Physicochemical Characterization of an Exopolysaccharide Produced by Lipomyces sp. and Investigation of Rheological and Interfacial Behavior

The present study aimed to evaluate the rheological and interfacial behaviors of a novel microbial exopolysaccharide fermented by L. starkeyi (LSEP). The structure of LSEP was measured by LC-MS, 1H and 13C NMR spectra, and FT-IR. Results showed that the monosaccharide composition of LSEP was D-mannose (8.53%), D-glucose (79.25%), D-galactose (7.15%), and L-arabinose (5.07%); there existed the anomeric proton of α-configuration and the anomeric carbon of α- and β-configuration; there appeared the characteristic absorption peak of the phosphate ester bond. The molecular weight of LSEP was 401.8 kDa. The water holding capacity (WHC, 2.10 g/g) and oil holding capacity (OHC, 12.89 g/g) were also evaluated. The results of rheological properties showed that the aqueous solution of LSEP was a non-Newtonian fluid, exhibiting the shear-thinning characteristics. The adsorption of LSEP can reduce the interfacial tension (11.64 mN/m) well and form an elastic interface layer at the MCT–water interface. Such functional properties make LSEP a good candidate for use as thickener, gelling agent, and emulsifier to form long-term emulsions for food, pharmaceutical, and cosmetic products.

The problem of the partial delamination of the elastic interface thin inclusion in the conditions of longitudinal shear of the bimaterial

The problem of longitudinal displacement of a bi -material with a thin inclusion of arbitrary physical and mechanical nature at the interface of the matrix materials is considered. The bulk is loaded by normal compression and various force factors in the longitudinal direction. The possibility of partial delamination of a part of the boundary between the inclusion and the matrix, where dry friction slip occurs, is assumed. A complete system of equations for the formulated problem is constructed. It is proposed to construct the solution using the structural modular method of jump functions, a description of which is given. A condition for the appearance of a slip zone on the inclusion-matrix boundary is founded. A convergent iterative algorithm for numerically analytical determination of the size of this zone is developed.

Creep Motion of Elastic Interfaces Driven in a Disordered Landscape

The thermally activated creep motion of an elastic interface weakly driven on a disordered landscape is one of the best examples of glassy universal dynamics. Its understanding has evolved over the past 30 years thanks to a fruitful interplay among elegant scaling arguments, sophisticated analytical calculations, efficient optimization algorithms, and creative experiments. In this article, starting from the pioneer arguments, we review the main theoretical and experimental results that lead to the current physical picture of the creep regime. In particular, we discuss recent works unveiling the collective nature of such ultraslow motion in terms of elementary activated events. We show that these events control the mean velocity of the interface and cluster into “creep avalanches” statistically similar to the deterministic avalanches observed at the depinning critical threshold. The associated spatiotemporal patterns of activated events have been recently observed in experiments with magnetic domain walls. The emergent physical picture is expected to be relevant for a large family of disordered systems presenting thermally activated dynamics.