A Polymer Blend Electrolyte Based on CS with Enhanced Ion Transport and Electrochemical Properties for Electrical Double Layer Capacitor Applications

The fabrication of energy storage EDLC in this work is achieved with the implementation of a conducting chitosan–methylcellulose–NH4NO3–glycerol polymer electrolyte system. The simple solution cast method has been used to prepare the electrolyte. The impedance of the samples was fitted with equivalent circuits to design the circuit diagram. The parameters associated with ion transport are well studied at various plasticizer concentrations. The FTIR investigation has been done on the films to detect the interaction that occurs among plasticizer and polymer electrolyte. To get more insights into ion transport parameters, the FTIR was deconvoluted. The transport properties achieved from both impedance and FTIR are discussed in detail. It was discovered that the transport parameter findings are in good agreement with both impedance and FTIR studies. A sample with high transport properties was characterized for ion dominancy and stability through the TNM and LSV investigations. The dominancy of ions in the electrolyte verified as the tion of the electrolyte is established to be 0.933 whereas it is potentially stable up to 1.87 V. The rechargeability of the EDLC is steady up to 500 cycles. The internal resistance, energy density, and power density of the EDLC at the 1st cycle are 53 ohms, 6.97 Wh/kg, and 1941 W/kg, respectively.

AC Conductivity and Conduction Mechanism of Iron (II) Chloride (FeCl2) /Poly (vinyl alcohol) (PVA)/Poly (vinylpyrroldone) (PVP) Polymer Blend Electrolyte

Blend sample based on Poly (vinyl alcohol) (PVA)/Poly (vinylpyrroldone) (PVP), (50:50), and their blend electrolyte with different weigh ratio of Iron (II) Chloride (FeCl2), (0.5, 1 and 2 wt.%), have been prepared using casting method. The AC electrical properties of these samples were investigated in the frequency range 1 kHz to 1 MHz and in temperature ranging from 30 to 150 °C. The real and imaginary impedance, frequency and temperature dependence, indicate the enhancement of the electrical conductivity of the blend due to addition of FeCl2. Pure and electrolyte blend samples were found to be characterized by a plateau region at low frequency and high temperature, and this plateau region increases with increase in temperature and /or FeCl2 weight ratio. Nyquist plots for pure and blend electrolyte samples presented depressed semicircles at all temperatures. For pure blend sample, the ac conductivity was attributed to hopping mechanism while for blend electrolyte sample ionic conduction represents the predominant conduction mechanism. Jonscher universal power law was used to study the conduction mechanism for pure and electrolyte blend sample. The activation energy for blend and blend electrolyte samples was calculated and two activation regions were appeared for blend electrolyte samples.