Qualitative profile of volatile compounds by SPME in Dendrocalamus latiflorus, Phyllostachys pubescens, and Phyllostachys makinoi culms used as eating utensils

Volatile compounds are released when bamboo culms are used as eating utensils. Volatile compounds of Dendrocalamus latiflorus, Phyllostachys pubescens, and P. makinoi culms were extracted using solid-phase microextraction (SPME). The bamboo culms were steamed or baked at different temperatures (100 °C and 230 °C) and durations (5 min, 30 min, and 60 min). Gas chromatography-mass spectrometry (GC-MS) analyses showed that, regardless of heating method and duration, P. makinoi culms comprised the most species of volatile compounds, with sesquiterpenes being the major compounds. Steaming and baking D. latiflorus culms at 100 °C for 30 min yielded more volatile compounds than baking at 230 °C. Benzenoids were the chief compounds in heated D. latiflorus and P. pubescens culms, with phenylacetaldehyde being the dominant constituent. Phenylacetaldehyde has fragrances of herb, flower, and oil. Moreover, the major volatile compound cyclosativene, which gives a terpene-like aroma, was obtained when P. makinoi culms were heated for different durations. After baking at 230 °C for 30 min, the major volatile compound released from P. makinoi culm was α-muurolene (41.19%), which produces a woody aroma. After continuous baking for 60 min, DT 1, a kind of diterpene compound, increased remarkably in relative content, while the content of α-muurolene decreased notably.

A Cleistanthane Diterpene From a Marine-derived Fusarium Species Under Submerged Fermentation

A cleistanthane-type diterpene, compound 1, was isolated from the marine-derived Fusarium sp. FH-146. The structure of 1 was determined by 1D and 2D NMR spectroscopy. Compound 1 showed moderate antimicrobial, cytotoxic, and phytotoxic activities

ent-Kaur-16-en-19-al

The title ent-kaurane diterpene compound, C20H30O, was isolated from the roots of Bruguiera cylindrica (Rhizophoraceae), a mangrove plant. The molecule contains a fused four-ring system, with the three cyclohexane rings in standard chair conformations and the cyclopentane ring adopting an envelope conformation. The aldehyde is bisectionally attached to the cyclohexane ring. The methylene group is coplanar with the attached cyclopentane ring. In the crystal structure, molecules are packed by van der Waals interactions.

Pheromone disseminating structures in tergites of male phlebotomines (Diptera: Psychodidae)

Following the examination of 53 Lutzomyia spp., seven Phlebotomus spp. and five Sergentomyia spp. (Diptera: Psychodidae) new observations are recorded on the presence of pheromone disseminating structures on the tergites of male phlebotomine sandflies. Descriptions are given of 11 of the species which include structures such as simple cuticular pores in craters, pores with emergent spines, and mammiform papules with or without spiny processes. Pheromone papule distribution on the tergites of Lutzomyia pessoai (Coutinho & Barretto) is plotted and gas chromatography and GC-mass spectroscopy have been used to demonstrate the presence of a diterpene compound similar to a sexual attractant pheromone observed in some L. longipalpis (Lutz & Neiva) populations.