Isotopic and hydrogeochemical characterization of groundwater and surface water from a mine site in Tanzania

This study used the hydrochemical properties of water to reveal the causes of water quality degradation. The results showed that most samples located downstream of the mine tailings dam were slightly acidic with pH as low as 4.6. Samples with high levels of Na+, Cl−, and could not be isotopically linked to the local geochemistry, but the anthropogenic activities and evaporation were probably responsible for the observed water chemistry. The Piper diagram indicated cations were dominate by Ca and Mg, while anions were dominated by bicarbonates and sulphates. Pb and Hg levels (mean 70.29 and 17.95 μg/L, respectively) were all higher than the World Health Organization (WHO) and Tanzanian drinking water guidelines. Mining activities probably contributed to the observed low pH values and elevated concentration of cyanides, heavy metals, and metalloids. Stable isotope results indicated a vulnerability of the water to recent contamination that could be attributed to anthropogenic activities. Moreover, isotopic studies indicated a flow pattern from the eastern to the western side of the mine study site. Lowland samples were more 3H-enriched than highland ones. The present study concludes that groundwater recharge from recent local precipitation may have an impact on the sources studied.

Integrated Geophysical and Hydrogeochemical Characterization and Assessment of Groundwater Studies in Adum West Area of Benue State,Nigeria

Integration of geophysical and hydrogeochemical methods has been scientifically proven to be useful in vulnerability study and groundwater characterization. Subsurface geoelectric parameters such as resistivity and thickness obtained from geophysical method (Vertical Electrical Sounding VES) was used to determine aquifers vulnerability, longitudinal resistance (ρL) and transverse unit resistance (Rt). Thirty four water samples were collected from groundwater sources for physicochemical analysis.Estimated results from longitudinal conductance (S), (Rt) and (ρL) showed that the values ranges from 0.03 to 2.5mhos, 103.64 to 1964417.8 Ω/m2 and 215.41 to 65731.68 Ω-m respectively. Result from S suggested that 50 % of groundwater is considered to be vulnerable to contamination from the earth surface, while the remaining 50 % is considered to be slightly vulnerable to surface contamination. Further findings obtained from hydrogeochemical analysis such as Gibb’s and Chadba plots revealed that groundwater is highly influenced by rock water interaction,groundwater is classified to be Na+ + HCO3¯, Ca2+ + Mg2++ HCO3¯ , Na+ + Cl¯ and Ca2+ + Mg2+ + Cl¯ water type. Deduction from Soltan classification suggested that groundwater is classified to be of Na+ ˗ HCO3¯ and Na+ ˗ SO4 2¯ water type. Results obtained from Ec and pH suggested that the values were below WHO permissible limit, while result obtained from TDS showed that at some sampling points TDS values were above WHO limit. Based on pH value obtained groundwater within the study area fell within slightly basic to acidic.

An Integrated Multi-Approach to Environmental Monitoring of a Self-Burning Coal Waste Pile: The São Pedro da Cova Mine (Porto, Portugal) Study Case

The São Pedro da Cova waste pile (Porto, Portugal) is composed of coal mining residues that have been self-burning since 2005 and is located close to an inhabited area and social infrastructures, further adding to effects on the environment and human health. Therefore, there is a great interest in the environmental monitoring of this waste pile. This work describes an integrative multi-approach that allows the environmental monitoring of several parameters of the waste pile, applying several technologies. The temperature measurements were obtained by a thermal infrared (TIR) sensor on board an unmanned aerial vehicle (UAV) and supplemented with field measurements. In order to evaluate the altimetric variations, for each flight, a digital elevation model (DEM) was generated considering a multispectral sensor also on board the UAV. The hydrogeochemical characterization was performed through the analysis of groundwater and surface water samples, with and without the influence of mine drainage. The soil monitoring included the analysis of waste material as well as the surface soil in the surrounding area of the waste pile. All the data were analyzed and integrated in a geographical information system (GIS) open-source application. The adopted multi-approach methodology, given its intrinsic interdisciplinary character, has proven to be an effective way of encompassing the complexity of this type of environmental problem.