crustal root, as a relict suture zone within the lithosphere. We suggest that the mantle reflectors were created either by subduction of an oceanic plate along the northern edge of the Yilgarn Craton, which started in the Mesoarchaean and produced the rocks in northern Yilgarn greenstone belts that formed in a supra-subduction zone setting, or, alternatively, by underthrusting of continental crust deep into the lithosphere during the Palaeoproterozoic.

The Paleoarchean and Mesoarchean TTGs of the western Azov area, the Ukrainian Shield

A large anticline structure occurs in the western part of the Azov Domain of the Ukrainian Shield. It is composed of rocks of the Mesoarchean (3.2-3.0 Ga) granite-greenstone association and relics of an older basement. The anticline is divided into two parts by the Bilotserkivka structure of sub-latitudinal strike. The northern part includes the Huliaipole and Remivka blocks, and the southern part comprises the Saltycha anticline. The U-Pb age of plagiogneisses of the Lantsevo anticline of the Bilotserkivka structure is 3299 ± 11 Ma. In terms of geochemical characteristics, they correspond to TTGs. In the western part of the Bilotserkivka structure, we previously identified quartz diorites having an age of 3297 ± 22 Ma. These data show that the Bilotserkivka structure represents an ancient basement. Dislocated trondhjemites were studied in the Ivanivka area at the eastern part of the Saltycha anticline. They contain numerous relics of heavily altered amphibolites. The U-Pb age of zircons from trondhjemite is 3013 ± 15 Ma. These rocks are of the same age as TTGs of the Shevchenko Complex cutting through the sedimentary- volcanogenic rocks of the greenstone structures of the Azov Domain. They share age and geochemical characteristics with biotite and amphibole-biotite gneisses of the “Kainkulak beds” in the Zrazkove village located at the Mokra Konka river (3.1-3.0 Ga) and with biotite gneisses in the lower reaches of the Kainkulak river (2.92 Ga). Thus, gneisses of the “Kainkulak beds” actually represent the Mesoarchean TTGs of the Shevchenko Complex, transformed in the Paleoproterozoic time due to the dislocation metamorphism. The late Paleoarchean (3.3 Ga) tonalites are known in the West Azov and KMA domains; they probably also occur in the basement of the Middle Dnieper domains, where detrital zircons of this age have been reported. These data allow us to assume the existence of a large Late Paleoarchean (3.3 Ga) protocraton, in which the Mesoarchean (3.2-3.0 Ga) greenstone belts and TTGs of the eastern part of the Ukrainian Shield and the KMA Domain were formed.

THE PALEOARCHEAN (3.3 Ga) AND MESOARCHEAN (3.0 Ga) TTGs OF THE WESTERN AZOV AREA, THE UKRAINIAN SHIELD

A large anticline structure that includes the West Azov and Remivka blocks occurs in the western part of the Azov Domain of the Ukrainian Shield. These blocks are composed of rocks of the Mesoarchean (3.2-3.0 Ga) granite-greenstone association and relics of an older basement. The anticline is divided into two parts by the Bilotserkivka structure of sub-latitudinal strike; the northern part includes the Huliaipole and Remivka blocks, and the southern part is comprised of the Saltycha anticline. The Archean plagiogranitoids of the West Azov underwent intense dislocation metamorphism during the Paleoproterozoic. In many areas they were transformed into plagioclase gneisses that were attributed to the Paleoarchean “Kainkulak thickness” of the Azov Series. Detailed geological-structural and geochronological studies are required to define the age of these gneisses.We have chosen two areas for our studies: the Lantsevo anticline within the Bilotserkivka structure, and the Ivanivka area in the eastern part of the Saltycha anticline. The Bilotserkivka structure is composed of rocks of the Central Azov Series and highly deformed Archean formations. We have dated plagiogneisses of the Lantsevo anticline. These rocks contain large relics of metamorphic rocks of unknown age, including two-pyroxene and pyroxene crystalline schists, and pyroxenemagnetite quartzites (BIF). In terms of chemical composition, two-pyroxene crystalline schists correspond to tholeiitic basalts and basaltic komatiites. Ferruginous-siliceous rocks belong to the Algoma type typical for the Archean greenstone belts. Biotite gneisses are similar to the medium-pressure tonalite-trondhjemite-granodiorite rocks (TTGs). The U-Pb age of zircon crystallization from biotite gneisses is 3299 ± 11 Ma. At 30 km in the western part of the Bilotserkivka structure, we have previously identified quartz diorites having an age of 3297 ± 22 Ma. In terms of geochemical characteristics, they correspond to low-pressure TTGs. These data show that the Bilotserkivka structure is a block representing an ancient basement. In the Ivanivka area in the eastern part of the Saltycha anticline, the strike of the Archean rocks was reorientated from northwestern to latitudinal. The studied dislocated trondhjemites of the Ivanivka area correspond to TTGs in terms of the geochemical characteristics. They contain numerous relics of highly altered amphibolites. The U-Pb age of zircon crystallization from trondhjemite is 3013 ± 15 Ma. These rocks are of the same age as TTGs of the Shevchenko Complex cutting through the sedimentary-volcanogenic rocks of the greenstone structures of the Azov Domain. They share age and geochemical characteristics with biotite and amphibole-biotite gneisses of the “Kainkulak thickness” in Zrazkove village located at the Mokra Konka river (3.1-3.0 Ga) and with biotite gneisses in the lower reaches of the Kainkulak river (2.92 Ga). Thus, gneisses of the “Kainkulak thickness” in fact represent the Mesoarchean TTGs of the Shevchenko Complex, which were transformed in the Paleoproterozoic time due to the dislocation metamorphism. Late Paleoarchean (3.3 Ga) tonalites are known in the West Azov and the KMA domains; they probably also occur in the basement of the Middle Dnieper domains, where detrital zircons of this age have been reported. These data allow us to conclude the existence of a large Late Paleoarchean (3.3 Ga) protocraton, in which the Mesoarchean (3.2-3.0 Ga) greenstone belts and TTGs of the eastern part of the Ukrainian Shield and the KMA Domain were formed.

Paragenesis of gold mineralization at the Kiyuk Lake Project, Kivalliq Region, Nunavut, Canada

ABSTRACT Exploration for gold in Nunavut has been primarily focused on Archean greenstone belts in the north and coastal regions of the territory, resulting in large areas of underexplored terrain in the south. The Kiyuk Lake property is located in the underexplored southwest corner of the Kivalliq Region of Nunavut within the Hearne domain of the ∼1.9 Ga western Churchill Province. The property is hosted by Proterozoic calc-silicate and clastic sedimentary units of the Hurwitz Group (<2.4–1.9 Ga) and the unconformably overlying Kiyuk Group (1.9–1.83 Ga). Gold mineralization in Proterozoic sedimentary rocks is rare in the Canadian Shield, so the Rusty Zone at Kiyuk Lake presents a unique opportunity to study the enigmatic gold mineralization hosted in such sedimentary rocks. Mineralization at the Rusty Zone is hosted by an immature lithic wacke cut by thin intermediate dikes that are associated with hydrothermal breccias composed of Fe-carbonate, calcite, calcic-amphibole, Fe-sulfide, Fe-oxide minerals, and gold. Textural and timing relationships suggest that the gold mineralization is post-sedimentary and syn- to post-intrusion of intermediate dikes. Stable isotope thermometry suggests that mineralization took place between 450 and 600 °C, and geochronological studies indicate that the intrusion and mineralization occurred before or about 1.83 Ga. Using basement breaching thrusts faults as conduits to the surface, over-pressurization along a later normal fault is thought to be the primary cause for the localized breccia pipe that controls gold mineralization. The hydrothermal fluids are postulated to be volatile-rich aqueous solutions exsolved from a source of cooling magmas at depth. Although sub-economic at present, the occurrence of high-grade gold in a Paleoproterozoic basin such as Kiyuk Lake could signal a new opportunity for exploration for gold in the Canadian Shield.

Petrogenesis and mode of emplacement of a Neoarchean tonalite-trondhjemite-diorite (TTD) suite: the Eau Jaune Complex, Abitibi greenstone belt

Magmatism during the maturation phase of Archean greenstone belts produced voluminous tonalite-trondhjemite-granodiorite (TTG) suites, as well as a lesser amount of tonalite-trondhjemite-diorite (TTD) suites. Such TTD suites have recently been recognized in the Archean Abitibi greenstone belt, on the southern flank of the Superior Craton, Canada, but their source(s), differentiation processes and depths of emplacement remain poorly constrained. The Neoarchean Eau Jaune Complex (EJC) lies in the northeastern corner of the Abitibi greenstone belt and represents one of the most voluminous tonalite-dominated and diorite-bearing intrusive suites of the Chibougamau region. This TTD suite comprises six intrusive phases with distinct petrology and chemistry. All units were emplaced as laccolith-like intrusions injected along discontinuities within the volcanic succession at ca. 2724 Ma (U-Pb zircon dating), during the synvolcanic interval (i.e., construction and maturation phase), at a depth of approximately 7–8 km. The most HREE-depleted phases (granodiorite, tonalite and trondhjemite) correspond to magmas that fractionated amphibole and were likely produced by partial melting of a garnet- and titanate-bearing amphibolite, akin to TTG magmas. The least HREE-depleted phases are dioritic in composition and correspond to mantle-derived magmas that may have interacted with TTG melts. This indicates interaction between coeval mantle-derived and crustal melts during the maturation phase of the Abitibi greenstone belt. Models formulated to address the geodynamic evolution of greenstone belts must account for the coeval production of basalt-derived (TTG suites) and mantle-derived (tholeiitic magmatism) melts occasionally interacting to form TTD suites.

Tellurium and Selenium Mineralogy of Gold Deposits in Northern Fennoscandia

Mineralization of Te and Se was found in gold deposits and uranium occurrences, located in the Paleoproterozoic greenstone belts in Northern Fennoscandia. These deposits are of different genesis, but all of them formed at the late stages of the Svecofennian orogeny, and they have common geochemical association of metals Au, Cu, Co, U, Bi, Te, and Se. The prevalentTe minerals are Ni and Fe tellurides melonite and frohbergite, and Pb telluride altaite. Bismuth tellurides were detected in many deposits in the region, but usually not more than in two–three grains. The main selenide in the studied deposits is clausthalite. The most diversified selenium mineralization (clausthalite, klockmannite, kawazulite, skippenite, poubaite) was discovered in the deposits, located in the Russian part of the Salla-Kuolajarvi belt. Consecutive change of sulfides by tellurides, then by selenotellurides and later by selenides, indicates increase of selenium fugacity, fSe2, in relation to fTe2 and to fS2in the mineralizing fluids. Gold-, selenium-, and tellutium-rich fluids are potentially linked with the post-Svecofennian thermal event and intrusion of post-orogenic granites (1.79–1.75 Ga) in the Salla-Kuolajarvi and Perapohja belts. Study of fluid inclusions in quartz from the deposits in the Salla-Kuolajarvi belt showed that the fluids were high-temperature (240–>300 °C) with high salinity (up to 26% NaCl-eq.). Composition of all studied selenotellurides, kawazulite-skippenite, and poubaite varies significantly in Se/Te ratio and in Pb content. Skippenite and kawazulite show the full range of Se-Te isomorphism. Ni-Co and Co-Fe substitution plays an important role in melonite and mattagamite: high cobalt was detected in nickel telluride in the Juomasuo and Konttiaho, and mattagamites from Ozernoe and Juomasuo contain significant Fe.In the Ozernoe uranium occurrence, the main mineral-concentrator of selenium is molybdenite, which contains up to 16 wt.% of Se in the marginal parts of the grains. The molybdenite is rich in Re (up to 1.2 wt.%), and the impurity of Re is irregularly distributed in molybdenite flakes and spherulites.