Igneous Rock Associations 28. Construction of a Venusian Greenstone Belt: A Petrological Perspective

The crustal evolution of Venus appears to be principally driven by intraplate processes that may be related to mantle upwelling as there is no physiographic (i.e. mid-ocean ridge, volcanic arc) evidence of Earth-like plate tectonics. Rocks with basaltic composition were identified at the Venera 9, 10, 13, and 14, and Vega 1 and 2 landing sites whereas the rock encountered at the Venera 8 landing site may be silicic. The Venera 14 rock is chemically indistinguishable from terrestrial olivine tholeiite but bears a strong resemblance to basalt from terrestrial Archean greenstone belts. Forward petrological modeling (i.e. fractional crystallization and partial melting) and primary melt composition calculations using the rock compositions of Venus can yield results indistinguishable from many volcanic (ultramafic, intermediate, silicic) and plutonic (tonalite, trondhjemite, granodiorite, anorthosite) rocks that typify Archean greenstone belts. Evidence of chemically precipitated (carbonate, evaporite, chert, banded-iron formation) and clastic (sandstone, shale) sedimentary rocks is scarce to absent, but their existence is dependent upon an ancient Venusian hydrosphere. Nevertheless, it appears that the volcanic–volcaniclastic–plutonic portion of terrestrial greenstone belts can be constructed from the known surface compositions of Venusian rocks and suggests that it is possible that Venus and Early Earth had parallel evolutionary tracks in the growth of proto-continental crust.

Determination of melt composition in an open-arc ore-thermal furnace

The aim of the study is to improve the technical and economic performance of the normal electrocorundum production process in an ore-thermal furnace by automated control of the melt composition at the final stage. The essence of the research is to exploit the valve effect of an AC arc. The expression for the Al2O3 content in the melt was obtained from the electrical characteristics of the melt. Studies have shown a fairly high degree of accuracy in the convergence of the results of the proposed method with laboratory data.

Geochemical variability as an indicator for large volume eruptions in volcanic arcs

Caldera-forming eruptions have the potential to impact global climate and induce drastic socioeconomic change. However, the criteria to identify volcanoes capable of producing large magnitude eruptions in the future are not well constrained. Here we compile and analyse data, revealing that volcanoes which have produced catastrophic caldera-forming eruptions in the past, typically show larger ranges of long-term erupted bulk-rock geochemistry compared to those that have not. This observation suggests that geochemical variability is a measure of a magmatic systems size. Using a 2D thermal model that simulates the growth and evolution of crustal-scale magmatic systems by stochastic injection of dikes and sills, we show that such behaviour is consistent with differences in crustal magma fluxes. Higher injection rates accumulate greater melt volumes in more extensive crustal plumbing systems, leading to more variable distributions of temperatures and thus melt composition. We conclude that compositional variability should be included in the catalogue of criteria to identify volcanic systems with greater probabilities of producing future large eruptions. Importantly, this allows to identify stratovolcanoes with caldera-like geochemical signatures, which have not yet been recognized as systems with greater probabilities of producing large magnitude eruptions.

Dynamic Metasomatism Experiments Investigating the Interaction between Migrating Potassic Melt and Garnet Peridotite

Dynamic metasomatism experiments were performed by reacting a lamproite melt with garnet peridotite by drawing melt through the peridotite into a vitreous carbon melt trap, ensuring the flow of melt through the peridotite and facilitating analysis of the melt. Pressure (2–3 GPa) and temperature (1050–1125 °C) conditions were chosen where the lamproite was molten but the peridotite was not. Phlogopite was formed and garnet and orthopyroxene reacted out, resulting in phlogopite wehrlite (2 GPa) and phlogopite harzburgite (3 GPa). Phlogopites in the peridotite have higher Mg/(Mg + Fe) and Cr2O3 and lower TiO2 than in the lamproite due to buffering by peridotite minerals, with Cr2O3 from the elimination of garnet. Compositional trends in phlogopites in the peridotite are similar to those in natural garnet peridotite xenoliths in kimberlites. Changes in melt composition resulting from the reaction show decreased TiO2 and increased Cr2O3 and Mg/(Mg + Fe). The loss of phlogopite components during migration through the peridotite results in low K2O/Na2O and K/Al in melts, indicating that chemical characteristics of lamproites are lost through reaction with peridotite so that emerging melts would be less extreme in composition. This indicates that lamproites are unlikely to be derived from a source rich in peridotite, and more likely originate in a source dominated by phlogopite-rich hydrous pyroxenites. Phlogopites from an experiment in which lamproite and peridotite were intimately mixed before the experiment did not produce the same phlogopite compositions, showing that care must be taken in the design of reaction experiments.

Atmospheres of lava exoplanets. Where and what to look for.

<p>Strongly irradiated rocky planets will have sufficiently high surface temperatures to sustain dayside magma lakes and oceans that will outgas low-pressure days-side silicate atmospheres. The surface magma will preferentially outgas its most volatile components and eventually equilibrate itself with the formed atmosphere. However, the volatile constituents may be depleted due to transport and condensation to the cooler night side or escape to space. If the atmospheric evolution is slower than the surface-interior exchange, the melt composition will remain coupled with the planet's interior. In such a case the atmospheric component will be continuously replenished. If atmospheric evolution is fast, the magma pool will lose its volatile component and the atmospheric composition will be irreversibly changed. We employ numerical models of outgassing, atmospheric chemistry, and radiative transfer to model the possible observable emission features of evolving magma atmospheres for all confirmed rocky lava worlds. . Our results highlight the best possible observable features in the atmospheres of hot rocky exoplanets that may give insight in their interior and atmospheric evolution. We also propose a set of ideal targets for JWST and ARIEL missions.<br><br><br></p>

Estimating the viscosity of volcanic melts from the vibrational properties of their parental glasses

The numerical modelling of magma transport and volcanic eruptions requires accurate knowledge of the viscosity of magmatic liquids as a function of temperature and melt composition. However, there is growing evidence that volcanic melts can be prone to nanoscale modification and crystallization before and during viscosity measurements. This challenges the possibility of being able to quantify the crystal-free melt phase contribution to the measured viscosity. In an effort to establish an alternative route to derive the viscosity of volcanic melts based on the vibrational properties of their parental glasses, we have subjected volcanologically relevant anhydrous glasses to Brillouin and Raman spectroscopic analyses at ambient conditions. Here, we find that the ratio between bulk and shear moduli and the boson peak position embed the melt fragility. We show that these quantities allow an accurate estimation of volcanic melts at eruptive conditions, without the need for viscosity measurements. An extensive review of the literature data confirms that our result also holds for hydrous systems; this study thus provides fertile ground on which to develop new studies of the nanoscale dynamics of natural melts and its impact on the style of volcanic eruptions.

Sub-lithospheric mantle sources for overlapping southern African Large Igneous Provinces

At least four spatially overlapping Large Igneous Provinces, each of which generated ∼1 x 106 km3 or more of basaltic magmas over short time intervals (<5 m.y.), were emplaced onto and into the Kaapvaal Craton between 2.7 and 0.18 Ga: Ventersdorp (2 720 Ma, ∼0.7 x 106 km3), Bushveld (2 056 Ma, ∼1.5 x 106 km3), Umkondo (1 105 Ma, ∼2 x 106 km3) and Karoo (182 Ma, ∼3 x 106 km3). Each of these has been suggested to have been derived from melting of sub-continental lithospheric mantle (SCLM) sources, but this is precluded because: (1) each widespread heating event sufficient to generate 1 to 2 x 106 km3 of basalt from the Kaapvaal SCLM (volume = 122 to 152 x 106 km3) would increase residual Mg# by 0.5 to 2 units, depending on degree of melting, and source and melt composition, causing significant depletion in already-depleted mantle, (2) repeated refertilization of the Kaapvaal SCLM would necessarily increase its bulk density, compromising its long-term buoyancy and stability, and (3) raising SCLM temperatures to the peridotite solidus would also have repeatedly destroyed lithospheric diamonds by heating and oxidation, which clearly did not happen. It is far more likely, therefore, that the Kaapvaal LIPs were generated from sub-lithospheric sources, and that their diverse geochemical and isotopic signatures represent variable assimilation of continental crustal components. Combined Sr and Nd isotopic data (n = 641) for the vast volumetric majority of Karoo low-Ti tholeiitic magmatic products can be successfully modelled as an AFC mixing array between a plume-derived parental basalt, with <10% of a granitic component derived from 1.1 Ga Namaqua-Natal crust. Archaean crustal materials are far too evolved (εNd ∼ -35) to represent viable contaminants. However, a very minor volume of geographically-restricted (and over-analysed) Karoo magmas, including picrites, nephelinites, meimechites and other unusual rocks may represent low-degree melting products of small, ancient, enriched domains in the Kaapvaal SCLM, generated locally during the ascent of large-volume, plume-derived melts. The SCLM-derived rocks comprise the well-known high-Ti (>2 to 3 wt.% TiO2) magma group, have εNd, 182 values between +10.5 and -20.9, and are characteristically enriched in Sr (up to 1 500 ppm), suggesting a possible connection to kimberlite, lamproite and carbonatite magmatism. These arguments may apply to continental LIPs in general, although at present, there are insufficient combined Sr + Nd isotopic data with which to robustly assess the genesis of other southern African LIPs, including Ventersdorp (n = 0), Bushveld (n = 55) and Umkondo (n = 18).

Model Development to Study Uncertainties in Electric Arc Furnace Plants to Improve Their Economic and Environmental Performance

A statistical model is developed in order to simulate the melt composition in electric arc furnaces (EAFs) with respect to uncertainties in 1) scrap composition, 2) scrap weighing and 3) element distribution factors. The tramp element Cu and alloying element Cr are taken into account. The model enables simulations of a charge program as well as backwards estimations of the element concentrations and their variance in scrap. In the backwards calculation, the maximum likelihood method is solved by considering three cases corresponding to the involved uncertainties. It is shown that the model can estimate standard deviations for elements so that the real values lie within the estimated 95% confidence interval. Moreover, the results of the model application in each target product show that the estimated scrap composition results in a melt composition, which is in good agreement with the measured one. The model can be applied to increase our understanding of scrap chemical composition and lower the charged material cost and carbon footprint of the products.