Investigating exospheric Na distributions at different spatial scales to disentangle between single and double peaked global patterns

<p>Since mid ‘80s the Na exosphere of Mercury has been investigated by means of both ground-based observations and spacecraft measurements, showing a wide range of variability from tens of minutes up to seasonal variations along the planetary orbit. It has been shown that the most common Na distribution is characterized by a high latitude double peak probably related to solar wind ion precipitation through the polar cusps. However, the existence of a single peaked equatorial Na emission has been frequently observed too. Generally, it is not straightforward to recognize the contributions due to different surface release processes that produces the observed Na exospheric global image.</p> <p>Here we apply the Multivariate Empirical Mode Decomposition (MEMD) to a dataset of images of the exospheric Na emission collected by the THEMIS ground-based telescope with the goal to disentangle the different contributions operating at different scales that are expected to be responsible of the occurrence of single vs. double peaked emissions or exospheric asymmetries. In particular, we found the existence of a wide range of scales characterizing both type of spatial patterns, ranging from small scales (less than 0.5 Mercury radii) up to large scales (about 1-2 Mercury radii). These scale-dependent patterns can be linked to different source mechanisms as the variability of solar wind magnetic field, different surface release mechanisms (thermal desorption, photon-stimulated desorption, micrometeoroid impact vaporization and ion-sputtering), as well as, to the whole Na exosphere surrounding the Hermean environment. Our conclusions are double checked by applying the MEMD both on Na exospheric measurements and on simulations of the Na exosphere as created by the different source mechanisms. The positive results show the great potential of the MEMD technique to study the complex environment of planetary exospheres and recognize the different components/processes that create it.</p>

Photolysis of diatomic molecules as a source of atoms in planetary exospheres

We calculated the cross sections of photolysis of OH, LiO, NaO, KO, HCl, LiCl, NaCl, KCl, HF, LiF, NaF, and KF molecules using quantum chemistry methods. The maximal values for photolysis cross sections of alkali metal monoxides are on the order of 10−18 cm2. The lifetimes of photolysis for quiet Sun at 1 astronomical unit are estimated as 2.0 × 105, 28, 5, 14, 2.1 × 105, 225, 42, 52, 2 × 106, 35 400, 486, and 30 400 s for OH, LiO, NaO, KO, HCl, LiCl, NaCl, KCl, HF, LiF, NaF, and KF, respectively. We performed a comparison between values of photolysis lifetimes obtained in this work and in previous studies. Based on such a comparison, our estimations of photolysis lifetimes of OH, HCl, and HF have an accuracy of about a factor of 2. We determined typical kinetic energies of main peaks of photolysis-generated metal atoms. Impact-produced LiO, NaO, KO, NaCl, and KCl molecules are destroyed in the lunar and Hermean exospheres almost completely during the first ballistic flight, while other considered molecules are more stable against destruction by photolysis.