The purpose of this investigation is to investigate the hydrophobicity of
geopolymers, new alumino-silicate materials and the influence of Si/Al ratio
on their surface properties. Contact angle measurement (CAM) as reliable
indicator of hydrophobicity was determined for synthesized geopolymers using
water and ethylene-glycol as reference liquids. Geopolymers were synthesized
from various precursors: kaolin, bentonite and diatomite. Characterization
of phase structure and microstructure was performed by XRD, FTIR, SEM/EDX
methods. Contact angle measurements confirmed that the geopolymers
synthesized from metakaolin are the most porous, which can be explained by
the smallest Si/Al ratio. The maximum value of contact angle and free
surface energy (110.2 mJ/m2) has been achieved for geopolymer synthesized by
diatoms (GPMD). SEM micrograph of GPMD shows a homogeneous surface with some
longitudinal cavities in the gel and is significantly different from the
micrographs of other two geopolymer samples, GPMB and GPMK.