Unexpected Substitution Reaction of 1,1-Dichloro-2,2,2-trifluoroethane (HCFC-123) with Phenolates

An unexpected substitution reaction of HCFC-123 with phenolates is reported. During the reaction, fluorine atoms in HCFC-123 are removed one by one in the presence of phenolates.

Experimental Evaluation on Low Global Warming Potential HFO-1336mzz-Z as an Alternative to HCFC-123 and HFC-245fa

HFO-1336mzz-Z with low global warming potential (GWP) was considered as a promising alternative of HCFC-123, HFC-245fa in air conditioning (AC) and heat pump (HP), respectively. In order to understand the operation performances of HFO-1336mzz-Z and HCFC-123, HFC-245fa in different working conditions, an experimental setup for testing the refrigeration cycle performance was built. The cycle performances of HFO-1336mzz-Z and HCFC-123 in AC conditions, HFO-1336mzz-Z and HFC-245fa in HP conditions were investigated by experiment. It was found in AC conditions, the discharge temperatures for the systems with HFO-1336mzz-Z and HCFC-123 were lower than 115 °C, the cooling capacity of the system with HFO-1336mzz-Z was 27% less than that with HCFC-123 at least, and the coefficient of performance (COP) of the system with HFO-1336mzz-Z was 0.1 lower than that with HCFC-123; in HP conditions, the discharge temperature with HFO-1336mzz-Z was lower than that with HFC-245fa, the former was never over 115 °C while the latter was up to 126 °C, the power input to the compressor with HFO-1336mzz-Z was 20% less than that with HFC-245fa in the same HP conditions, the heating capacity of the system with HFO-1336mzz-Z was 30–40% less than that with HFC-245fa.

Cu-Mediated 2,2,2-trifluoroethylation of terminal alkynes using 1,1-dichloro-2,2,2-trifluoroethane (HCFC-123)

Cu-Promoted coupling reactions of HCFC-123 with terminal alkynes give trifluoroethylated internal alkynes.