Electrochemical Impedance Spectroscopy Evaluation of the Corrosion Behavior of Die Cast and Thixocast AXJ530 Magnesium Alloy in Chloride Solution

2007 ◽  
Vol 9 (1-2) ◽  
pp. 75-83 ◽  
Author(s):  
S. Jin ◽  
S. Amira ◽  
E. Ghali
2014 ◽  
Vol 624 ◽  
pp. 77-81
Author(s):  
Zhi Lin Wu ◽  
Duo Xiang Wu ◽  
Ren Shu Yuan ◽  
Lei Zhao ◽  
Yan Bao Zhao

The corrosion behavior of hydrostatic extruded tube AZ80 magnesium alloy was investigated by polarization curves and electrochemical impedance spectroscopy (EIS) in simulated atmosphere. The results indicated that, the corrosion resistance of the hydrostatic extruded AZ80 magnesium alloy with uneven deformed grains and increased sub-grains were obviously weakened, with larger corrosion current density in the polarization curves and lower corrosion resistances in the electrochemical impedance spectroscopy plots. This was mainly because of the hydrostatic extrusion which made AZ80 magnesium alloy within large numbers of dislocation tangles. So the residual stress increased the electrochemical activity of magnesium alloy which reduced the corrosion resistance of magnesium alloys.


RSC Advances ◽  
2016 ◽  
Vol 6 (83) ◽  
pp. 80275-80285 ◽  
Author(s):  
Bhavana Rikhari ◽  
S. Pugal Mani ◽  
N. Rajendran

In the present work, dynamic electrochemical impedance spectroscopy (DEIS) was used to investigate the corrosion behavior of polypyrrole (PPy)-coated titanium (Ti) in simulated body fluid (SBF) solution.


2018 ◽  
Vol 42 (17) ◽  
pp. 14394-14409 ◽  
Author(s):  
S. Pugal Mani ◽  
Bhavana Rikhari ◽  
Perumal Agilan ◽  
N. Rajendran

In the present investigation, the corrosion behavior of TiN-coated 316L SS was evaluated for use in a proton-exchange membrane fuel cell using dynamic electrochemical impedance spectroscopy (DEIS).


CORROSION ◽  
10.5006/3254 ◽  
2019 ◽  
Vol 75 (11) ◽  
pp. 1339-1353
Author(s):  
Maryam Eslami ◽  
Flavio Deflorian ◽  
Caterina Zanella

The electrochemical behavior of a low silicon aluminum alloy cast by the conventional and rheo-high-pressure die cast processes is evaluated using polarization test and electrochemical impedance spectroscopy in 0.01 M, 0.05 M, 0.1 M, and 0.6 M sodium chloride solutions. Compared to the conventional high-pressure die cast process, rheocasting introduces some alterations in the microstructure including the presence of aluminum grains with different sizes, formed at different solidification stages. According to the results of the anodic polarization test, conventional cast and rheocast samples show similar breakdown potentials. However, the rheocast samples present enhanced oxygen reduction kinetics compared to the conventional cast sample. Based on scanning electron microscopy examinations, localized microgalvanic corrosion is the main corrosion mechanism for both alloys and it initiates at the interface of aluminum with iron-rich intermetallic particles which are located inside the eutectic regions. The corrosion further develops into the eutectic area. Although the rate of the cathodic reaction can be influenced by the semisolid microstructure, according to the results of anodic polarization and electrochemical impedance spectroscopy tests, the corrosion behavior is not meaningfully affected by the casting process.


2011 ◽  
Vol 695 ◽  
pp. 425-428
Author(s):  
Duo Wang ◽  
De Ning Zou ◽  
Chang Bin Tang ◽  
Kun Wu ◽  
Huan Liu

Supermartensitic stainless steel grades are widely used in oil and gas industries to substitute duplex and super duplex stainless steels these years. In this paper the corrosion behavior of supermartensitic stainless steels with different chemical compositions, S-165 and HP, was investigated in Cl-environment. All the samples were treated by quenching at 1000 °C followed by tempering at 630 °C for 2h. After heat treatment, potentiodynamic polarization curves and electrochemical impedance spectroscopy (EIS) were determined on both kinds of samples. Polarization curves shows that the metastable pitting nucleuses were formed in passive area and the Cr content is the most important factor leading to the differences of pitting potential. The potentiodynamic polarization curves were conducted at various NaCl contents (5000, 15000 and 35000 ppm) and emphasized the need to account for the Cl-sensitivity of samples under corrosion environment. The results show that, the pitting potential decrease with the increase of chloride contents. The behavior of passive film was analyzed by electrochemical impedance spectroscopy.


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