Experimental Evaluation on Low Global Warming Potential HFO-1336mzz-Z as an Alternative to HCFC-123 and HFC-245fa

Author(s):  
Shikuan Wang ◽  
Zhikai Guo ◽  
Xiaohong Han ◽  
Xiangguo Xu ◽  
Qin Wang ◽  
...  

HFO-1336mzz-Z with low global warming potential (GWP) was considered as a promising alternative of HCFC-123, HFC-245fa in air conditioning (AC) and heat pump (HP), respectively. In order to understand the operation performances of HFO-1336mzz-Z and HCFC-123, HFC-245fa in different working conditions, an experimental setup for testing the refrigeration cycle performance was built. The cycle performances of HFO-1336mzz-Z and HCFC-123 in AC conditions, HFO-1336mzz-Z and HFC-245fa in HP conditions were investigated by experiment. It was found in AC conditions, the discharge temperatures for the systems with HFO-1336mzz-Z and HCFC-123 were lower than 115 °C, the cooling capacity of the system with HFO-1336mzz-Z was 27% less than that with HCFC-123 at least, and the coefficient of performance (COP) of the system with HFO-1336mzz-Z was 0.1 lower than that with HCFC-123; in HP conditions, the discharge temperature with HFO-1336mzz-Z was lower than that with HFC-245fa, the former was never over 115 °C while the latter was up to 126 °C, the power input to the compressor with HFO-1336mzz-Z was 20% less than that with HFC-245fa in the same HP conditions, the heating capacity of the system with HFO-1336mzz-Z was 30–40% less than that with HFC-245fa.

2021 ◽  
pp. 45-45
Author(s):  
Zhaofeng Meng ◽  
Yin Liu ◽  
Dingbiao Wang ◽  
Long Gao ◽  
Junhai Yan

Refrigerants with low global warming potential (GWP) are much needed in automotive air conditioning systems. This paper compares two refrigerants, R134a (GWP=1300) and R513A (GWP=573) experimentally. The results show that the latter has lower cooling capacity, lower COP and lower discharge temperature than the former, revealing that R513A is a promising replacement of its high GWP partner.


Author(s):  
Rabah Touaibi ◽  
Hasan Koten

An energy analysis study carried out on a vapor compression refrigeration cycle using refrigerants with low global warming potential (GWP) of the Hydro-Fluoro-Olefin (HFO) type, in particular R1234yf and R1234ze fluids to replace HFC refrigerants . Computer code was developed using software for solving engineering equations to calculate performance parameters; for this, three HFC type fluids (R134a, R404A and R410A) were selected for a comparative study. The results showed that R1234ze is the best refrigerant among those selected for the mechanical vapor compression refrigeration cycle. The thermodynamic analysis showed the effect of the evaporator temperature (-22 °C to 10 °C) and the condenser temperature (30 °C to 50 °C) on the steam cycle performance. Compression refrigeration, including the coefficient of performance. The results showed that the HFO-R1234ze with low GWP gives the best coefficient of performance of 3.14 close to that of the R134a fluid (3.17). In addition, R1234ze is considered an alternative fluid to R134a for their ecological properties.


2019 ◽  
Vol 69 (4) ◽  
pp. 147-158
Author(s):  
Sk Mohammad Hasheer ◽  
Kolla Srinivas

AbstractChlorofluorocarbons and hydro chlorofluorocarbons (HCFCs) are replaced by hydroflourocarbons (HFCs) which is not harmful to the ozone layer. However, few of HFCs have a relatively high global warming potential (GWP) and are subject to further examination due to growing concerns about global climate change. The goal now is to find the next generation of environmentally sustainable work fluids with an insignificant direct environmental impact in terms of ozone depletion and global warming potential. This document introduces the mixture of low-GWP refrigerants like R440A, R430A, R1234ze (E)/152a (50:50 by mass), R290/600a (40/60), R290/600(60/40), R290/600(50/50), ARM 42,ARM 42a and AC5 are used to replace R-134a in a domestic refrigeration system without doing any modifications to the system. The performance of the refrigerator was observed in terms of volumetric cooling capacity, blower discharge temperature, and coefficient of performance, refrigeration effect and energy consumption of a blower.


2011 ◽  
Vol 243-249 ◽  
pp. 4918-4922
Author(s):  
Jian Bo Chen ◽  
Kuang Wei Min ◽  
Fen Li

The natural refrigerant R29O and mixed refrigerant R417A is currently approved ideal substitutes of R22, The performance of R290 and R410A in the same heat pump air conditioning water heater combination was studied experimentally, heating capacity, cooling capacity, power input, COP ,discharge pressure, suction pressure,discharge temperature were measured, the performance of heat pump air conditioning water heater combination at standard air condition and varied inlet-water temperature was analyzed .The results show that the most appropriate charge mass of R290 is only 52% of R417A in the same systems ,so using r290 more environmentally friendly.The coefficient of performance (COP) is higher than R417A in the same capacity, so using r290 have lower energy consumption, more energy-saving. Compressor discharge pressure and temperatures of R290 is lower than R417A in the same inlet-water temperature, so using r290 favors the system security operation. But the performance of R290 influenced by the inlet water temperature more obvious than R417A, it's not very suitable for the occasion of high inlet-water temperature.


2019 ◽  
Vol 11 (1) ◽  
pp. 168781401881956 ◽  
Author(s):  
Liu Zhang ◽  
Jin-xiu Zhao ◽  
Li-fang Yue ◽  
Hong-xing Zhou ◽  
Chun-li Ren

Blend refrigerants combing hydrofluorocarbons and hydrocarbons are good substitutes to decrease the flammability of hydrocarbons while reducing the global warming potential of hydrofluorocarbons. Four hydrofluorocarbon/hydrocarbon blends (R134a/R290, R134a/R600, R134a/R600a, and R134a/R1270) with various compositions are investigated in vapor-compression heat pump cycles. The effects of hydrocarbon fraction on the blend properties, including critical temperature, critical pressure, latent heat, saturated liquid line, and azeotropic behavior, are comparatively analyzed. Thermodynamic models are established for heat pump simulation. For each R134a/hydrocarbon blend, both the cooling and heating coefficient of performances generally first decrease and then increase with the hydrocarbon mass fraction. The coefficient of performances of R134a/R600 and R134a/R600a have dramatic changes within the hydrocarbon mass fraction of 0.2–1.0, while those of R134a/R290 and R134a/R1270 have dramatic changes within the fraction of 0.0–0.4. Lower condensing or higher evaporating temperatures lead to higher coefficient of performances. In addition, the volumetric capacities first increase and then decrease with the increase of hydrocarbon fraction. R134a/R290 and R134a/R1270 show much higher volumetric capacities as compared to R134a/R600 and R134a/R600a under higher hydrocarbon fractions, which can greatly reduce the required compressor size of pure R134a. The discharge temperatures are kept in the range of 43.0°C–72.3°C for all the blends. To obtain low global warming potential R134a/hydrocarbon blends, the hydrocarbon fraction need to be greater than 0.9, at which R134a/R1270 performs the best, with cooling/heating coefficient of performances of 5.25/4.70 and cooling/heating volumetric capacities of 4.78/3.53 MJ/m3. Generally, R134a/R290 and R134a/R1270 perform much better than R134a/R600 and R134a/R600a at the low global warming potential composition. This study can contribute to the determination of hydrofluorocarbon/hydrocarbon compositions based on comprehensive considerations of cycle efficiency, volumetric capacity, and low global warming potential target.


Energies ◽  
2020 ◽  
Vol 13 (6) ◽  
pp. 1514
Author(s):  
Piyanut Saengsikhiao ◽  
Juntakan Taweekun ◽  
Kittinan Maliwan ◽  
Somchai Sae-ung ◽  
Thanansak Theppaya

This research presents the development of R463A refrigerant, a nonflammable refrigerant that was retrofitted to replace R404A. R463A is primarily composed of hydrofluorocarbons/hydrocarbons/carbon dioxide (HFCs/HCs/CO2), and has global-warming potential (GWP) of 1494. It is a nonazeotropic mixture of R32 (36%), R125 (30%), R134a (14%), R1234yf (14%), and R744 (6%). R463A is composed of polyol ester oil (POE), and it is classified as a Class A1 incombustible and nontoxic refrigerant. R463A has a higher cooling capacity (Qe) than that of R404A, as it is composed of hydrofluorocarbons (HFCs) R32 and carbon dioxide (CO2) R744, and has lower GWP than that of R404A due to the use of hydrofluoroolefins (HFOs) from R1234yf. The results of this research showed that R463A can be retrofitted to replace R404A due to its composition of POE, Class A1 incombustibility, and lower toxicity. The properties of R463A and R404A, as analyzed using national institute of standards and technology (NIST) reference fluid thermodynamic and transport properties database (REFPROP) software and NIST vapor compression cycle model accounting for refrigerant thermodynamic and transport properties (CYCLE_D-HX) software, are in accordance with the CAN/ANSI/AHRI540 standards of the Air-Conditioning, Heating, and Refrigeration Institute (AHRI). The normal boiling point of R463A was found to be higher than that of R404A by 23%, with a higher cooling capacity and a 63% lower GWP value than that of R404A. The critical pressure and temperature of R463A were found to be higher than those of R404A; it can be used in a high-ambient-temperature environment, has higher refrigerant and heat-rejection effects, and has lower GWP than that of R404A by 52% due to the HFOs from the R1234yf component. The cooling coefficient of performance (COPc) of R463A was found to be higher than that of R404A by 10% under low-temperature applications. R463A is another refrigerant option that is composed of 7% carbon dioxide (CO2), and is consistent with the evolution of fourth-generation refrigerants that contain a mixture of HFCs, HFOs, HCs, and natural refrigerants, which are required to produce a low-GWP, zero-ozone-depletion-potential (ODP), high-capacity, low-operating-pressure, and nontoxic refrigerant.


Energies ◽  
2021 ◽  
Vol 14 (4) ◽  
pp. 946
Author(s):  
Bartosz Gil ◽  
Anna Szczepanowska ◽  
Sabina Rosiek

In this work, which is related to the current European Parliament Regulation on restrictions affecting refrigeration, four new three-component refrigerants have been proposed; all were created using low Global Warming Potential(GWP) synthetic and natural refrigerants. The considered mixtures consisted of R32, R41, R161, R152a, R1234ze (E), R1234yf, R1243zf, and RE170. These mixtures were theoretically tested with a 10% step in mass fraction using a triangular design. The analysis covered two theoretical cooling cycles at evaporating temperatures of 0 and −30 °C, and a 30 °C constant condensing temperature. The final stage of the work was the determination of the best mixture compositions by thermodynamic and operational parameters. R1234yf–R152a–RE170 with a weight share of 0.1/0.5/0.4 was determined to be the optimal mixture for potentially replacing the existing refrigerants.


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