Evolution of fluid flow and carbonate recrystallization rates in deep-sea sediments of the Equatorial Pacific

Fluid flow and carbonate recrystallization rates of deep-sea sediments from eight locations in the Equatorial Eastern Pacific were determined by using δ44/40Ca values of pore water and corresponding sediments. The studied drill sites of IODP Exp. 320/321 are located along a transect of decreasing crustal age and reveal different characteristic pore water depth profiles. The younger sites show an overall isotopic equilibration with the sediment in the upper part of the sedimentary column. In the lower part, the δ44/40Ca of the pore water increases back to seawater-like values at the sediment/basalt interface, forming a bulge-shaped pore water profile. The magnitude of the δ44/40Ca pore water bulge decreases with increasing age of the oceanic crust and sediment cover, resulting in seawater-like δ44/40Ca values throughout the sedimentary column in the oldest Sites U1331 and U1332. These findings indicate a seawater-like fluid input from the underlying crust into the sediment. Thus, after sedimentation, carbonate recrystallization processes start to enrich the pore water in 40Ca, and after a time of carbonate recrystallization and cooling of oceanic crust, a flow of seawater-like fluid starts to move upwards through the sedimentary column, enriching the pore water with 44Ca. We established a carbonate recrystallization and fluid flow model to quantify these processes. Our determined carbonate recrystallization rates between 0.000013e(−t/15.5) and 0.00038e(−t/100.5) and fluid flow rates in the range of 0.42–19 m*Myr−1 indicate that the fluid flow within the investigated sites of IODP Exp. 320/321 depends on the sedimentary composition and location of the specific site, especially the proximity to a recharge or discharge site of a hydrothermal convection cell.

Palaeoenvironmental context and significance of ferruginous tubular bioforms and other authigenic mineral formations in source-to-sink sedimentary systems

Surficial sediments on the seafloor from passive continental margins can provide insight into recent Late Quaternary sedimentary dynamics acting over offshore sedimentary systems. This work focuses on the study of some particular ferruginous tubular structures resembling bioforms (FTB) located in the distal Galician Continental Margin (NW Iberian Margin) at water depths between ~ 1550 and ~ 2200 m. The characterisation of these structures made it possible to study in depth their formation environment and subsequent sedimentary evolution during the Late Pleistocene and Holocene. The FTB consist of goethite with a framboidal texture. They were interpreted as formed by an initial pyrite precipitation in reducing microenvironments conditioned by the activity of sediment-dwelling organisms during the early diagenesis. This is followed by the oxidation of pyrite by a combination of hydrothermal fluids and erosional processes, which triggers the formation of the framboidal oxyhydroxides. The data allowed obtaining a comprehensive understanding of the environmental context and the significance of these ferruginous tubules, as there are no previous studies in the scientific literature that describe these structures in a source-to-sink sedimentary system.