Polyolefin–Silicate Nanocomposites: Mechanical Properties and Fracture Mechanics

2008 ◽  
pp. 365-414
Author(s):  
Sie C. Tjong
Author(s):  
Licheng Guo ◽  
Zhihai Wang ◽  
Naotake Noda

This study aimed to develop a method to build a ‘bridge’ between the macro fracture mechanics model and stochastic micromechanics-based properties so that the macro fracture mechanics model can be expanded to the fracture mechanics problem of functionally graded materials (FGMs) with stochastic mechanical properties. An analytical fracture mechanics model is developed to predict the stress intensity factors (SIFs) in FGMs with stochastic uncertainties in phase volume fractions. Considering the stochastic description of the phase volume fractions, a micromechanics-based method is developed to derive the explicit probabilistic characteristics of the effective properties of the FGMs so that the stochastic mechanical properties can be combined with the macro fracture mechanics model. A thought for choosing the samples efficiently is proposed so that the stable probabilistic characteristic of SIFs can be obtained with a very small sample size. The probability density function of SIFs can be determined by developing a histogram from the generated samples. The present method may provide a thought to establish an analytical model for the crack problems of FGMs with stochastic properties.


2002 ◽  
Vol 740 ◽  
Author(s):  
Pralay Maiti ◽  
Carl A. Batt ◽  
Emmanuel P. Giannelis

ABSTRACTNanocomposites of α-hydroxy polyester, polylactide (PLA) and β-hydroxy polyester, polyhydroxybutyrate (PHB) with layered silicates have been successfully prepared by melt extrusion of PLA and PHB with organically modified montmorillonite (MMT) and fluoromica. The mechanical properties of the nanocomposites are improved compared to the neat polymers. Storage modulus increase up to 40% compared with the pure polymers by adding only 2–3 wt% nanoclay. Biodegradation can be controlled by the choice of the nanoclay used.


2016 ◽  
Vol 821 ◽  
pp. 464-470
Author(s):  
Ľubomír Gajdoš ◽  
Martin Šperl

For standard fracture mechanical tests flat specimens (principally CT or SENB) are required. When investigating fracture mechanical properties of thin – walled pipes this brings about a problem because it is necessary to straighten pipe bands. However, this operation causes internal stresses to be induced not only in the semi-product subjected to straightening but also in finished specimens. A question therefore arises to what extent are then the magnitudes of the fracture toughness determined representative for the actual cylindrical wall. To solve this problem fracture mechanics tests were caried out on flat (straightened) CT specimens as well as on curved CT specimens with the natural curvature. The R – curves as well as the resulting parameters of the fracture toughness, obtained for both types of CT specimens, were compared and it was concluded that the fracture toughness of the pipe material determined on straightened CT specimens was practically the same as that obtained on curved CT specimens.


1968 ◽  
Vol 10 (4) ◽  
pp. 329-336
Author(s):  
L. P. Pook

The results of tests on two high-strength steels, beryllium copper and perspex, together with some published data on high-strength steels were examined to see whether there was any relationship between the fracture mechanics parameter K1C and conventional mechanical properties. It was found that for steels and beryllium copper a correlation appeared to exist between K1C and the zero gauge length strain (= Z/(1 - Z) where Z is the reduction of area measured in a tensile test). It was also found that for constant, K1C was proportional to the square root of Young's modulus. The correlation band for steels was too wide for K1C to be estimated accurately from.


Polymer ◽  
2009 ◽  
Vol 50 (15) ◽  
pp. 3478-3487 ◽  
Author(s):  
Yaru Shi ◽  
Takashi Kashiwagi ◽  
Richard N. Walters ◽  
Jeffrey W. Gilman ◽  
Richard E. Lyon ◽  
...  

2008 ◽  
Vol 8 (4) ◽  
pp. 1858-1866 ◽  
Author(s):  
Pralay Maiti ◽  
Jaya P. Prakash Yadav

Copolymer of hydroxybutyrate and hydroxyvalerate, P(HB-HV)/layered silicate or hydroxyapatite nanocomposites were prepared via melt extrusion. The nanostructure, as observed from wide-angle X-ray diffraction and transmission electron microscopy, indicate intercalated hybrids for layered silicates. Hydroxyapatite of nanometer dimension is uniformly distributed in matrix copolymer. The nanohybrids show significant improvement in thermal and mechanical properties of the copolymer as compared to the neat copolymer. The layered silicate nanocomposites exhibit superior mechanical properties as compared to hydroxyapatite nanohybrid. The thermal expansion coefficient is significantly reduced in nanohybrids. The biodegradability of pure copolymer and its nanocomposites were studied at room temperatures under controlled conditions in compost media. The rate of biodegradation of copolymer is enhanced dramatically in the nanohybrids. Hydroxyapatite hybrid shows highest rate of biodegradation. The change in biodegradation is streamlined in terms of nature of nanoparticles used to prepare hybrids.


2014 ◽  
Vol 496-500 ◽  
pp. 2402-2406
Author(s):  
Kui He ◽  
Hui Yang ◽  
Fang Fang Jia ◽  
Er Po Wang ◽  
Zhen Bao Lu ◽  
...  

Workability, strength and fracture mechanics of polypropylene macro-fiber reinforced Reactive powder concrete (RPC) were studied in this work. The results showed that the incorporation of macro-fiber could influence the workability of RPC, the slump of RPC decreased with the increasing of macro-fiber content; compressive strength decreased while splitting strength increased with the increasing of macro-fiber, meanwhile the flexural strength invariant. Macro-fiber could strongly enhance the flexural toughness of RPC and changed the failure mode from brittle to ductile; fracture energy tends to increase linearly with the increasing of macro-fiber.


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