Study on Preparation of High-Quality Synthetic Rutile from Titanium Slag by Activation Roasting Followed by Acid Leaching

Author(s):  
Yu-feng Guo ◽  
Shui-shi Liu ◽  
Tao Jiang ◽  
Guan-zhou Qiu
Crystals ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 888
Author(s):  
Helin Fan ◽  
Ruixiang Wang ◽  
Zhifeng Xu ◽  
Huamei Duan ◽  
Dengfu Chen

Synthetic rutile was prepared from titanium slag melt with low energy consumption and a small amount of additive (B2O3) in our previous work. The modification mechanism of titanium slag was not clear enough. The migration and enrichment behaviors of Ca and Mg elements during cooling and crystallization of boron-bearing titanium slag melt were characterized by XRF, FESEM, EMPA, and XPS. Results show that when additive (B2O3) is added, Ti elements are migrated and enriched in the area to generate rutile, while Ca, Mg, and B elements are migrated and enriched in another area to generate borate. With the additive (B2O3) amount increased, Ca and Mg element migration is complete and more thorough. Additive (B2O3) promotes rutile formation and inhibits the formation of anosovite during cooling and crystallization of titanium slag melt. With the additive (B2O3) amount increasing from 0% to 6%, the proportion of Ti3+ in the modified titanium slag reduces from 9.15% to 0%, and the proportion of Ti4+ increases from 90.85% to 100% under the same cooling and crystallization condition. The result will lay the foundation for the efficient preparation of synthetic rutile by adding B2O3 to the titanium slag melt.


2021 ◽  
Vol 11 (1) ◽  
pp. 89-93
Author(s):  
Chinh Tran Van ◽  
Anh Tran Thi Hien ◽  
Tu Ha Thi Cam ◽  
Hoai Truong Viet ◽  
Phuong Nguyen Thi Hoai ◽  
...  

This paper describes a novel process for the synthesis of TiO2 from titanium slag, which is realized via roasting titanium slag with KHSO4, acid leaching and hydrolysis. The results showed that the optimum conditions were a mass ratio of KHSO4 to titanium slag of 6, a temperature of 600 oC for 1,5 hours. Besides, this study investigated the possibility of synthesized TiO2 for photocatalytic degradation of methylene blue.


2013 ◽  
Vol 53 (1) ◽  
pp. 70-77 ◽  
Author(s):  
Longsheng Zhao ◽  
Yahui Liu ◽  
Lina Wang ◽  
Hongxin Zhao ◽  
Desheng Chen ◽  
...  

2014 ◽  
Vol 147-148 ◽  
pp. 134-141 ◽  
Author(s):  
Yufeng Guo ◽  
Shuishi Liu ◽  
Tao Jiang ◽  
Guanzhou Qiu ◽  
Feng Chen

2018 ◽  
Vol 323 ◽  
pp. 115-119 ◽  
Author(s):  
Aoxi He ◽  
Guo Chen ◽  
Jin Chen ◽  
Jinhui Peng ◽  
C. Srinivasakannan ◽  
...  

JOM ◽  
2018 ◽  
Vol 70 (10) ◽  
pp. 1985-1990
Author(s):  
Longsheng Zhao ◽  
Lina Wang ◽  
Tao Qi ◽  
Desheng Chen ◽  
Hongxin Zhao ◽  
...  

2018 ◽  
Vol 5 (6) ◽  
pp. 171858 ◽  
Author(s):  
Guo Chen ◽  
Jing Pu ◽  
Jin Chen ◽  
Jinhui Peng ◽  
C. Srinivasakannan ◽  
...  

In this paper, the phase transition of titanium slag under microwave heating observed through electron microscopy was systematically investigated. The phase identification and transformation as well as the morphology of samples before and after each treatment were characterized using X-ray powder diffraction (XRD), Fourier-transform infrared spectroscopy, Raman spectroscopy and scanning electron microscopy (SEM). The XRD confirmed that sodium salt roasting could modify the phase composition of titanium slag. The microwave roasting in the presence of sodium salt increased the rutile TiO 2 with high crystallinity after acid leaching. The Raman spectroscopy demonstrated the phase transition of titanium slag from anosovite to rutile TiO 2 after a series of treatments, and the SEM analyses showed that the surface of calcined products grew plenty of rutile TiO 2 with typical characteristics. The results indicate a successful process for an effective and efficient way for the utilization of both titanium slag and preparation of rutile TiO 2 .


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