In the next few chapters we shall discuss tensors of rank zero to four which relate the intensive variables in the outer triangle of the Heckmann Diagram to the extensive variables in the inner triangle. Effects such as pyroelectricity, permittivity, pyroelectricity, and elasticity are the standard topics in crystal physics that allow us to discuss tensors of rank one through four. First, however, it is useful to introduce the thermodynamic relationships between physical properties and consider the importance of measurement conditions. Before discussing all the cross-coupled relationships, we first define the coupling within the three individual systems. In a thermal system, the basic relationship is between change in entropy δS [J/m3] and change in temperature δT [K]: . . . δS = CδT, . . . where C is the specific heat per unit volume [J/m3 K] and T is the absolute temperature. S, T, and C are all scalar quantities. In a dielectric system the electric displacement Di [C/m2] changes under the influence of the electric field Ei [V/m]. Both are vectors and therefore the electric permittivity, εij , requires two-directional subscripts. Occasionally the dielectric stiffness, βij , is required as well. . . . Di = εijEj Ei = βijDj. . . . Some authors use polarization P rather than electric displacement D. The three variables are interrelated through the constitutive relation . . . Di = Pi + ε0Ei = εijEj. . . . The third linear system in the Heckmann Diagram is mechanical, relating strain xij to stress Xkl [N/m2] through the fourth rank elastic compliance coefficients sijkl [m2/N]. . . . xij = sijklXkl. . . . Alternatively, Hooke’s Law can be expressed in terms of the elastic stiffness coefficients cijkl [N/m2]. . . Xij = cijklxkl. . . . When cross coupling occurs between thermal, electrical, and mechanical variables, the Gibbs free energy G(T, X, E) is used to derive relationships between the property coefficients. Temperature T, stress X, and electric field E are the independent variables in most experiments.