Industrial Relevance of Asymmetric Organocatalysis in the Preparation of Chiral Amine Derivatives

2021 ◽  
pp. 187-241
Author(s):  
Luca Bernardi ◽  
Armando Carlone ◽  
Francesco Fini
Keyword(s):  
Chiral Amine ◽  
Asymmetric Organocatalysis ◽  
Industrial Relevance

Continuous production of a chiral amine in a packed bed reactor with co-immobilized amine dehydrogenase and formate dehydrogenase

2021 ◽  
Vol 407 ◽  
pp. 127065
Author(s):  
Robert D. Franklin ◽  
Joshua A. Whitley ◽  
Adam A. Caparco ◽  
Bettina R. Bommarius ◽  
Julie A. Champion ◽  
...  
Keyword(s):  
Formate Dehydrogenase ◽  
Continuous Production ◽  
Packed Bed ◽  
Packed Bed Reactor ◽  
Chiral Amine ◽  
Amine Dehydrogenase

scholarly journals Continuous Flow Chiral Amine Racemization Applied to Continuously Recirculating Dynamic Diastereomeric Crystallizations

2021 ◽  
Vol 86 (3) ◽  
pp. 2458-2473
Author(s):  
Maria H. T. Kwan ◽  
Jessica Breen ◽  
Martin Bowden ◽  
Louis Conway ◽  
Ben Crossley ◽  
...  
Keyword(s):  
Continuous Flow ◽  
Chiral Amine

Engineering the large pocket of an (S)-selective transaminase for asymmetric synthesis of (S)-1-amino-1-phenylpropane

2021 ◽  
Author(s):  
Youyu Xie ◽  
Feng Xu ◽  
Lin Yang ◽  
He Liu ◽  
Xiangyang Xu ◽  
...  
Keyword(s):  
Asymmetric Synthesis ◽  
Environmentally Benign ◽  
Chiral Amine ◽  
Synthesis Route

Amine transaminases offer an environmentally benign chiral amine asymmetric synthesis route.

Chemoselective Hydrogenation of Cinnamaldehyde over Tailored Oxygen Vacancy Rich Pd@ZrO2 Catalyst

2021 ◽  
Author(s):  
Komal N. Patil ◽  
Divya Prasad ◽  
Jayesh T. Bhanushali ◽  
Bhalchandra Kakade ◽  
Arvind H. Jadhav ◽  
...  
Keyword(s):  
Oxygen Vacancy ◽  
Selective Hydrogenation ◽  
Oxygen Vacancies ◽  
Synthesis Method ◽  
Chemoselective Hydrogenation ◽  
Zro2 Catalyst ◽  
Industrial Relevance

Selective hydrogenation of cinnamaldehyde to hydrocinnamaldehyde is captivating due to its industrial relevance. Herein, two-step synthesis method was adopted to develop oxygen vacancies in Pd@ZrO2 catalysts. The oxygen vacancies were...

Short syntheses of 1-substituted dibenzothiophene derivatives

2021 ◽  
Vol 19 (9) ◽  
pp. 2000-2007
Author(s):  
Erin N. Welsh ◽  
Katherine N. Robertson ◽  
Alexander W. H. Speed
Keyword(s):  
Cross Coupling ◽  
One Pot ◽  
Chiral Amine ◽  
Rapid Access

A one-pot double benzyne cascade allows rapid access to 1-substituted dibenzothiophene derivatives, including cross-coupling partners and a chiral amine.

scholarly journals Cross-trienamines in Asymmetric Organocatalysis

2012 ◽  
Vol 134 (31) ◽  
pp. 12943-12946 ◽  
Author(s):  
Kim Søholm Halskov ◽  
Tore Kiilerich Johansen ◽  
Rebecca L. Davis ◽  
Marianne Steurer ◽  
Frank Jensen ◽  
...  
Keyword(s):  
Asymmetric Organocatalysis

ChemInform Abstract: Chiral Amine—Polyoxometalate Hybrids as Highly Efficient and Recoverable Asymmetric Enamine Catalysts.

ChemInform ◽  
2008 ◽  
Vol 39 (4) ◽  
Author(s):  
Sanzhong Luo ◽  
Jiuyuan Li ◽  
Hui Xu ◽  
Long Zhang ◽  
Jin-Pei Cheng
Keyword(s):  
Chiral Amine ◽  
Highly Efficient
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