Bifurcating reactions: distribution of products from energy distribution in a shared reactive mode

Reactive Mode Composition Factor (RMCF) analysis is a powerful tool to forecast the product distribution of bifurcating reactions through analysis of the kinetic energy distribution within the first transition state traversed by the reacting system.

Analysis of Droplet Characteristics and Kinetic Energy Distribution for Fixed Spray Plate Sprinkler at Low Working Pressure

HighlightsAn experiment was conducted to investigate the hydraulic performance of a fixed spray plate sprinkler (FSPS).A model was developed for estimating the cumulative kinetic energy of the FSPS under a moving system.The droplet characteristics and kinetic energy distribution were affected by the working pressure and FSPS structure.A high cumulative kinetic energy could lead to a low water infiltration rate into the soil.Abstract. The kinetic energy of droplets from a fixed spray plate sprinkler (FSPS) has a substantial influence on runoff and soil erosion, as well as on the energy consumption of moving sprinkler irrigation systems. To determine the droplet characteristics and kinetic energy of an FSPS, an experiment was conducted to investigate the effects of working pressure, plate structure, and nozzle size on the droplet diameter, velocity, and kinetic energy. Two plates (the FSPSB with a concave trajectory and deep grooves in the blue plate, and the FSPSY with a flat trajectory and shallow grooves in the yellow plate) were used in the tests. The cumulative kinetic energy and water depth were calculated for a single sprinkler moving in a straight line. The results show that the FSPSB, which had deeper grooves in the plate, produced a larger droplet diameter than the FSPSY, with shallow grooves in the plate. The droplet landing velocities presented a logarithmic relationship with the droplet diameter, and velocities increased with an increase in droplet diameter. The peak specific power (SP) value of the FSPSB was 1.14 to 16.76 times that of the FSPSY. When the working pressure was less than 150 kPa, the peak SP of the FSPSB remained at a high level. With an increase in working pressure, the peak SP of the FSPSB initially increased and then decreased, while the peak SP of the FSPSY increased. The cumulative kinetic energy of the FSPSB was higher than that of the FSPSY under mobile spray conditions. Compared with the cumulative water depth, the cumulative kinetic energy of the FSPSB increased and then decreased as the working pressure increased for the same applied water volume. Because the soil had a lower infiltration rate under the FSPSB, surface ponding was more likely to occur with the FSPSB than with the FSPSY at low working pressure. Keywords: Cumulative kinetic energy, Droplet size, Specific power, Sprinkler irrigation, Working condition.

The H2+ + HD reaction at low collision energies: H3+/H2D+ branching ratio and product-kinetic-energy distributions

The reactions between H2+ and HD forming H3+ + D as well as H2D+ + H were measured at collision energies between 0 and kB·30 K and a resolution of 75 mK and the H3+/H2D+ product branching ratio and the product kinetic-energy distribution were determined.